• Title/Summary/Keyword: gas properties

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Study on the Mechanical Properties of Laser Welded AZ31 Magnesium Alloy (AZ31 마그네슘 합금 레이저 용접부의 기계적 성질에 관한 연구)

  • Lee, M.Y.;Jeong, B.H.;Jeong, S.M.;Park, H.J.
    • Laser Solutions
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    • v.9 no.1
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    • pp.25-29
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    • 2006
  • This study aimed to investigate the change of mechanical properties with the rolling direction and shielding condition during laser welding of AZ31 magnesium alloy. AZ31 magnesium alloy sheets of 1mm thickness were welded using a continuous wave Nd:YAG laser with and without Ar shielding gas. The effect of Ar shielding gas and rolling direction on the mechanical properties were investigated using Vickers hardness, transverse-weld tensile. Porosity in the weld metals was investigated using an optical microscope. The experimental results showed that mechanical properties of AZ31 magnesium alloy laser welds were upgraded compared to those of base metal. Mechanical properties of AZ31 magnesium alloy laser welds were not substantially changed when Ar shielding gas was supplied.

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Geotechnical properties of gas hydrate bearing sediments (가스 하이드레이트 부존 퇴적토의 지반공학적 물성)

  • Kim, Hak-Sung;Cho, Gye-Chun;Lee, Joo-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.151-151
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    • 2011
  • Large amounts of natural gas, mainly methane, in the form of hydrates are stored on continental margins. When gas hydrates are dissociated by any environmental trigger, generation of excess pore pressure due to released free gas may cause sediment deformation and weakening. Hence, damage on offshore structures or submarine landslide can occur by gas hydrate dissociation. Therefore, geotechnical stability of gas hydrate bearing sediments is in need to be securely assessed. However, geotechnical characteristics of gas hydrates bearing sediments including small-strain elastic moduli have been poorly identified. Synthesizing gas hydrate in natural seabed sediment specimen, which is mainly composed of silty-to-clayey soils, has been hardly attempted due to their low permeability. Moreover, it has been known that hydrate loci in pore spaces and heterogeneity of hydrate growth in specimen scale play a critical role in determining physical properties of hydrate bearing sediments. In the presented study, we synthesized gas hydrate containing sediments in an instrumented oedometric cell. Geotechnical and geophysical properties of gas hydrate bearing sediments including compressibility, small-strain elastic moduli, elastic wave, and electrical resistivity are determined by wave-based techniques during loading and unloading processes. Significant changes in volume change, elastic wave, and electrical resistivity have been observed during formation and dissociation of gas hydrate. Experimental results and analyses reveal that geotechnical properties of gas hydrates bearing sediments are highly governed by hydrate saturation, effective stress, void ratio, and soil types as well as morphological feature of hydrate formation in sediments.

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Hydrogen sulfide gas sensing mechanism study of ZnO nanostructure and improvement of sensing property by surface modification

  • Kim, Jae-Hyeon;Yong, Gi-Jung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.450-450
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    • 2011
  • This study reports the hydrogen sulfide gas sensing properties of ZnO nanorods bundle and the investigation of gas sensing mechanism. Also the improvement of sensing properties was also studied through the application of ZnO heterstructured nanorods. The 1-Dimensional ZnO nano-structure was synthesized by hydrothermal method and ZnO nano-heterostructures were prepared by sonochemical reaction. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) spectra confirmed a well-crystalline ZnO of hexagonal structure. The gas response of ZnO nanorods bundle sensor increased with increasing temperature, which is thought to be due to chemical reaction of nanorods with gas molecules. Through analysis of X-ray photoelectron spectroscopy (XPS), the sensing mechanism of ZnO nanorods bundle sensor was explained by well-known surface reaction between ZnO surface atoms and hydrogen sulfide. However at high sensing temperature, chemical conversion of ZnO nanorods becomes a dominant sensing mechanism in current system. In order to improve the gas sensing properties, simple type of gas sensor was fabricated with ZnO nano-heterostructures, which were prepared by deposition of CuO, Au on the ZnO nanorods bundle. These heteronanostructures show higher gas response and higher current level than ZnO nanorods bundle. The gas sensing mechanism of the heteronanostructure can be explained by the chemical conversion of sensing material through the reaction with target gas.

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MOLECULAR GAS PROPERTIES UNDER ICM PRESSURE IN THE CLUSTER ENVIRONMENT

  • LEE, BUMHYUN;CHUNG, AEREE
    • Publications of The Korean Astronomical Society
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    • v.30 no.2
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    • pp.491-494
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    • 2015
  • We present 12CO (2-1) data for four spiral galaxies (NGC 4330, NGC 4402, NGC 4522, NGC 4569) in the Virgo cluster that are undergoing different ram pressure stages. The goal is to probe the detailed molecular gas properties under strong intra-cluster medium (ICM) pressure using high-resolution millimeter data taken with the Submillimeter Array (SMA). Combining this with Institut de RadioAstronomie $Millim{\acute{e}}trique$ (IRAM) data, we also study spatially resolved temperature and density distributions of the molecular gas. Comparing with multi-wavelength data (optical, $H\small{I}$, UV, $H{\alpha}$), we discuss how molecular gas properties and star formation activity change when a galaxy experiences $H\small{I}$ stripping. This study suggests that ICM pressure can modify the physical and chemical properties of the molecular gas significantly even if stripping does not take place. We discuss how this affects the star formation rate and galaxy evolution in the cluster environment.

Magnetic Properties and Microstructure of Co Thin Films by RF-diode Sputtering Method (RF-diode Sputtering법으로 제작한 Co박막의 자기특성과 미세구조)

  • Han, Chang-Suk;Kim, Sang-Wook
    • Korean Journal of Materials Research
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    • v.28 no.3
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    • pp.159-165
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    • 2018
  • In order to increase the efficiency of the sputtering method widely used in thin film fabrication, a dc sputtering apparatus which supplies both high frequency and magnetic field from the outside was fabricated, and cobalt thin film was fabricated using this apparatus. The apparatus can independently control the applied voltage, the target-substrate distance, and the target current, which are important parameters in the sputtering method, so that a stable glow discharge is obtained even at a low gas pressure of $10^{-3}$ Torr. The fabrication conditions using the sputtering method were mainly performed in $Ar+O_2$ mixed gas containing about 0.6 % oxygen gas under various Ar gas pressures of 1 to 30 mTorr. The microstructure of Co thin films deposited using this apparatus was examined by electron diffraction pattern and X-ray techniques. The magnetic properties were investigated by measuring the magnetization curves. The microstructure and magnetic properties of Co thin films depend on the discharge gas pressure. The thin film fabricated at high gas pressure showed a columnar structure containing a large amount of the third phase in the boundary region and the thin film formed at low gas pressure showed little or no columnar structure. The coercivity in the plane was slightly larger than that in the latter case.

Properties of Sputtered Ga Doped ZnO Thin Film Under Various Reaction Gas Ratio (Reaction Gas 변화에 따라 스퍼터된 Ga Doped ZnO 박막의 특성)

  • Kim, Jong-Wook;Kim, Hong-Bae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.4
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    • pp.289-293
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    • 2013
  • We have studied structural, optical, and electrical properties of the Ga-doped ZnO (GZO) thin films being usable in transparent conducting oxides. The GZO thin films were deposited on the corning 1737 glass plate by the RF magnetron sputtering system. To find optimal properties of GZO for transparent conducting oxides, the Ar gas in sputtering process was varied as 40, 60, 80 and 100 sccm, respectively. As reaction gas decreased, the crystallinity of GZO thin film was increased, the optical bandgap of GZO thin film increased. The transmittance of the film was over 80% in the visible light range regardless of the changes in reaction gas. The measurement of Hall effect characterizes the whole thin film as n-type, and the electrical property was improved with decreasing reaction gas. The structural, optical, and electrical properties of the GZO thin films were affected by Ga dopant content in GZO thin film.

Study on the Thermodynamic Properties and Combustion Information of Natural Gases from Various Producing Districts (산지별 천연가스들의 열 물성치 및 연소 정보 검토)

  • Lee, Chang-Eon;Hyun, Seung-Ho;Hwang, Cheol-Hong;Lee, Sung-Min;Ha, Young-Cheol;Lee, Kang-Jin
    • Journal of the Korean Society of Combustion
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    • v.12 no.1
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    • pp.38-47
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    • 2007
  • The diversification of import districts of natural gas is trying to prepare an increase in the demand and price. The interchangeability of natural gases should be examined prior to supply to gas appliances, although compositional differences among natural gases are not large. The object of this study is to investigate numerically the thermodynamic and transport properties as well as information on combustion of 6 natural gases. Comparing the properties of BOG1 with those of standard gas, the maximum differences of heating value, Wobbe index, air-fuel ratio, and specific heat are 10%, 4%, 10% and 5.54%, respectively. That is, the BOG1 is required careful application. However, all gases except for BOG1 show the similar properties with standard gas. Finally, the combustion information such as flame temperature and burning velocity are examined. These results will provide the useful information related to the interchangeability of various natural gases in practical combustion appliances.

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Preparation, Characterization, and Gas Permeation Properties of Carbon Molecular Sieve Membranes Derived from Dense P84-Polyimide Film

  • Park, Ho-Bum;Nam, Sang-Yong;Jang, Jeong-Gyu;Lee, Young-Moo
    • Korean Membrane Journal
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    • v.4 no.1
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    • pp.25-35
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    • 2002
  • The gas permeation properties have been studied on carbon molecular sieve (CMS) membranes prepared by pyrolysis of P84 polyimide under various conditions. P84 polyimide shows high permselectivities (O$_2$/N$_2$= 9.17 and CO$_2$/N$_2$= 35) for various gas pairs and has a good processibility because it is easily soluble in high polar solvents such as N-methylpyrrolidinone (NMP), dimethylformamide (DMF), and N,N-dimethylacetamide (DMAc). After pyrolysis under Ar flow, the change in the heating rate was found to affect the gas permeation properties to some extent. The permeabilities of the selected gases were shown to be in the order He > CO$_2$> O$_2$> N$_2$for all the CMS membranes, whose order was in accordance with the order of kinetic gas diameters. It also revealed that the pyrolysis temperature considerably influenced the gas permeation properties of the CMS membranes derived from P84 polyimide. The CMS membranes pyrolized at 700$\^{C}$ temperature exhibited the highest permeability with relatively targe loss in permselectivity. This means that the pyrolysis temperature should be varied in accordance with target gases to be separated.

Effects of Oxygen Contents in Shielding Gas on the Properties of Ferritic Stainless Steel GTA Weld (페라이트계 스테인리스강 GTA 용접부 특성에 미치는 보호가스 중 산소의 영향)

  • Lee, Won-Bae;Uhm, Sang-Ho;Woo, In-Su
    • Journal of Welding and Joining
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    • v.28 no.5
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    • pp.93-98
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    • 2010
  • The properties of GTA weld for ferritic stainless steel have been studied with different $O_2$ contents in Ar shielding gas at the constant welding speed. A small amount of $O_2$ (0.01~1.0%) was mixed in Ar shielding gas in order to improve the weld penetration. The fully penetrated GTA weld was acquired at 160A weld current shielded by pure Ar gas. Addition of oxygen larger than 0.1% made a full penetration at lower weld current than 160A. The small addition of $O_2$ in Ar shielding gas improved the penetration properties of GTA weld because the $O_2$ in the molten pool accelerated the flow of molten pool and changed the flow pattern from outward to inward direction. The impact energy and DBTT (Ductile- Brittle- Transition-Temperature) of the GTA weld shielded by Ar+$O_2$ (less 0.3%) was similar and the corrosion properties of GTA weld was slightly inferior to those of GTA weld shielded by pure Ar gas.

The Fabrication of FET-Type NOx Gas Sensing System Using the MWCNT (다중벽 카본 나노튜브를 이용한 FET식 NOx 가스 센싱 시스템 제작)

  • Kim, Hyun-Soo;Jang, Kyung-Uk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.4
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    • pp.325-329
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    • 2013
  • Carbon nanotubes(CNT) have excellent electrical, chemical stability and mechanical properties. These can be used in a variety of fields. MWCNT are extremely sensitive for minute changes in the ambient gas, namely, their sensing properties varies greatly with the absorption of gas such as NOx and $H_2$. We investigate the electrical properties of CNTs and make a NOx gas sensor based on Multi-walled carbon nanotubes (MWCNT) materials. We obtained the NOx gas sensor of MWCNT based on P-type Si wafer that has the resistivity of $1.667{\times}10^{-1}[{\Omega}{\cdot}cm]$. We knew that the sensitivity of sensor decreased with increasing of NOx gas concentration. And the sensitivity of sensor shows the largest value at $20^{\circ}C$. The sensitivity of sensor decrease with increasing the temperature. Also absorption energy of NOx gas molecule on the MWCNT surface decreases with increasing concentration of NOx gas.