• Title/Summary/Keyword: gas diffusion

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Fabrication of SmBCO coated conductor using $CeO_2$ single buffer layer ($CeO_2$ 단일 완충층을 이용한 SmBCO 초전도테이프 제조)

  • Kim, T.H.;Kim, H.S.;Oh, S.S.;Yang, J.S.;Ko, R.K.;Ha, D.W.;Song, K.J.;Ha, H.S.;Jung, K.D.;Pa, K.C.;Cho, S.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.261-262
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    • 2006
  • High temperature superconducting coated conductor has multi-layer structure of protecting layer/superconducting layer/buffer layer/metallic substrate. The buffer layer consists of multi layer, and the architecture most widely used in RABiTS approach is $CeO_2$(cap layer)/YSZ(diffusion barrier layer)/$CeO_2$(seed layer). Multi-buffer layer deposition required many times and process. Therefore single buffer layer deposition study reduce 2G HTS manufacture efforts. Evaporation technique for single buffer deposition method is used for the $CeO_2$ layer. $CeO_2$ single buffer film could be achieved in the chamber. Detailed deposition conditions (temperature and partial gas pressure of deposition) were investigated for the rapid growth of high quality $CeO_2$ single buffer film.

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Low-Temperature Growth of N-doped SiO2 Layer Using Inductively-Coupled Plasma Oxidation and Its Effect on the Characteristics of Thin Film Transistors (플라즈마 산화방법을 이용한 질소가 첨가된 실리콘 산화막의 제조와 산화막 내의 질소가 박막트랜지스터의 특성에 미치는 영향)

  • Kim, Bo-Hyun;Lee, Seung-Ryul;Ahn, Kyung-Min;Kang, Seung-Mo;Yang, Yong-Ho;Ahn, Byung-Tae
    • Korean Journal of Materials Research
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    • v.19 no.1
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    • pp.37-43
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    • 2009
  • Silicon dioxide as gate dielectrics was grown at $400^{\circ}C$ on a polycrystalline Si substrate by inductively coupled plasma oxidation using a mixture of $O_2$ and $N_2O$ to improve the performance of polycrystalline Si thin film transistors. In conventional high-temperature $N_2O$ annealing, nitrogen can be supplied to the $Si/SiO_2$ interface because a NO molecule can diffuse through the oxide. However, it was found that nitrogen cannot be supplied to the Si/$SiO_2$ interface by plasma oxidation as the $N_2O$ molecule is broken in the plasma and because a dense Si-N bond is formed at the $SiO_2$ surface, preventing further diffusion of nitrogen into the oxide. Nitrogen was added to the $Si/SiO_2$ interface by the plasma oxidation of mixtures of $O_2/N_2O$ gas, leading to an enhancement of the field effect mobility of polycrystalline Si TFTs due to the reduction in the number of trap densities at the interface and at the Si grain boundaries due to nitrogen passivation.

Dynamic Rectangle Zone-based Collaboration Mechanism for Continuous Object Tracking in Wireless Sensor Networks (센서 네트워크에서 연속적인 개체 추적을 위한 동적 직사각형 영역 기반 협동 메커니즘)

  • Park, Bo-Mi;Lee, Eui-Sin;Kim, Tae-Hee;Park, Ho-Sung;Lee, Jeong-Cheol;Kim, Sang-Ha
    • Journal of KIISE:Computing Practices and Letters
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    • v.15 no.8
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    • pp.591-595
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    • 2009
  • Most existing routing protocols for object detection and tracking in wireless sensor networks concentrate on finding ways to detect and track one and more individual objects, e.g. people, animals, and vehicles, but they do not be interested in detecting and tracking of continuous objects, e.g., poison gas and biochemical. Such continuous objects have quite different properties from the individual objects since the continuous objects are continuously distributed across a region and usually occupy a large area, Thus, the continuous objects could be detected by a number of sensor nodes so that sensing data are redundant and highly correlated. Therefore, an efficient data collection and report scheme for collecting and locally aggregating sensing data is needed, In this paper, we propose the Continuous Object Tracking Mechanism based on Dynamic Rectangle Zone for detecting, tracking, and monitoring the continuous objects taking into account their properties.

Antimicrobial and cytotoxic activity of Ferula gummosa plant essential oil compared to NaOCl and CHX: a preliminary in vitro study

  • Abbaszadegan, Abbas;Gholami, Ahmad;Mirhadi, Hosein;Saliminasab, Mina;Kazemi, Aboozar;Moein, Mahmood Reza
    • Restorative Dentistry and Endodontics
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    • v.40 no.1
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    • pp.50-57
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    • 2015
  • Objectives: The usage of medicinal plants as natural antimicrobial agents has grown in many fields including dental medicine. The aim of this in vitro study was three-fold: (i) to determine the chemical compositions of the Ferula gummosa essential oil (FGEO), (ii) to compare the antimicrobial efficacy of the oil with sodium hypochlorite (NaOCl) and chlorhexidine (CHX), (iii) to assess the toxic behavior of FGEO in different concentrations compared to 5% NaOCl and 0.2% CHX. Materials and Methods: Gas chromatography/mass spectrometry (GC/MS) was used to determine the chemical compositions of the oil. The disk diffusion method and a broth micro-dilution susceptibility assay were exploited to assess the antimicrobial efficacy against Enterococcus faecalis, Staphylococcus aureus, Streptococcus mitis, and Candida albicans. The cytocompatibility of the FGEO was assessed on L929 fibroblasts, and compared to that of NaOCl and CHX. Results: Twenty-seven constituents were recognized in FGEO. The major component of the oil was ${\beta}$-pinene (51.83%). All three irrigants significantly inhibited the growth of all examined microorganisms compared to the negative control group. FGEO at $50{\mu}g/mL$ was effective in lower concentration against Enterococcus faecalis than 5% NaOCl and 0.2% CHX, and was also more potent than 0.2% CHX against Candida albicans and Staphylococcus aureus. FGEO was a cytocompatible solution, and had significantly lower toxicity compared to 5% NaOCl and 0.2% CHX. Conclusions: FGEO showed a promising biological potency as a root canal disinfectant. More investigations are required on the effectiveness of this oil on intracanal bacterial biofilms.

Optimal Aluminizing Coating on Incoloy 909 (Incoloy 909 합금의 최적 알루미나이징 확산 코팅)

  • Kwon, S.W.;Yoon, J.H.;Joo, Y.K.;Cho, T.Y.;Ahn, J.S.;Park, B.K.
    • Journal of the Korean institute of surface engineering
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    • v.40 no.4
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    • pp.175-179
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    • 2007
  • An Fe-Ni-Co based superalloy Incoloy 909 (Incoloy 909) has been used for gas turbine engine component material. This alloy is susceptible to high temperature oxidation and corrosion because of the absence of corrosion resistant Cr. For the improvement of durability of the component of Incoloy 909 aluminizing-chromate coating by pack cementation process has been investigated at relatively low temperature of about $550^{\circ}C$ to protect the surface microstructure and properties of Incoloy 909 substrate. As a previous study to aluminizing-chromate coating by pack cementation of Incoloy 909, the optimal aluminizing process has been investigated. The size effects of source Al powder and inert filler $Al_O_3$ powder and activator selection have been studied. And the dependence of coating growth rate on aluminizing temperature and time has also been studied. The optimal aluminizing process for the coating growth rate is that the mixing ratio of source Al powder, activator $NH_4Cl$ and filler $Al_O_3$ are 80%, 1% and 19% respectively at aluminizing temperature $552^{\circ}C$ and time 20 hours.

Bioactive Compound Produced by Endophytic Fungi Isolated From Pelargonium sidoides Against Selected Bacteria of Clinical Importance

  • Manganyi, Madira Coutlyne;Tchatchouang, Christ-Donald K.;Regnier, Thierry;Bezuidenhout, Cornelius Carlos;Ateba, Collins Njie
    • Mycobiology
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    • v.47 no.3
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    • pp.335-339
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    • 2019
  • Endophytic fungi have the ability to live inside the host plant tissues without causing neither symptoms of diseases/or harm. Opportunistic infections are accountable for majority of the outbreaks, thereby putting a burden on the health system. To investigate and characterize the bioactive compounds for the control of bacteria of clinical importance, extracts from endophytic fungi were isolated from indigenous South African medicinal plants. Extracts from endophytic fungi were isolated from 133 fungal strains and screened against Gram positive and negative bacteria namely Bacillus cereus, Escherichia coli, Enterococcus faecium, and E. gallinarum using disk diffusion. Furthermore, gas chromatography-mass spectrometry was performed to identify the bioactive compounds. Sixteen out of one hundred and thirty-three (12%) fungi extracts exhibited antibacterial properties against some of the selected bacteria. E. coli was found to be the most susceptible in contrast to E. faecium and E. gallinarum which were the most resistant. The isolate MHE 68, identified as Alternaria sp. displayed the greater spectrum of antibacterial activities by controlling selected clinical bacteria strains including resistant E. faecium and E. gallinarum. The chemical analysis of the extract from MHE 68 indicated that linoleic acid (9,12-octadecadienoic acid (Z,Z)) and cyclodecasiloxane could be accountable for the antibacterial activity. This is the first study conducted on the secondary metabolites produced by endophytic fungal strains isolated from the Pelargonium sidoides DC. possessing antibacterial properties.

Changes in CO2 Absorption Efficiency of NaOH Solution Trap with Temperature

  • Park, Se-In;Park, Hyun-Jin;Yang, Hye In;Choi, Woo-Jung
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.6
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    • pp.554-561
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    • 2017
  • Under the projected global warming, release of carbon as $CO_2$ through soil organic matter decomposition is expected to increase. Therefore, accurate measurement of $CO_2$ released from soil is crucial in understanding the soil carbon dynamics under increased temperature conditions. Sodium hydroxide (NaOH) traps are frequently used in laboratory soil incubation studies to measure soil respiration rate, but decreasing $CO_2$ gas solubility with increasing temperature may render the reliability of the method questionable. In this study, the influences of increasing temperature on the $CO_2$ capture capacity of NaOH traps were evaluated under $5{\sim}35^{\circ}C$ temperature range at $10^{\circ}C$ interval. Two closed-chamber experiments were performed where NaOH traps were used to capture $CO_2$ either released from acidified $Na_2CO_3$ solution or directly injected into the chamber. The sorption of ambient $CO_2$ within the incubators into NaOH traps was also measured. The amount $CO_2$ captured increased as temperature increased within 2 days of incubation, suggesting that increased diffusion rate of $CO_2$ at higher temperatures led to increases in $CO_2$ captured by the NaOH traps. However, after 2 days, over 95% of $CO_2$ emitted in the emission-absorption experiment was captured regardless of temperature, demonstrating high $CO_2$ absorption efficiency of the NaOH traps. Thus, we conclude that the influence of decreased $CO_2$ solubility by increased temperatures is negligible on the $CO_2$ capture capacity of NaOH traps, supporting that the use of NaOH traps in the study of temperature effect on soil respiration is a valid method.

Variation of Performance with Operation Condition of Benthic Microbial Fuel Cells (저생 미생물 연료전지(BMFC)의 구동조건에 따른 성능 변화)

  • Oh, So-Hyeong;Kwag, Ha-Won;Lee, Ye-Jin;Kim, Young-Sook;Chu, Cheun-Ho;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.57 no.2
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    • pp.172-176
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    • 2019
  • A benthic microbial fuel cells(BMFC) is fuel cell using electricity produced by decomposing organic matter in a sea or a lake. In this study, we used a gas diffusion layer (GDL) of a polymer electrolyte fuel cell (PEMFC) as a BMFC electrode to find out the operation conditions with high performance. The performance of BMFC was increased as resistance of external resistor increased. It was possible to maintain the performance by avoiding the increase of the contact resistance with the electrode due to corrosion of the lead wire in seawater. The bubble generator was able to increase the maximum power density by more than 2 times and the optimum operating temperature was $40^{\circ}C$.

Anisotropic Acorn-like Particle Fabrication Via a Dynamic Phase Separation Method (동적 상분리법을 이용한 이방성 도토리형상 입자 제조)

  • Park, Chul Ho;Baek, Il-hyun
    • Membrane Journal
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    • v.29 no.1
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    • pp.61-65
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    • 2019
  • Anisotropic particles have been issued in various fields due to their unique physical properties. Herein, a novel dynamic phase separation method (DPS) is introduced to fabricate anisotropic acorn-like nanoparticles. DPS consists of two dynamic conditions; solvent evaporation and nonsolvent induced precipitation. The bottom layer is controlled by feeding the water as a non-solvent diluent, and the phase separation of the upper layer relies on the diffusion and evaporation of a volatile good solvent. At this condition, the acorn-like particles were fabricated. Under a closed box filled with water (spontaneous phase separation), monodisperse polystyrene (PS) particles were synthesized. At the coexistence between DPS and spontaneous phase separation, the sizes of cap and particle were changed. Also, the volume of PS solutions influences on the particle shape. Since the unique structures could be utilized into various applications, if advanced techniques such as membrane-based controlled water feeding is developed, monodisperse acorn-like particles could be tuned.

Global Fitting Functions for Kinetics of Fe-Selective Chlorination in Ilmenite and Successive Chlorination of Beneficiated TiO2 (일메나이트 중 철의 선택적 염화와 선광된 TiO2의 추가 염화반응에 대한 글로벌 피팅함수)

  • Chung, Dong-Kyu;Won, Yong Sun;Kim, Yong-Ha;Jung, Eun-Jin;Song, Duk-Yong
    • Korean Journal of Materials Research
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    • v.29 no.7
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    • pp.412-424
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    • 2019
  • Global fitting functions for Fe-selective chlorination in ilmenite($FeTiO_2$) and successive chlorination of beneficiated $TiO_2$ are proposed and validated based on a comparison with experimental data collected from the literature. The Fe-selective chlorination reaction is expressed by the unreacted shrinking core model, which covers the diffusion-controlling step of chlorinated Fe gas that escapes through porous materials of beneficiated $TiO_2$ formed by Fe-selective chlorination, and the chemical reaction-controlling step of the surface reaction of unreacted solid ilmenite. The fitting function is applied for both chemical controlling steps of the unreacted shrinking core model. The validation shows that our fitting function is quite effective to fit with experimental data by minimum and maximum values of determination coefficients of $R^2$ as low as 0.9698 and 0.9988, respectively, for operating parameters such as temperature, $Cl_2$ pressure, carbon ratio and particle size that change comprehensively. The global fitting functions proposed in this study are expressed simply as exponential functions of chlorination rate(X) vs. time(t), and each of them are validated by a single equation for various reaction conditions. There is therefore a certain practical merit for the optimal process design and performance analysis for field engineers of chlorination reactions of ilmenite and $TiO_2$.