• Title/Summary/Keyword: functional effect

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Heavy Metal Adsorption of Anodically Treated Activated Carbon Fibers in Aqueous Solution

  • Park, Soo-Jin;Kim, Young-Mi
    • Carbon letters
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    • v.4 no.1
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    • pp.21-23
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    • 2003
  • In this work, the effect of anodic oxidation treatment on Cr(VI) ion adsorption behaviors of activated carbon fibers (ACFs) was investigated. The aqueous solutions of 10 wt% $H_3PO_4$ and $NH_4OH$ were used for acidic and basic electrolytes, respectively. Surface characteristics and textural properties of ACFs were determined by XPS and $N_2$ adsorption at 77 K. The heavy metal adsorption of ACFs was conducted by ICP. As a result, the adsorption amount of the anodized ACFs was improved in order of B-ACFs > A-ACFs > pristine-ACFs. In case of the anodized treated ACFs, the specific surface area was decreased due to the pore blocking or pore destroying by acidic electrolyte. However, the anodic oxidation led to an increase of the Cr(VI) adsorption, which can be attributed to an increase of oxygen-containing functional groups, such as, carboxylic, lactonic, and phenolic groups. It was clearly found that the Cr(VI) adsorption was largely influenced by the surface functional groups, in spite of the reduced specific surface area of the ACFs.

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Local Structure Study of Liquid Phase Ethylene Glycol and 1,3-propanediol through Density Functional Theory

  • Nam, Seungsoo;Sim, Eunji
    • Proceeding of EDISON Challenge
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    • 2016.03a
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    • pp.140-146
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    • 2016
  • Using density functional Theory, we studied local structure of liquid ethylene glycol and 1,3-propanediol. For both liquid, making intramolecular hydrogen bonding is not preferred, because relative energy between with and without intramolecular hydrogen bond is only -1.95kcal/mol, which is far less than intermolecular hydrogen bonding energy, about -7.5kcal/mol. Also, hydrogen bond induce polarization of hydroxyl group and make $2^{nd}$ hydrogen bond more stronger. This effect was small in intramolecular hydrogen bond of ethylene glycol. When considering energy per hydrogen bond, making only one intermolecular hydrogen bond for ethylene glycol pair is energetically favored, while two intermolecular hydrogen bond can be formed in 1,3-propanediol pair.

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Development of Susceptible Functional Fibers using Microcapsule of Susceptible Materials(I) ―Photochromic functional fibers― (감성물질의 마이크로캡슐화에 의한 감성기능 섬유이 개발(I) ―감광변색 기능섬유―)

  • Kim, Moon Sik;Park, Sun Ju;Park, Soo Min
    • Textile Coloration and Finishing
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    • v.7 no.4
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    • pp.97-104
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    • 1995
  • The photochromic dyes(spiroxazine) as a susceptible material were synthesized by condensing 1-nitroso-$\beta$-naphthol with piperidine. The melting point of the synthesized spiroxazine dye was 245$^{\circ}C$. Irradiation with ultraviolet light had effect on reversible coloration reaction. The photochromic dye microcapsules were produced by interfacial precipitation method using polyvinylalcohol and ethylcellulose. The average diameter of microcapsules was 5.4$\mu$m. The dyeability and fastness of dyeings of the microcapsule fibers were increased by pretreatment of the cationic agent.

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A Study on Characteristics of Surface Modified Polyimide Film by Wet Process (습식 표면개질 처리된 폴리이미드 필름 표면의 특성에 관한 연구)

  • Koo, S.B.;Lee, H.K.
    • Journal of the Korean institute of surface engineering
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    • v.39 no.4
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    • pp.166-172
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    • 2006
  • Metallized Polyimide films are extensively used as base materials in microelectronics, optical and automotive applications. However it is difficult to deposit metals on those because of their structural stabilities. In this work, polyimide films are modified by a wet process with alkalinemetalhydroxide and additives to introduce functional groups. The surface molecular structures of polyimide are investigated using X-ray photoelectron spectroscopy(XPS), fourier transform infrared reflection spectroscopy(FTIR-ATR), atomic force micro-scopic(AFM). XPS spectra and FTIR spectra show that the surface structure of polyimide is converted into potassium polyamate. AFM image and AFM cross-sectional analyses reveal the increased roughness on the modified surface of polyimide films. As a result, it is shown that the adhesion strength between polyimide surface and electroless nickel layer is increased by the nano-anchoring effect.

The Effect of Plasma Treatment on Surface Properties and Adhesion Characteristics of semiconductive Silicone Rubber (반도전성 실리콘 고무의 표면 특성과 접착특성에 미치는 플라즈마 처리의 영향)

  • Hwang, Sun-Mook;Hong, Joo-Il;Hwang, Cheong-Ho;Huh, Chang-Su
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.254-255
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    • 2005
  • In this work, the effects of plasma treatment on surface properties of semi conductive silicone rubber were investigated in terms of X-ray photoelectron spectroscopy(XPS). The adhesion characteristics of semiconductive-insulating interface layer of silicone rubber were studied by measuring the T-peel strengths. As a result, semiconductive silicone rubber surfaces treated with plasma discharge led to and increase in oxygen-containing functional groups, resulting in improving the degree of adhesion of the semiconductive-insulating interface layer of silicone rubber. these results are probably due to the modifications of surface functional groups or polar component of surface free energy of the semi conductive silicone rubber.

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Effect of Ankle Stabilization Training Using Biofeedback on Balance Ability and Lower Limb Muscle Activity in Football Players with Functional Ankle Instability

  • Kim, Je-Ho;Uhm, Yo-Han
    • The Journal of Korean Physical Therapy
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    • v.28 no.3
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    • pp.189-194
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    • 2016
  • Purpose: This study focuses on influence of ankle stabilization training on balance ability and lower limb muscle activation of soccer player with functional ankle instability. Methods: Subjects were grouped into ankle stabilization training group using biofeedback comprised of 15 subjects and general exercise group of 15. The training was conducted for 30 minutes, 3 times a week for 8 weeks in total. All 30 football players conducted plyometric training for 30 minutes before main training. To evaluate balance ability, biorescure was used to measure whole path length and surface area and surface electromyography (EMG) system was used to measure tibialis anterior, tibialis posterior, and soleus to evaluate lower limb muscle activation. Results: The experiment group showed significant difference to the comparison group in regard of whole path length and surface area which represents balancing capability and muscle activation of tibialis anterior, tibialis posterior, and soleus. Conclusion: Therefore, ankle stabilization training using biofeedback is more effective in enhancing balance ability and lower limb muscle activation than general exercise.

Mobility-Spectrum Analysis of an Anisotropic Material System with a Single-Valley Indirect-Band-Gap Semiconductor Quantum-Well

  • Joung, Hodoug;Ahn, Il-Ho;Yang, Woochul;Kim, Deuk Young
    • Electronic Materials Letters
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    • v.14 no.6
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    • pp.774-783
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    • 2018
  • Full maximum-entropy mobility-spectrum analysis (FMEMSA) is the best algorithm among mobility spectrum analyses by which we can obtain a set of partial-conductivities associated with mobility values (mobility spectrum) by analyzing magnetic-field-dependent conductivity-tensors. However, it is restricted to a direct band-gap semiconductor and should be modified for materials with other band structures. We developed the modified version of FMEMSA which is appropriate for a material with a single anisotropic valley, or an indirect-band-gap semiconductor quantum-well with a single non-degenerate conduction-band valley e.g., (110)-oriented AlAs quantum wells with a single anisotropic valley. To demonstrate the reliability of the modified version, we applied it to several sets of synthetic measurement datasets. The results demonstrated that, unlike existing FMEMSA, the modified version could produce accurate mobility spectra of materials with a single anisotropic valley.

A Study on the Evaluation of Flow Characteristics of Heating and Cooling Unit Installed within Ceiling with Functional Modules (기능성 모듈이 적용된 천장 매립식 냉난방 유닛의 유동특성 평가에 관한 연구)

  • Lee, Hong-Cheol;Hwang, In-Ju
    • Proceedings of the SAREK Conference
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    • 2006.06a
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    • pp.1131-1136
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    • 2006
  • In this study, an experimental and numerical analysis on the flow characteristics of heating and cooling unit installed within ceiling with functional modules was carried out. And the flow characteristics of the heating and cooling unit was investigated with the main parameters such as each filter and inside structure. The experimental results show the possibility of medium filter application. And the numerical results show that the effect of improved inside structure of heating-cooling and air-conditioning unit on flow distribution.

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User Review Mining: An Approach for Software Requirements Evolution

  • Lee, Jee Young
    • International journal of advanced smart convergence
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    • v.9 no.4
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    • pp.124-131
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    • 2020
  • As users of internet-based software applications increase, functional and non-functional problems for software applications are quickly exposed to user reviews. These user reviews are an important source of information for software improvement. User review mining has become an important topic of intelligent software engineering. This study proposes a user review mining method for software improvement. User review data collected by crawling on the app review page is analyzed to check user satisfaction. It analyzes the sentiment of positive and negative that users feel with a machine learning method. And it analyzes user requirement issues through topic analysis based on structural topic modeling. The user review mining process proposed in this study conducted a case study with the a non-face-to-face video conferencing app. Software improvement through user review mining contributes to the user lock-in effect and extending the life cycle of the software. The results of this study will contribute to providing insight on improvement not only for developers, but also for service operators and marketing.

Reaction of Thexylalkoxyboranes with Selected Orgnic Compounds Containing Representative Functional Groups Comparison of Reducing Characteristics of the Alkoxy Derivatives

  • 차진순;장석원;권오운;전중현
    • Bulletin of the Korean Chemical Society
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    • v.19 no.2
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    • pp.243-249
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    • 1998
  • The reaction of alcohol with a solution of thexylborane (ThxBH2) in tetrahydrofuran (THF) provides a new class of mild and selective reducing agents, thexylalkoxyboranes (ThxBHOR: R=Et, i-Pr, i-Bu, s-Bu, t-Bu, Ph). In order to elucidate the effect of the alkoxy group in reduction reactions, the reducing power of ThxBHOR toward selected organic compounds containing representative functional groups under practical conditions (THF, 25°, the quantitative amount of reagent to compound) has been investigated. Generally, the reactivity of ThxBHOR is largely dependent upon the alkoxy substituent. ThxBHOR can be synthesized from a variety of alcohols, thus allowing control of the steric and electronic environment of these reagents.