• Title/Summary/Keyword: functional coating

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Synthesis and Physical Property of Multi-Functional Siloxane Protective Coating Materials Applicable for Electronic Components

  • Kim, Cheol Hyun;Cho, Hyeon Mo;Lee, Myong Euy
    • Bulletin of the Korean Chemical Society
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    • v.35 no.6
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    • pp.1665-1669
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    • 2014
  • Four multialkoxy-functionalized siloxane base-polymers (BP-1~4) were synthesized through either hydrosilylation or condensation reactions in order to prepare multi-networked siloxane polymers having appropriate physical properties for protective coating in fabrications of electronics. Formulations of 4 base-polymers gave coating materials A and B. Product A showed well-controlled flowing and leveling properties, and product A-2 was successfully applied to protective insulating coating for junction areas of connectors and chips in PDP controller. Tack free time, extrusion rate, dielectric breakdown voltage, hardness, thermal stability, water resistance and flame resistance of products A and B were examined.

Durability and Bioassay of a Sulfur Polymer Surface Protecting Agent for Concrete Structures (콘크리트 구조물용 유황폴리머 표면보호재의 내구성능 및 생물독성)

  • Seok, Byoung-Yoon;Lee, Byung-Jae;Kim, Yun-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.6
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    • pp.29-36
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    • 2015
  • In this study, to examine the use of sulfur polymer as a coating agent for concrete, durability and hazard evaluations were performed. The result of the evaluation indicated that the chemical resistance of the coating agent for concrete was outstanding against acidic, base, and alkaline solutions. The evaluation of the bond strength after an accelerated weathering test depending on the mixing condition indicated that the most outstanding strength characteristic was obtained when silica powder and fly ash were mixed at the same time. The bond strength exceeded 1 MPa in every mixing condition even after the repeated hot and cold treatment of the coating agent specimen for concrete, and the SFS mix proportion showed the highest bond strength. The examination of the accelerated carbonation and chloride ion penetration resistance of the concrete coated with the coating agent indicated that the specimen coated with the coating agent using silica powder as a filler showed the most outstanding durability. When a fish toxicity test was performed to examine the hazard of the use of the functional polymer as a coating agent for concrete, the functional polymer was found to have no effect on the organisms. When the chemical resistance, freezing and thawing resistance, carbonation, and chloride ion penetration resistance of the coating agent were considered, substituting silica powder and fly ash as the fillers of the functional polymer by 20%, respectively, was the optimal level in the range of this study.

A Clinical Study on the Relationship between Pattern Identifications for Patients with Functional Dyspepsia and Tongue Features (기능성소화불량 환자에서 변증유형과 설 지표의 상관성 연구)

  • Lee, Hanul;Jeong, Hae In;Lee, Hyun-Jin;Cho, Yunjae;Keum, Chang-Yul;Han, Aram;Ha, Na-Yeon;Kim, Jinsung
    • The Journal of Internal Korean Medicine
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    • v.42 no.6
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    • pp.1199-1210
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    • 2021
  • Objectives: The aim of this study was to analyze the correlation between patterns determined by pattern identification of functional dyspepsia (FD) and tongue features, including tongue coating and tooth marks, in FD patients. Methods: We reviewed the clinical records of 68 FD patients who visited the Department of Digestive Diseases of Kyung Hee University Korean Medicine Hospital from September 1, 2020 to August 31, 2021. The subjects were evaluated with a computerized tongue image acquisition system (CTIS) and by pattern identification of FD. Measurement included the percentage of tongue coating, tooth mark levels, and pattern scores. Results: Statistically significant negative correlations were noted between the scores of the pattern of 'spleen and stomach deficiency and cold' (SSDC) and the percentage of tongue coating in whole, center, and root of the tongue body. However, no other patterns were correlated with any parameter measured by CTIS. No significant difference was noted in the percentage of tongue coating and the tooth mark level between the patterns. Conclusions: This study demonstrated that the pattern of SSDC was significantly associated with the percentage of tongue coating. We suggest that the percentage of tongue coating could be a useful indicator for identifying the degree of patterning of SSDC in patients with FD.

High Durable Anti-Reflective Polymer with Silica Nanoparticle Array Fabricated by RF Magnetron Sputter (RF sputter를 이용한 실리카 증착 고 내구성 반사 방지막 제조)

  • Jeon, Seong-Gwon;Jeong, Eun-Uk;Rha, Jong-Joo;Kwon, Jung-Dae
    • Journal of the Korean institute of surface engineering
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    • v.52 no.2
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    • pp.84-89
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    • 2019
  • We fabricated durable anti-reflective(AR) layer with silica globular coating on polymer by two steps. Firstly, nano-protrusions of polymer were formed by plasma etching known as R.I.E(reactive ion etching) process. Secondly, silica globular coating was deposited on polymer nano-protrusions for mechanically protective and optically enhancing AR layers by RF magnetron sputter. And then durable antireflective polymers were synthesized adjusting plasma power and time, working pressures of RIE and RF sputtering processes. Consequently, we acquired the average transmission (94.10%) in the visible spectral range 400-800 nm and the durability of AR layer was verified to sustain its transmission until 5,000 numbers by rubber test at a load of 500 gf.

Fabrication and Characterization of Cu-based Amorphous Coatings by Cold Spray Process (저온 분사를 이용한 Cu계 비정질 코팅층의 제조 및 특성 연구)

  • Jung, Dong-jin;Park, Dong-Yong;Lee, Jin Kyu;Kim, Hyung Jun;Lee, Kee-Ahn
    • Korean Journal of Metals and Materials
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    • v.46 no.5
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    • pp.321-327
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    • 2008
  • Cu based amorphous ($Cu_{54}Zr_{22}Ti_{18}Ni_6$) coating was produced by cold spraying as a new fabrication process. The microstructure and macroscopic properties of amorphous coating layer was investigated and compared with those of cold sprayed pure Cu coating. Amorphous powders were prepared by gas atomization and Al 6061 was used as the substrate plate. X-ray diffraction results showed that Cu based amorphous powder could be successfully deposited by cold spraying without any crystallization. The Cu based amorphous coating layer ($300{\sim}400{\mu}m$ thickness) contained 4.87% porosity. The hardness of Cu based amorphous coating represented $412.8H_v$, which was correspond to 68% of the hardness of injection casted bulk amorphous material. The wear resistance of Cu based amorphous coating was found to be three times higher than that of pure Cu coating. The 3-point bending test results showed that the adhesion strength of Cu based amorphous coating layer was higher than that pure Cu coating. It was also observed that hard Cu base amorphous particle could easily deform soft substrate by particle collisions and thus generated strong adhesion between coating and substrate. However, the amorphous coating layer unexpectedly represented lower corrosion resistance than pure Cu coating, which might be resulted from the higher content of porosity in the cold sprayed amorphous coating.

Studies of Physicochemical Properties of Baby Powder Developed from Rice-flour (쌀 분말을 이용한 유아용 파우더의 이화학적 특성 연구)

  • Han, Sang-Ik;Jang, Ki Chang;Seo, Woo Duck;Oh, Seong-Hwan;Ra, Ji-Eun;Song, Yu-Cheon;Lee, Jong-Hee;Kim, Byung-Joo;Nam, Min-Hee;Lee, Jin-Tae
    • Journal of Life Science
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    • v.23 no.7
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    • pp.879-885
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    • 2013
  • Baby powder is an astringent powder used to prevent diaper rash. It also has other cosmetic uses. In general, it is composed of talc powder (talcum powder). Talc powder is harmful if inhaled because it can cause significant lung damage. With the aim of developing a new rice-based baby powder, three kinds of rice varieties were selected and pulverized. To determine the cost-effectiveness of the different states of rice powder, several milling processes were tried, and the powder characteristics of the resulting rice powder, such as particle size, biological activities, digitalized color value, and moisture content before and after coating treatment with essential oil and silicon oil, were examined. "Goami" showed good flour characteristics with respect to lightness (92.0, $L^*$[D65] value) and particle size ($8.9{\mu}m$). SEM analysis showed that the rice powder particles coated in the essential oil and silicon oil showed a smoother and rounder appearance than those of the talc powder. In addition, the average particle size was decreased by the essential oil and silicon oil coating. The silicon oil coating solved the problem of moisture absorption in rice flour. Rice flour properly coated with essential oil and silicon oil shows great potential as a new material source of powder.

Characteristic Analysis of Functional Nano-coating Films Synthesized according to the Annealing Ambient and Fabrication of Anti-pollution PV Module (기능성 나노코팅 박막의 열처리 분위기에 따른 특성분석 및 오염방지 태양광 모듈제작)

  • Kang, Hyunil;Shin, Seung Kwon;Kim, Hyungchul;Lim, Yonnsik;Yoo, Youngsik;Joung, Yeun-Ho;Kim, Junghyun;Choi, Won Seok
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.64 no.3
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    • pp.182-186
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    • 2015
  • We investigated that effects of annealing ambient on the characteristics of functional nano thin film synthesized on glass substrate. The functional nano thin films were annealed by using rapid thermal annealing (RTA) equipment in vacuum, oxygen and nitrogen ambient, respectively. The hardness of the functional nano thin films were measured by a standard hardness testing method (ASTM D3363) such as a H-9H, F, HB and B-6B pencil (Mitsubishi, Japan). Also, the adhesion of the functional nano thin films were measured by a standard adhesion testing method (ASTM D3359) using scotch tape (3M, Korea). The contact angle of the functional nano thin films was measured by a contact angle analyzer (Phoenix 300 Touch, S.E.O.). The optical property of functional nano thin films was measured via UV-visible spectroscopy (S-3100, Scinco).

Preparation of TiO2-SiO2 Organic-Inorganic Hybrid Coating Material by Sol-gel Method and Evaluation of Corrosion Characteristics (졸-겔법에 의한 유·무기 TiO2-SiO2 혼성(Hybrid)코팅재료의 제조 및 부식 특성 평가)

  • Noh, J.J.;Maeng, W.Y.
    • Corrosion Science and Technology
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    • v.14 no.2
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    • pp.64-75
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    • 2015
  • Single $TiO_2$ coating prepared by sol-gel process usually experiences cracks in coating layer. In order to prevent cracks, an inorganic-organic hybrid $TiO_2-SiO_2$ coating was synthesized by combining precursors with an organic functional group. Five different coatings with various ratios of (1:8, 1:4, 1:1, 1:0.25 and 1:0.125) titanium alkoxide (TBOT, Tetrabutylorthotitanate) to organo-alkoxysilane (MAPTS, ${\gamma}$-Methacryloxy propyltrimethoxysilane) on carbon steel substrate were made by sol-gel dip coating. The prepared coatings were analyzed to study the coating properties (surface crack, thickness, composition) by scanning electron microscope (SEM), focused ion beam (FIB), and Fourier transform infrared spectroscopy (FT-IR). Potentiodynamic polarization tests and electrochemical impedance spectroscopy (EIS) were also performed to evaluate the corrosion characteristics of the coatings. Crack free $TiO_2-SiO_2$ hybrid coatings were prepared with the optimization of the ratio of TBOT to MAPTS. The corrosion rates were significantly decreased in the coatings for the optimized precursor ratio without cracks.