• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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• pp.382-382
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• 2009

In this study, we prepared electrodes containing ionic liquid for high temperature polymer electrolyte fuel cells. Effects of ILs on electrochemical properties of the electrodes were investigated carrying out measurement of cyclic voltammograms of the various electrodes with the content of IL in a strong supporting electrolyte. As the ILs content increased in electrodes, electrochemical surface area(ESA) decreased due to the leakage of ILs from Nafion ionomer. In addition, two case of cyclic voltammograms under two simulated environment, i.e. IL leakage from Nafion ionomer in I) electrode and ii) polymer electrolyte, were investigated. As a result, IL leakage from polymer electrolyte showed worse results in electrochemical properties of the electrode.

• 대한기계학회논문집B
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• 제31권3호
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• pp.234-241
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• 2007

The regulations for hydrocarbon emission from vehicles have become much more stringent in recent years. These more stringent regulations request vehicle manufacturers to develop the advanced exhaust system for reducing exhaust emissions. The exhaust emissions has many sources in vehicle. In order to investigate the characteristics of hydrocarbon(HC) in the exhaust manifold, concentrations of individual HC species were measured in exhaust process. Using sampling valve, the light hydrocarbon emissions were captured in the exhaust manifold(catalyst before and after) and analyzed from LPLi engine exhaust manifold(catalyst before and after) using different fuel properties. Then exhaust samples were measured by gas chromatography(GC) and exhaust gas analyzer. Catalyst conversion efficiency for fuel properties of Butane 100% was better than Propane 100%. Start delay of LPLi engine was observed as increment of propane contents in LPG fuels.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 추계학술대회 논문집
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• pp.172-175
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• 2009

A bipolar plate is an important component in a fuel cell in the sense of cost and weight. This study aimed at developing highly conductive, lightweight, and low cost bipolar plates. Hybrid carbons filled poly(phenylene sulfide)(PPS) composite bipolar plates were prepared by using the compression molding technique. Various types and amounts of conducting carbon fillers such as graphite, carbon black, carbon fibers, and carbon nanotubes (CNTs) were adopted for the composites. Electrical conductivity and mechanical properties of the composites were measured in order to investigate effects of each components of fillers. When the graphite is only used as a conducting filler, the electrical conductivity of the composites increases with increasing the content, but the flexural strength decreases dramatically. However, for CNTs and carbon fibers, the flexural strength initially increases and then decreases with increasing the amount of the conducting fillers. The amount of graphite corresponding to the peak of flexural strength was moved to lower content with increasing the amount of CNTs or carbon fiber. When hybrid conducting fillers such as fibrous and particulate fillers were used, the synergy effect in mechanical and electrical properties was observed.

• 한국세라믹학회지
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• 제42권12호
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• pp.816-820
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• 2005

The doped-ceria is a strong candidate material for an intermediate temperature SOFC. However, the mechanical strength and the magnitude of electrical conductivity need to be increased at low sintering temperature. In this study, to improve both properties, $1at\% $ of Mg, Ca, Cr, Fe, Co, Ni, Cu, Ga, and Zr were added to the GDC20 ($20at\%$ Gd-doped Ceria) and sintered at $1350^{\circ}C$ that is $250^{\circ}C$ lower than $1600^{\circ}C$. With addition, the relative density of the sintered sample increased. Fe, Co, Ni, Cu, Ga doped-GDC20 showed high relative density over $92\%$. Among them, Ga doped-GDC20 showed the most improved sinterability. The conductivity of doped­GDC20 increased by $\~10$ times at $300\~700^{\circ}C$.

• 한국재료학회지
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• 제18권5호
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• pp.259-265
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• 2008

The corrosion and degradation factors of a current collector in a molten carbonate fuel cell (MCFC) were investigated to determine the optimized coating thickness of nickel on STS316L. The results show that the surface morphology and electrical properties depended on the nickel coating thickness. The surface morphology gradually changed from a flat to a porous structure along as the nickel coating thickness decreased, and the electrical resistance of the nickel-coated STS316L increased as the nickel coating thickness decreased. This can be attributed to the diffusion of elements of Fe and Cr from the substrate through the nickel grain boundaries. Additionally, carburization in the metal grains or grain boundaries in an anodic environment was found to influence the electrical properties due to matrix distortion. The resistance of Cr-oxide layers formed in an anodic environment causes a drop in the potential, resulting in a decrease in the system efficiency.

• Korean Membrane Journal
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• 제5권1호
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• pp.18-24
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• 2003

In order to improve the mechanical properties of the sulfonated polysulfone (SPSf) membranes previously synthesized in our laboratory, poly(vinyl alcohol) (PVA) was blended which is well known as the excellent physical and chemical properties. The resulting membranes blended with several molecular weight of PVA varying from 13,000 to 124,000 have been characterized to investigate the effect of PVA molecular weight in terms of ion conductivities, methanol permeabilities, water contents and ion exchange capacities for both heat treated and untreated membranes at 150$^{\circ}C$. The proton conductivity is decreased as the molecular weight of PVA increases. The plain SPSf-6.0 showed the proton conductivity of 0.078 S/cm whereas the blended membrane with M.W. 31,000 PVA indicated 0.04 S/cm. For methanol permeabilities, when PVA is added to SPAf-6.0, methanol crossover is increased because of the gain of the hydrophilicity from 3.4 to 6.5${\times}$10$\^$-6/ $\textrm{cm}^2$/s. For the annealed blended membranes (with M.W. 31,000 PVA), both the methanol corssover and proton conductivity showed very consistent values, about 2.3${\times}$10$\^$-6/ $\textrm{cm}^2$/s and 0.036 S/cm, respectively.

• Journal of Electrochemical Science and Technology
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• 제7권4호
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• pp.316-326
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• 2016

Development and discovery of efficient, cost-effective, and robust electrocatalysts are imperative for practical and widespread implementation of water electrolysis and fuel cell techniques in the anticipated hydrogen economy. The electrochemical reactions involved in water electrolysis, i.e., hydrogen and oxygen evolution reactions, are complex inner-sphere reactions with slow multi-electron transfer kinetics. To develop active electrocatalysts for water electrolysis, the physicochemical properties of the electrode surfaces in electrolyte solutions should be investigated and understood in detail. When electrocatalysis is conducted using nanoparticles with large surface areas and active surface states, analytical techniques with sub-nanometer resolution are required, along with material development. Scanning electrochemical microscopy (SECM) is an electrochemical technique for studying the surface reactions and properties of various types of electrodes using a very small tip electrode. Recently, the morphological and chemical characteristics of single nanoparticles and bio-enzymes for catalytic reactions were studied with nanometer resolution by combining SECM with atomic force microscopy (AFM). Herein, SECM techniques are briefly reviewed, including the AFM-SECM technique, to facilitate further development and discovery of highly active, cost-effective, and robust electrode materials for efficient electrolysis and photolysis.

• 소성∙가공
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• 제23권3호
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• pp.171-177
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• 2014

The current collector for the molten carbonate fuel cell (MCFC) which has sheared protrusions is manufactured by the three-stage forming process that integrates slitting, preforming and final forming. Due to the repetition of sheared protrusions, an effective simulation method is required to predict the mechanical behavior. In the current study, a sheet with sheared protrusions was assumed to be an orthotropic plate, which has the same length, width and height. FEM simulations were conducted to evaluate the homogenized properties of the current collector, which has 4 (longitudinal direction) x 4 (transverse direction) sheared protrusions. The simulation model was constructed using hexahedral mesh coarsening. From the verification examples, it was found that the proposed simulation method was efficient within reasonable accuracy. The calculated homogenized properties can be applied to the design of a stack for molten carbonate fuel cells and the prediction of mechanical behavior for other applications.

• 대한금속재료학회지
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• 제50권2호
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• pp.171-175
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• 2012

By measuring the absorbed hydrogen quantity as a function of the number of cycles, the cycling properties of the Mg-15 wt%Ni-5 wt%$Fe_2O_3$ alloy were investigated. The absorbed hydrogen quantity decreased as the number of cycles increased. The $H_a$ value varied almost linearly with the number of cycles. The maintainability of absorbed hydrogen quantity at n=100 was 89.0% for the hydriding reaction time of 10 min. After the $150^{th}$ hydriding-dehydriding cycle, Mg, $Mg_2Ni$, $Mg(OH)_2$, MgO, and Fe were observed. The phases were analyzed by Rietveld analysis from the XRD patterns of the Mg-15 wt%Ni-5 wt%$Fe_2O_3$ alloy after 150 hydriding-dehydriding cycles. The crystallite size and strain of Mg were then estimated with the Williamson-Hall technique.

• 한국수소및신에너지학회논문집
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• 제30권2호
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• pp.128-135
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• 2019

In this study, the mesoporous $SiO_2$ (5, 10, or 15 wt%) was incorporated into the polybenzimidazole matrix in order to improve the proton conduction as well as physiochemical properties of composite membrane. The chemical structure of mesoporous $SiO_2$ and crystallinity of as-prepared membranes were analyzed by Fourier-transform infrared (FT-IR) spectroscopy and X-ray diffraction (XRD) analysis, respectively. The thermal stability of the pristine $X_1Y_9$ and composite membranes were evaluated by thermogravimetric analyzer (TGA). On other side, the physical and chemical properties of the pristine $X_1Y_9$ and composite membranes were also determined by acid uptake and oxidative stability tests, respectively. With the incorporation of 15 wt% $SiO_2$, the composite membrane exhibits the higher proton conductivity that may be applicable for non-humidified high temperature fuel cell applications.