• Title/Summary/Keyword: frequency shifts

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Reaction Monitoring of Imine Synthesis Using Raman Spectroscopy

  • Lee, Moon-Kwon;Kim, Hye-Sung;Rhee, Hak-June;Choo, Jae-Bum
    • Bulletin of the Korean Chemical Society
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    • v.24 no.2
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    • pp.205-208
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    • 2003
  • Laser-induced Raman spectroscopy has been utilized to demonstrate its feasibility for studying the kinetics of imine formation in chloroform solvent. The imine formation, by the nucleophilic addition of primary amine to the carbonyl group of ketone, has been monitored at ten minute intervals for eight hours. The intensity of the C=O stretching mode at 1684 $cm^{-1}$ was measured to determine the rate constant of the reaction. In order to correct the sample-to-sample fluctuations in Raman peak area, this peak was normalized to the C-Cl bending peak at 666 $cm^{-1}$. By the peak area change during the course of reaction, the second order rates at three different temperatures have been determined. The substituent effects on the π conjugations of imine product have also been investigated. On the basis of Raman frequency shifts, the delocalization properties of the aromatic system modified by substitution of a hydrogen atom with -Cl and $-CH_3O$ groups could be clearly understood.

Dynamic stability of nanocomposite Mindlin pipes conveying pulsating fluid flow subjected to magnetic field

  • Esmaeili, Hemat Ali;Khaki, Mehran;Abbasi, Morteza
    • Structural Engineering and Mechanics
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    • v.67 no.1
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    • pp.21-31
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    • 2018
  • In this work, the dynamic stability of carbon nanotubes (CNTs) reinforced composite pipes conveying pulsating fluid flow is investigated. The pipe is surrounded by viscoelastic medium containing spring, shear and damper coefficients. Due to the existence of CNTs, the pipe is subjected to a 2D magnetic field. The radial induced force by pulsating fluid is obtained by the Navier-Stokes equation. The equivalent characteristics of the nanocomposite structure are calculated using Mori-Tanaka model. Based on first order shear deformation theory (FSDT) or Mindlin theory, energy method and Hamilton's principle, the motion equations are derived. Using harmonic differential quadrature method (HDQM) in conjunction with the Bolotin's method, the dynamic instability region (DIR) of the system is calculated. The effects of different parameters such as volume fraction of CNTs, magnetic field, boundary conditions, fluid velocity and geometrical parameters of pipe are shown on the DIR of the structure. Results show that with increasing volume fraction of CNTs, the DIR shifts to the higher frequency. In addition, the DIR of the structure will be happened at lower excitation frequencies with increasing the fluid velocity.

A Level Shifter Using Aluminum-Doped Zinc Tin Oxide Thin Film Transistors with Negative Threshold Voltages

  • Hwang, Tong-Hun;Yang, Ik-Seok;Kim, Kang-Nam;Cho, Doo-Hee;KoPark, Sang-Hee;Hwang, Chi-Sun;Byun, Chun-Won;Kwon, Oh-Kyong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.464-465
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    • 2009
  • A new level shifter using n-channel aluminum-doped zinc tin oxide (AZTO) thin film transistors (TFTs) was proposed to integrate driving circuits on qVGA panels for mobile display applications. The circuit used positive feedback loop to overcome limitations of circuits designed with oxide TFTs which is depletion mode n-channel TFTs. The measured results shows that the proposed circuit shifts 10 V input voltage to 20 V output voltage and its power consumption is 0.46 mW when the supply voltage is 20 V and the operating frequency is 10 kHz.

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Fatigue Patterns on Trunk Muscles at Various Asymmetric Twisting Conditions (비틀림 동작에서의 허리근육의 피로도 패턴)

  • Jo, Yeong-Jin;Kim, Jeong-Ryong
    • Journal of the Ergonomics Society of Korea
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    • v.20 no.2
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    • pp.71-82
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    • 2001
  • Twisting posture in lifting tasks has been identified as a risk factor of low back pain. However, it has been usually estimated in terms of compressive stress or muscular activity. Thus, this study was conducted to predict the influence on muscular fatigue during lifting simulation. Fifteen young and healthy subjects were recruited and performed isometric trunk exertions during upright standing, two-level flexions and five-level asymmetric twisting conditions. EMG signals from five primary trunk muscles in right part of body were collected during 20sec for 45 different lifting conditions. RMS(root mean square) and MPF(mean power frequency) parameters were used to analyze the EMG signals. Twisting postures were significant in right erector spinae(ERSR), right latissimus dorsi(LATR), right internal oblique(INOR) for muscular activities. Especially, when trunk was $30^{\circ}$ CCW twisting posture. ERSR and INOR activities increased respectively by 11% and 3%. Regarding the trunk muscle fatigue, we found that MPF shifts in twisting posture increased 2.3 and 2.6 times for ERSR and INOR muscles respectively. Therefore, It is probable for workers to suffer from low back disorders when they were exposed to a extreme twisting posture during prolonged lifting. This study suggests NIOSH(National Institute for Occupational Safety and Health) lifting equation needs the time-duration multiplier in addition to asymmetric multiplier.

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The characteristics of terahertz electromagnetic pulses by electrical and optical parameters. (전기적 광학적 변화가 테라헤르츠 전자기 펄스의 모양에 미치는 영향)

  • 전태인
    • Korean Journal of Optics and Photonics
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    • v.12 no.6
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    • pp.503-506
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    • 2001
  • When DC voltages from 5 V up to 90 V are applied to a transmitter chip excited by an ultrafast lacer beam, the terahertz electromagnetic pulses and their spectra are changed. The spectrum shifts to the high frequency range when the high DC voltage is applied to the chip. At that time, the signal-to-noise ratio is increased from 250: 1 to 10,000: 1. The spectrum can expand up to 4 THz by optimal realignment of the THz system. Also, two terahertz electromagnetic pulses are generated from a receiver chip when the laser detection beam is reflected to the back side of the chip.

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Monitoring of Strength Gain in Concrete Using Smart PZT Transducers

  • Qureshi, Adeel Riaz;Shin, Sung-Woo;Yun, Chung-Bang
    • Journal of the Korean Society for Nondestructive Testing
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    • v.27 no.6
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    • pp.501-508
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    • 2007
  • This paper presents the feasibility of using electromechanical impedance based active sensing technique for nondestructive strength gain monitoring of early-age concrete by employing piezoelectric lead-zirconate-titanate (PZT) patches on concrete surface. The strength development of early age concrete is actively monitored by performing a series of experiments on concrete specimens under moist curing condition. The electrical admittance signatures are acquired for five different curing ages and compared with each other. The resonant frequency shifts of PZT patches with increasing days is observed which is on account of additional stiffening due to strength gain of concrete during curing and level of stiffening being related to strength obtained from compression tests on companion cylinder specimens. The proposed approach is found to be suitable for monitoring the development of compressive strength in early-age concrete. It is also observed in this study that root mean square deviation (RMSD) in admittance signatures of the PZT patches can also be used as an indicator of concrete strength development.

Output Characteristics of the PMS-PZT Piezoelectric Transformer Driving High Power Amplifier (PMS-PZT를 이용한 압전 변압기의 하이파워 시 출력 특성)

  • Kim, Dong-Soo;Kim, Young-Deog;Kim, Kwang-Il;Sohn, Joon-Ho;Nam, Hyo-Duk
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.830-833
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    • 2004
  • Voltage step-down characteristics of Ring/Dot type piezoelectric transformer were examined with increasing input voltage from $10\;V_{pp}$ to $140V_{pp}$. Then the output load resistance was fixed to $125\;\Omega$. The voltage gain showed constant value till the input voltage of $70\;V_{pp}$. And then it linearly decreased till the input voltage of $140V_{pp}$. The output voltage of fabricated piezoelectric transformer increased with increasing input voltage. And driving frequencies when the output voltage was maximum value were changed according to input voltage. Frequency shifts and temperature rise of fabricated sample showed 2 kHz, $13^{\circ}C$, respectively when input voltage was changed from $10\;V_{pp}$ to $140V_{pp}$. Because of the temperature rise of fabricated piezoelectric transformer, the step-down characteristics of it was deteriorated above the input voltage of $70\;V_{pp}$.

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Non-stationary vibration and super-harmonic resonances of nonlinear viscoelastic nano-resonators

  • Ajri, Masoud;Rastgoo, Abbas;Fakhrabadi, Mir Masoud Seyyed
    • Structural Engineering and Mechanics
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    • v.70 no.5
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    • pp.623-637
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    • 2019
  • This paper analyzes the non-stationary vibration and super-harmonic resonances in nonlinear dynamic motion of viscoelastic nano-resonators. For this purpose, a new coupled size-dependent model is developed for a plate-shape nano-resonator made of nonlinear viscoelastic material based on modified coupled stress theory. The virtual work induced by viscous forces obtained in the framework of the Leaderman integral for the size-independent and size-dependent stress tensors. With incorporating the size-dependent potential energy, kinetic energy, and an external excitation force work based on Hamilton's principle, the viscous work equation is balanced. The resulting size-dependent viscoelastically coupled equations are solved using the expansion theory, Galerkin method and the fourth-order Runge-Kutta technique. The Hilbert-Huang transform is performed to examine the effects of the viscoelastic parameter and initial excitation values on the nanosystem free vibration. Furthermore, the secondary resonance due to the super-harmonic motions are examined in the form of frequency response, force response, Poincare map, phase portrait and fast Fourier transforms. The results show that the vibration of viscoelastic nanosystem is non-stationary at higher excitation values unlike the elastic ones. In addition, ignoring the small-size effects shifts the secondary resonance, significantly.

Moderating and Mediating Effects of Resilience in the Relationship between Work Intensity, Interpersonal Conflict and Burnout among Nurses (간호사의 업무 강도, 대인관계 갈등과 소진의 관계에서 회복탄력성의 조절 및 매개 효과)

  • Baek, Yun Mi;Kim, Souk Young
    • Journal of Korean Clinical Nursing Research
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    • v.26 no.3
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    • pp.275-284
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    • 2020
  • Purpose: For this study the moderating and mediating effects of resilience on the relationships between work intensity, conflicts in interpersonal relationship and nurses' burnout were investigated. Methods: In this descriptive research 227 nurses who consented to participate in the study were surveyed. The tool included nurses' objective work intensity, subjective work intensity, conflicts in interpersonal relationships, resilience, and burnout. Data were collected from nurses in general hospitals in D city from July to August 2017. Collected data were analyzed using SPSS 23.0 program. Results: Participants' burnout showed a statistically significant difference according to age, marital status, total clinical experience, position, work pattern, frequency of night shifts, work department, and salary. Participants' burnout was significantly positively correlated with subjective work intensity and conflicts in interpersonal relationships, and significantly negatively correlated with resilience. Resilience moderated the relationship between participants' subjective work intensity and burnout, and mediated the relationship between conflicts in interpersonal relationships and burnout. Conclusion: Resilience had a moderating effect on the relationship between subjective work intensity and burnout, and a mediating effect on the relationship between conflicts in interpersonal relationships and burnout. Therefore, further efforts and diverse intervention measures are required to enhance resilience and reduce work intensity and conflicts in interpersonal relationships in order to prevent burnout in nurses.

Coherence Analysis of Jaw and Neck Muscle Coordination during Chewing in Healthy Adults

  • Ho-Jun Song;Sang-Ho Han;Ji-Yeon Kim;Yeong-Gwan Im
    • Journal of Oral Medicine and Pain
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    • v.48 no.4
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    • pp.159-168
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    • 2023
  • Purpose: Coordinated activity between the jaw and neck muscles is important in oral motor tasks such as chewing. This study examined coherence between the jaw and neck muscles during chewing in healthy adults. Methods: A total of 12 healthy adults underwent electromyography (EMG) of the jaw and neck muscles during right-sided chewing at a frequency of 1 Hz. Surface electrodes were placed over the temporalis (TA), masseter (MS), anterior digastric (DA), and sternocleidomastoid (SM) muscles on the right side. EMG signals were processed for coherence and phase analysis using advanced signal processing techniques. Results: The MS and TA muscle pair exhibited high synchronization when chewing (median coherence=0.992). Contrarily, the coherence values between the MS and DA, as well as the MS and SM muscle pairs, were relatively low (median coherence=0.848 and 0.957, respectively). Phase analysis revealed minimal temporal differences between the MS and TA muscle pair and the MS and SM muscle pair, whereas substantial phase shifts were observed between the MS and DA muscle pair. Conclusions: During chewing in healthy adults, the TA muscle works synergistically whereas the DA muscle antagonistically with the MS muscle, and the SM muscle supports the activity of the MS muscle. The observed synchrony and coordination provide insights into the intricate interplay among these muscles during oral motor tasks.