• Proceedings of the Korea Water Resources Association Conference
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• 2007.05a
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• pp.46-52
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• 2007

As flue gas desulfurization (FGD) wastewater contains high concentrations of nitrate and is very low in organic carbon, the feasibility of nitrate removal by autotrophic denitrification using Thiobacillus denitrificans was studied. This autotrophic bacteria oxidizes elemental sulfur to sulfate while reducing nitrate to elemental nitrogen gas, thereby eliminating the need for addition of organic compounds such as methanol. Owing to the unusually high concentrations of dissolved salts $(Ca^{2+},\;Mg^{2+},\;Na^+,\;K^+,\;B^+,\;SO_4^{2-},\;Cl^-,\;F^-,)$ in the FGD wastewater, extensive laboratory-scale and pilot-scale tests were carried out in sulfur-limestone reactors (1) to determine the effect of salinity on autotrophic denitrification, (2) to evaluate the use of limestone for pH control and as source of inorganic carbon for microbial growth, and, (3) to find the optimum environmental and operational conditions for autotrophic denitrification of FGD wastewater. The experimental results demonstrated that (1) autotrophic denitrification is not inhibited up to 1.8 mol total dissolved salt content; (2) inorganic carbon and inorganic phosphorus must be present in sufficiently high concentrations; (3) limestone can supply effective buffering capacity and inorganic carbon; (4) the high calcium concentration may interfere with pH control, phosphorus solubility and limestone dissolution, hence requiring pretreatment of the FGD wastewater; and, 5) under optimum conditions, complete autotrophic denitrification of FGD wastewater was obtained in a sulfur-limestone packed bed reactor with a sulfur:limestone volume ratio of 2:1 for volumetric loading rates up to 400g $NO_{3^-}N/m^3.d$. The interesting interactions between autotrophic denitrification, pH, alkalinity, and the unusually high calcium and boron content of the FGD wastewater are highlighted. The engineering significance of the results is discussed.

• Journal of environmental and Sanitary engineering
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• v.14 no.4
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• pp.69-76
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• 1999

This research was carried but to investigate the characteristics of mist removal with the change of operating conditions in the plasma reactor of impulse streamer corona based on the distribution of particle size measured by laser diffraction spectrometers. The operating conditions in this experiment were power of impulse streamer corona, gas velocity, collection time, and SOx/NOx concentration. The collection efficiency T(d) was estimated by distribution of particle size in the collection zone through the advanced model.

• 한국연소학회:학술대회논문집
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• 2013.06a
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• pp.9-10
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• 2013

This study reports the results of an experimental investigation of emission and temperatures from the syngas-air premixed flame with a various mixture composition in the region of large equivalence ratios. The effects of hydrogen contents and equivalence ratios on the flame velocity, which reported before, and emission of syngas fuel are examined. In this study, representative syngas mixture compositions ($H_2:CO$) such as $H_2:CO=10:90$, 25:75, 50:50 and 75:25 and equivalence ratios from 0.5 to 5.0 have been conducted. The emissions of syngas fuel were measured by the high precision analyzer with enclosure configuration and the adiabatic temperatures are calculated by used Chemkin basis. The NOx emission level is coincided relatively well with the adiabatic temperature distributions in lean mixture conditions, but for rich mixture conditions NOx level was also increased again even though the adiabatic temperature decreases. Such an increasing characteristics in rich mixture conditions is coincided well with the tendency that rather the flue gas temperature increases.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.125.1-125.1
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• 2011

$CO_2$ separation from a flue gas by using the gas hydrate technology was suggested by Kang et al. They reported phase equilibrium conditions of mixed gases composed of $CO_2$ and N2 with THF as a thermodynamic promoter. In this study, we reported the phase equilibrium conditions of a mixed gas which had a realistic composition of the blast furnace gas (BFG) emitted from the steel-making process. The phase equilibrium measurements were done by using the "continuous" QCM method, and the results demonstrate that this method is efficient and as accurate as the conventional temperature search method.

• Journal of the Korean Society of Combustion
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• v.12 no.4
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• pp.22-30
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• 2007

The NOx emission characteristics were studied in an oscillating combustion burner equipped with a specially designed proportioning valve. The effects of various parameters on the NOx emission which are important in oscillating combustion were investigated. Also, the effects of coincident application of flue gas recirculation(FGR) were evaluated. The results show that oscillating combustion is an efficient tool for reducing NOx in the burner. Up to 53% of NOx reduction could be acquired in low frequency and small duty ratio conditions. The coincident application of FGR further reduced the NOx emission up to 74%. Thus, this study assured that oscillating combustion technology with FGR could be a fascinating method for NOx reduction in industrial burners.

• 연구논문집
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• s.23
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• pp.93-107
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• 1993

The chemistry and performance characteristics of the EBDS process have been introduced, in which experimental results from laboratory, test plant, and pilot plant studies agree very well and can be understood from detailed kinetic models. The parametric dependencies of the NOx and $SO_2$, removal yields on the input conditions have been discussed and formulated quantitatively. The process is best suited for flue gas with high $SO_2$, loadings. The operation conditions, such as dose, ammonia, and water additions, can be adjusted fast upon load changes. The process works waste water free and the major product is a mixture of ammonium nitrate and sulfate that can be used as fertilizer. The up-date results show that the EBDS technology is safe and competitive with other already well-established technologies. Due to these interesting features, the electron beam process has gained much international recognition. Demonstration units of 100MW have been proposed in the United States and Japan. Further pilot plants are under construction in Poland and China, countries that make abundant use of highsulfur coal. Additional research activities are under way to further improve the energy efficiency of process, and accelerator prices have been decreasing during the past 10 years. So the EBDS process has a good chance to start a new generation of emission-control technology.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.12
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• pp.2247-2254
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• 2000

This study was carried out to investigate the reaction characteristics of NOx with reagents to grope the power consumption rate reduction and NOx removal rate improvement for the non-thermal plasma denitrification process. The experiments were performed using the real flue gas and wire-plate type plasma reactor. and the flow rate of real flue gas is $20Nm^3/hr$. Paraffinic and olefinic hydrocarbons and ammonia were used as reagents. Olefinic hydrocarbon oxidizes NO more actively than paraffinic hydrocarbon under the non-thermal plasma conditions, resulting in the generation of large amount of $NO_2$ and a very small amount of CO. When the initial NOx concentration increases. oxidation rate of NO decreases and the consumption rate of olefinic hydrocarbon increases significantly. On the other hand. $NH_3$ did not promote reduction reaction with NO under non-thermal plasma conditions. however, there was a tendency that the NHa was effective to remove the $NO_2$ oxidized by olefinic hydrocarbon.

• 한국연소학회:학술대회논문집
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• 2001.06a
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• pp.82-89
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• 2001

This paper concerns lean gas cyclone combustion system adopting distributed inlets with different velocity to promote ignition and burnout properties. Detailed temperature measurements have been achieved under different operating conditions and flue gas compositions and NOx have been measured. Experimental results show that cyclone combustor provided increasing combustion stability and reduction NOx emission level to negligible level.

• Proceedings of the KSME Conference
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• 2001.06d
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• pp.79-84
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• 2001

The effect of spray characteristics on desulfurization yield was evaluated by performing experiments with pilot spray drying sorber (SDS). Among the variables of operating conditions, the slurry-spraying conditions were chosen as major parameters; Stoichiometric ratio and Sauter mean diameter of slurry droplet were varied for the different gas temperatures and $SO_{2}$ concentrations in the inlet gas flow. From the experimental results, we proposed semi-empirical models of desulfurization yield for both Stoichiometric ratio and Sauter mean diameter of droplets. The optimal condition of spray can be determined based on these results, which might be applied to the design or scale-up of SDS systems.

• Journal of the Korean Society for Precision Engineering
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• v.29 no.11
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• pp.1178-1182
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• 2012

The organic linings at flue gas desulfurization systems (FGD system) in power plant have the excellent chemical properties but, lose the anticorrosive properties according to the aging with environment conditions. The properties of the organic linings depend on the manufacturing company. Therefore, the basic properties of organic linings for the preestimate of life time should be examined by conducting the aging and the bond strength test according to temperature. The pre-aging samples were compared with the post-aging samples. The temperature conditions of the aging process were 70, 150 and $200^{\circ}C$. The bond strength was calculated and the cross sections of fracture surface were examined by optical microscope and SEM. The $T_g$ was examined by DSC, DTA and TGA.