• 제목/요약/키워드: flat membrane

검색결과 176건 처리시간 0.025초

고체 슈퍼캐퍼시터를 위한 폴리비닐알콜 고분자 전해질막 (Poly(vinyl alcohol)-based Polymer Electrolyte Membrane for Solid-state Supercapacitor)

  • 이재훈;박철훈;박민수;김종학
    • 멤브레인
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    • 제29권1호
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    • pp.30-36
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    • 2019
  • 본 연구에서는 titanium nitride (TiN) 나노 섬유와 poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT-PSS) 전도성 고분자로 이루어진 전극과 poly(vinyl alcohol) (PVA) 기반 고분자 전해질 분리막을 이용하여 슈퍼 캐퍼시터를 제조하였다. TiN 나노 섬유의 경우 높은 전기 전도도와 이차원적 구조로 인한 스케폴드 효과를 기대할 수 있다는 점에서 전극 물질로 사용되었다. PEDOT-PSS 전도성 고분자는 수소 이온과 산화-환원 반응을 통해 보다 높은 정전용량을 나타낼 수 있으며 용액상에 분산이 용이해 유무기 복합제를 형성하기에 적합하였다. PVA 기반의 고분자 전해질 분리막은 기존의 액상의 전해질의 문제인 외부 충격에 대한 안정성을 확보할 수 있으며 염으로 사용된 $H_3PO_4$의 경우 수소 이온은 빠른 확산으로 인해 캐퍼시터의 충방전 효율에 이점이 있다. 본 연구에서 보고된 PEDOT-PSS/TiN 슈퍼캐퍼시터의 정전용량은 약 75 F/g으로 기존의 탄소기반 캐퍼시터에 비해 큰 폭으로 증가한 값이다.

Comparative preclinical assessment of the use of dehydrated human amnion/chorion membrane to repair perforated sinus membranes

  • Chang, Yun-Young;Kim, Su-Hwan;Goh, Mi-Seon;Yun, Jeong-Ho
    • Journal of Periodontal and Implant Science
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    • 제49권5호
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    • pp.330-343
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    • 2019
  • Purpose: The aim of this study was to evaluate the use of dehydrated human amnion/chorion membrane (dHACM) to repair perforated sinus membranes in rabbits. Methods: Bilateral surgical windows (7.5-mm diameter) were prepared on the nasal bones of 14 rabbits. Standardized circular perforations (5-mm diameter) were made in the sinus membrane by manipulating implant twist drills. The perforated sinus membranes were repaired using dHACM or a resorbable collagen membrane (CM). The negative control (NC) group did not undergo perforated sinus membrane repair, while the positive control (PC) group underwent sinus augmentation without perforations. The same amount of deproteinized porcine bone mineral was grafted in all 4 groups. After 6 weeks, micro-computed tomography (micro-CT) and histomorphometric evaluations were conducted. Results: The micro-CT analysis revealed that the total augmented volume was not significantly different among the groups. In the dHACM group, newly formed bone filled the augmented area with remaining biomaterials; however, non-ciliated flat epithelium and inflammatory cells were observed on the healed sinus membrane. Histometric analysis showed that the percentage of newly formed bone area in the dHACM group did not differ significantly from that in the CM group. The dHACM group showed a significantly higher percentage of newly formed bone area than the NC group, but there was no significant difference between the dHACM and PC groups. Conclusions: dHACM could be a feasible solution for repairing sinus membrane perforations that occur during sinus floor augmentation.

Effect of post-treatment routes on the performance of PVDF-TEOS hollow fiber membranes

  • Shadia R. Tewfik;Mohamed H. Sorour;Hayam F. Shaalan;Heba A. Hani;Abdelghani G. Abulnour;Marwa M. El Sayed;Yomna O. Mostafa;Mahmoud A. Eltoukhy
    • Membrane and Water Treatment
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    • 제14권2호
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    • pp.85-93
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    • 2023
  • Membrane separation is widely used for several applications such as water treatment, membrane reactors and climate change. Cross-linked organic-inorganic hybrid polyvinylidene fluoride (PVDF) / Tetraethyl orthosilicate (TEOS) was adopted for the preparation of optimized hollow membrane (HFM) for membrane distillation or other low pressure separators for mechanical properties and permeability under varying pretreatment schemes. HFMs were prepared on semi-pilot membrane fabrication system. Novel adopted post-treatment schemes involved soaking in glycerol, magnesium sulphate (MgSO4), sodium hypochlorite (NaOCl), and isopropanol for different durations. All fibers were characterized for morphology using a scanning electron microscope (SEM), surface roughness using atomic force microscope (AFM), elemental composition by examining Energy Dispersive Spectroscopy (EDS), water contact angle (CA°) and porosity. The performance of the fibers was evaluated for pure water permeation flux (PWF). Post-treatment with MgSO4 gave the highest both tensile modulus and flux. Assessment of properties and performance revealed comparable results with other organic-inorganic separators, HF or flat. In spite of few reported data on post treatment using MgSO4 in presence of TEOS, this proves the potential of low cost treatment without negative impact on other membrane properties. The flux is also comparable with hypochlorite which manifests substantial precaution requirements in actual industrial use.The relatively high values of flux/bar for sample treated with TEOS, post treated with MgSO4 and hypochlorite are 88 and 82 LMH/bar respectively.

MBR 시스템에서의 금속필터 적용타당성 연구 (A Study on the Validity of the Metal Filter Application in MBR Process)

  • 이민수;이강훈;이용수;정건용
    • 멤브레인
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    • 제32권1호
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    • pp.66-73
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    • 2022
  • 본 연구에서는 stainless steel로 재질로 된 금속평막모듈을 이용하여 고플럭스가 유지되면서 처리수의 안정화 방안을 모색하였다. 이 모듈은 기공사이즈가 13 ㎛ 단위여서 플럭스가 60 LMH에서 100 LMH까지 고플럭스로 운전이 가능하다 그러나 SS가 초기 운전 시 30~50 ppm 정도 유출되지만 SS가 응집핵으로 작용하므로 응집이 가능하게 된다. 기존 고분자막 여과수는 응집핵이 없어서 coagulation은 되지만 floculation이 안되므로 추가적으로 응집보조제인 clay나 벤토나이트를 투여하게 되는데 본 연구에서는 이런 응집보조제 필요 없이 SS 누출만으로 floculation이 되므로 총인처리와 처리수질이 안정성을 도모하고자 하였다. 최종적으로 안정적인 처리수에 고플럭스가 가능한 Metal필터 운전이 MBR 시스템에서 적용가능한지 타당성을 연구하고자 하였다.

원통으로 보강된 평판의 응력해석 (Stress analysis near a circular hole in a flat plate reinforced by a cylinder)

  • 정인승;이대희;이완익;윤갑영
    • 대한기계학회논문집
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    • 제11권5호
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    • pp.800-809
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    • 1987
  • 본 연구에서는 원통에 대하여는 Donnel 식과 Flugge식을 사용하여 원통의 유 한길이에 대한 일반적인 해를 구하였고, 평판에 대하여는 막이론과 굽힘이론을 사용하 여 일반해를 구한 후 중첩하였다. 평판과 원통에 발생하는 미정력계를 구하기 위하 여 가장 합리적이라고 생각되는 접합부에 모든 미정력계가 집중하여 작용한다고 가정 하고, 이 부분에서 평판과 원통의 각각에 대한 하중, 모우멘트, 기울기, 변위 등이 연 속하도록 접한조건식을 세웠다.그리고 이론해석의 타당성을 알아보기 위하여 S 45C 강재로 플러시타잎의 모델을 제작하여 실험을 행하였다.

Parametric studies on punching shear behavior of RC flat slabs without shear reinforcement

  • Elsamak, Galal;Fayed, Sabry
    • Computers and Concrete
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    • 제25권4호
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    • pp.355-367
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    • 2020
  • This paper proposed a numerical investigation based on finite elements analysis (FEA) in order to study the punching shear behavior of reinforced concrete (RC) flat slabs using ABAQUS and SAP2000 programs. Firstly, the concrete and the steel reinforcements were modeled by hexahedral 3D solid and linear elements respectively, and the nonlinearity of the used materials was considered. In order to validate this model, experimental results considered in literature were compared with the proposed FE model. After validation, a parametric study was performed. The parameters include the slab thickness, the flexure reinforcement ratios and the axial membrane loads. Then, to reduce the time of FEA, a simplified modelling using 3D layered shell element and shear hinge concept was also induced. The effect of the footings settlement was studied using the proposed simplified nonlinear model as a case study. Results of numerical models showed that increase of the slab thickness by 185.7% enhanced the ultimate load by 439.1%, accompanied with a brittle punching failure. The punching failure occurred in one of the tested specimens when the tensile reinforcement ratio increased more than 0.65% and the punching capacity improved with increasing the horizontal flexural reinforcement; it decreased by 30% with the settlement of the outer footings.

적응적체눈세분화를 위한 변절점 평면 쉘 요소 (Variable-node-flat shell element for adaptive mesh refinement)

  • 최창근;이완훈
    • 한국전산구조공학회:학술대회논문집
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    • 한국전산구조공학회 1994년도 가을 학술발표회 논문집
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    • pp.1-8
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    • 1994
  • A variable-node-flat shell element designated as CLS which has variable mid-side nodes with drilling freedom has been presented in this paper. The shell element to be applied in finite element analysis has been developed by combining a membrane element named as CLM with drilling rotation d.o.f. and plate bending element. The combined shell element possess six degrees of freedom per node. By introducing the variable-node elements which have physical midside nodes, some difficulties associated with imposing displacement constraints on irregular nodes to enforce interelement compatibility in common adaptive h-refinement on quadrilateral mesh are easily overcome. Detailed numerical studies show the excellent performance of the new shell elements developed in this study.

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단섬유 보강 이방성 사출성형품의 휨 해석 (Warpage Analysis of Fiber Reinforced Injection Molded Parts)

  • 정성택;김진곤;구본흥
    • 대한기계학회논문집A
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    • 제24권8호
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    • pp.1968-1799
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    • 2000
  • A warpage analysis program has been developed for fiber-reinforced injection molded parts. The warpage is predicted from the residual stress and anisotropic thermo-mechanical properties coupled with fiber orientation in the integrated injection molding simulation. A simple elastic model is used for the calculation of thermally and pressure-induced residual stresses which are employed as the initial conditions in the structural analysis. To improve the reliability of warpage analysis, a new triangular flat shell element superimposing well-known efficient plate bending and membrane element is presented. The numerical examples address the necessity to use anisotropic models for fiber-reinforced materials and show that predicted warpage is in good agreement with experimentally measured one.

회전자유도를 갖는 평면쉘요소에 의한 박판구조물의 기하비선형해석 (Geometrical Nonlinear Analysis of Thin-walled Structures by Flat Shell Elements with Drilling D.O.F.)

  • 최창근;송명관
    • 한국전산구조공학회:학술대회논문집
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    • 한국전산구조공학회 1998년도 봄 학술발표회 논문집
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    • pp.317-324
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    • 1998
  • A nonlinear anile element formulation of flat shell elements with drilling d.o.f, is presented for the geometrical nonlinear analysis of thin-walled structures. The shell element to be applied in finite element analysis was developed by combining a membrane element named as CLM with drilling rotation d.o.f, and plate bending element. The combined shell element possesses six degrees of freedom per node. The element showed the excellent performance in the linear analysis of the folded plate structures, in which the normal rotational rigidity of folded plates is considered, therefore, using this element geometrical nonlinear analysis of those structures is fulfilled in this study. An incremental total Larangian approach is adopted through out in which displacements are referred to the original configuration. Comparing the results with those of other researches shows the performance of this element and a folded plate structure is analyzed as an example.

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PVdF 나노섬유 나권형 정밀여과와 입상 활성탄의 혼성 수처리에서 활성탄 충진량의 영향 (Effect of GAC Packing Mass in Hybrid Water Treatment Process of PVdF Nanofibers Spiral Wound Microfiltration and Granular Activated Carbon)

  • 경규명;박진용
    • 멤브레인
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    • 제27권1호
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    • pp.68-76
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    • 2017
  • 고강도, 내약품성, 무독성, 내연소성의 장점을 가지고 있는 PVdF (polyvinylidene fluoride) 나노섬유로 기공이 $0.4{\mu}m$ 평막을 제조한 후, 부직포와 평막으로 나권형 모듈을 제작하였다. 용존유기물의 흡착 제거를 위한 입상 활성탄(GAC, granular activated carbon) 흡착 컬럼과 자체 제작한 나권형 모듈로 혼성 수처리 공정을 구성하였다. 카올린과 휴믹산으로 조제한 모사 용액을 대상으로, 처리수를 재순환하는 경우와 배출하는 경우 각각 GAC 충진량의 영향을 알아보았다. 여과실험 후 물 역세를 하여 회복률과 여과저항을 계산하였다. 또한, 탁도와 $UV_{254}$ 흡광도를 측정하여 GAC의 흡착 효과를 고찰하였다. 그 결과, 처리수를 재순환하는 경우와 배출하는 경우 모두 탁도 처리율에는 GAC 충진량의 영향이 없었다, 하지만 GAC의 $UV_{254}$ 흡광도 처리율이 처리수를 순환하는 경우 0.7~3.6%이었는데, 처리수를 배출하는 경우 3.2-5.7%로 증가하였다. 처리수를 순환하는 경우 GAC의 충진량이 증가함에 따라, 가역적 여과저항($R_r$)과 비가역적 여과저항($R_{ir}$)은 감소하는 경향을 보였다. 그러나 총여과저항($R_t$)은 거의 일정하였고, 물 역세 회복률($R_b$)은 다소 증가하는 경향을 보였다.