• 제목/요약/키워드: fixed carbon

검색결과 451건 처리시간 0.026초

석유 코크스의 에너지 전환 : CO2 가스화 (Energy conversion of petroleum coke : CO2 gasification)

  • 국진우;곽인섭;이시훈
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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    • pp.255-257
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    • 2014
  • The installation of light oil facilities or delayed cokers seems to be inevitable in the oil refinery industry due to the heavy crude oil reserves and the increased use of light fuels as petroleum products. Petroleum coke is a byproduct of oil refineries and it has higher fixed carbon content, higher calorific value, and lower ash content than coal. However, its sulfur content and heavy metal content are higher than coal. In spite of disadvantages, petroleum coke might be one of promising resources due to gasification processes. The gasification of petroleum coke can improve economic value of oil refinery industries by handling cheap, toxic wastes in an environment-friendly way. In this study, $CO_2$ gasification reaction kinetics of petroleum coke, various coals and mixing coal with petroleum coke have investigated and been compared by using TGA. The kinetics of $CO_2$ gasification has been performed with petroleum coke, 3 kinds of bituminous coal [BENGALLA, White Haven, TALDINSKY], and 3 kinds of sub-bituminous coal [KPU, LG, MSJ] at various temperature[$1100-1400^{\circ}C$].

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흡착공정을 이용한 프레온-12와 공기혼합가스의 분리 (Separation of Freon-12 and Air Mixture by Adsorption Process)

  • 강석호;이태진;안희관;김윤갑
    • 한국대기환경학회지
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    • 제9권1호
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    • pp.101-106
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    • 1993
  • In order to separate the Freon-12 and air mixture$(CF_2Cl_2/Air=0.1/99.9 vol.%)$ by pressure swing adsorption (PSA), the breakthrough curve was experimentally observed in a fixed bed adsorption column. A single adsorber was packed with various adsorbents such as, the activated carbon(S-AC, W-AC) and the molecular sieve(MS-5A, MS-13X). The order of appearance of breakthrough curve is MS-5A > MS-13X > W-AC > S-AC. The activated carbon was found to be more effective adsorbent for separating Freon-12 from the mixture than the molecular sieve was. From the experimental data obtained by the separation of Freon-12 gas out of the air stream in the steady-state PSA process cycle, whose size is the same one of column used for the breakthrough curve observation, it has been confirmed that Freon-rich gas could be obtained from the purge step of PSA and Freon-free air could be obtained from the adsorption step of PSA cycle.

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2-D Braided Textile 금속복합재료의 성형과 특성 해석 (Fabrication and Analytical Characterization of 2-D Braided Textile Metal Matrix Composites)

  • 이상관;김효준;변준형;홍순형
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2001년도 춘계학술발표대회 논문집
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    • pp.38-41
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    • 2001
  • A new 2-D braided textile metal matrix composite was developed and characterized. The constituent materials consist of PAN type carbon fiber as reinforcements and pure aluminum as matrices. The braided preforms of different braider yarn angles were fabricated. For a fixed bundle size of 12K, three braider yarn angles was selected: $30^{\circ}$, $45^{\circ}$, and $60^{\circ}$. The braided preforms were infiltrated with pure Al by vacuum assisted squeeze casting. Through the investigation of melt pressing methods and the effects of process parameters such as applied pressure, and pouring temperature, the optimal process conditions were identified as follows: applied pressure of 60MPa, pouring temperature of $800^{\circ}C$. Using the measured geometric parameters, 3-D engineering constants of metal matrix composites have been determined from the elastic model, which utilizes the coordinate transformation and the averaging of stiffened and compliance constants based upon the volume of each reinforcement and matrix material.

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탄소피막 저항기용 자기소체 제조에 있어 Barite 활용에 관한 연구 (Study on the Utilization of Barite in Making Carbon Film Ceramic Resistor)

  • 박정현;전병세;배원태
    • 한국세라믹학회지
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    • 제19권2호
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    • pp.95-100
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    • 1982
  • Instead of barium carbonate, domestic barite was used as the flux in manufacturing theinsulating porcelain. To avoid the problems arising from the decomposition of barite in the body during firing, BaO.$Al_2O_3$ was synthesized at $1300^{\circ}C$ for 5 hours. synthetic BaO.$Al_2O_3$ was mixed with other materials such as kaoline, alumina, clay, dolomite. The RO content (CaO. MgO. BaO) of the batches was varied from range of 4 to 14wt. % at 2wt. % - intervals, and firing temperature was varied from 1280 to 140$0^{\circ}C$-at 4$0^{\circ}C$ intervals The properties such as water absorption, bulk density. mechnical strength, specific resistance, and linear shrinkage were measured. The body containing 12 wt.% of RO content showed the satisfactory for the application in the Fixed Carbon Film Resistor.

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전기철도 집전판 응용을 위한 Ti 나노금속 함량에 따른 나노결정 탄소박막의 물리적, 전기적 특성 (Physical and Electrical Properties of Nanocrystalline Carbon Films Prepared with Ti Concentration for Contact Strip Application of Electric Railway)

  • 박용섭;정호성;박철민
    • 전기학회논문지
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    • 제61권10호
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    • pp.1561-1564
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    • 2012
  • In this work, we have fabricated the nanocrystalline carbon films by using unbalanced magnetron sputtering method with graphite and Ti targets for contact strip application of electrical railway. The power density of graphite target was fixed and the power density was increased for the increase of Ti concentration in TiC films. We investigated the hardness, surface roughness, contact angle, resistivity, HRTEM and XPS of TiC films with Ti concentration. The hardness and resistivity were improved with increasing Ti concentration. These results indicate that the improvement of hardness and resistivity is related to the increase of sp2 clusters in TiC films.

신 열환원 공정에 의한 초미립 티타늄 카바이드 분말 합성 (Synthesis of Ultrafine Titanium Carbide Powder by Novel Thermo-Reduction Process)

  • 이동원;;배정현;김병기
    • 한국분말재료학회지
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    • 제10권6호
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    • pp.390-394
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    • 2003
  • Ultra fine titanium carbide particles were synthesized by novel metallic thermo-reduction process. The vaporized TiC1$_4$+$CCl_4$ gases were reacted with liquid magnesium and the fine titanium carbide particles were then produced by combining the released titanium and carbon atoms. The vacuum treatment was followed to remove the residual phases of MgC1$_2$ and excess Mg. The stoichiometry, microstructure, fixed and carbon contents and lattice parameter were investigated in titanium carbide powders produced in various reaction parameters.

고밀도, 등방성 탄소의 제조에 관한 연구 (Preparation of Isotropic Carbon with High Density)

  • 오종기;이선우;박광원
    • 한국세라믹학회지
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    • 제28권11호
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    • pp.908-916
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    • 1991
  • The characteristics of the carbonized and calcined products made from coal tar pitch coke and coal tar pitch, were investigated in the aspect of the manufacture of isotropic graphite with high density. The mesophase from the pitch was rapidly formed at higher heat-treatment temperature between 410$^{\circ}C$ and 450$^{\circ}C$, where the insolubes in the pitch accelerated the rate of nucleation and growth of the mesophase. The benzene insolubles and the quinoline insolubes were increased as the heat treatment temperature and the heat-treatment time increased. The ratio of benzene insolubles and quinoline solubles (BI/QS) was decreased as the heat-treatment temperature was higher and maintained to be nearly constant regardless of heat-treatment time at fixed heat treatment temperature. The bulk density of the calcined carbon was linearly proportional to the ratio of quinoline solubes to volatile matter in the green coke. Anisotropic ratio of electrical resistance was measured to be between 0.98 and 1.10.

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CNT 첨가량에 따른 Ni-CNT 복합도금막의 특성 (Characteristics of Ni-Carbon Nanotube Composite Coatings with the CNT Content)

  • 배규식
    • 반도체디스플레이기술학회지
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    • 제12권3호
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    • pp.7-12
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    • 2013
  • Ni-CNT(Carbon Nanotube) composite coatings is were formed by electrodeposition and their physical properties were investigated with variations of CNT content(1, 3, 6. 9 g/L) in the electrolyte solution, while the current density and electroplating time were fixed respectively at $6A/dm^2$ and 90 min.. With increasing CNT content from 1 to 9 g/L, incorporated CNTs into the composite coating were limited from 4.65 wt.% to 7.38 wt.%. Microhardness and contact angle values were increased with increasing CNT content of upto 3 g/L. With increasing the CNT content further, physical properties were degraded due to agglomeration, poor adhesion of CNTs to Ni matrix and thus rough surfaces. Optimum electroplating conditions were found to be the CNT content of 3 g/L, current density of 6 A/dm2 and electroplating time of 90 min.

Effect of Oxygen for Diamond Film Synthesis with C-Hexane in Microwave Plasma Enhanced CVD Process

  • Han, Sang-Bo
    • Journal of Electrical Engineering and Technology
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    • 제7권6호
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    • pp.983-989
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    • 2012
  • The purpose of this paper is to decide the optimum synthesis conditions of polycrystalline diamond films according to the ratio of gas mixture. Diamond films were deposited with cyclo-hexane as a carbon precursor by the microwave plasma enhanced chemical vapor deposition process. The optimum oxygen ratio to cyclo-hexane was reached about 125 % under the fixed 0.3% c-hexane in hydrogen. Oxygen plays a role in etching the graphitic components of carbon sp2 bond effectively. By OES measurement, the best synthesis conditions found out about 12.5 % and 15.75 %, which is the emission intensity ratios of CH(B-X) and $H{\beta}$ on $H{\alpha}$, respectively. Also, the electron temperature was similar about 5,000 to 5,200 K in this work.

Estimation of Material Budget in Okutama Forest Area from Satellite Images

  • Ito, Hisao;Ogawa, Susumu
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2003년도 Proceedings of ACRS 2003 ISRS
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    • pp.476-478
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    • 2003
  • Capability of material fixation in forest was noticed since COP3, but now it was difficult to understand material fixation in wide area. In this study, we attempted to estimate and test the amount of carbon, nitrogen, and phosphorus fixed by forest from satellite images. First, we classified into tree species and estimated the number of trees in the forest by species, area, and digital numbers. We inspected to apply it in wide area. Next, we compared the amount of carbon, nitrogen, and phosphorus with NDVI and each band of satellite images.

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