• 제목/요약/키워드: fire-retardancy

검색결과 59건 처리시간 0.025초

클로로프렌 고무의 난연성 및 내방사선 특성 향상 (The Improvements for Fire Retardancy and Radiation Resistance of Chloroprene Rubber)

  • 김기엽;이청;류부형
    • 한국전기전자재료학회논문지
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    • 제17권11호
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    • pp.1205-1211
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    • 2004
  • This study has investigated radiation degradation of chloroprene rubber in the presence of some fire retardant. Ammonium polyphosphate, aluminium trihydroxide, magnesium hydroxide, calcium carbonate and antimony trioxide were selected as flame retardant. Samples were irradiated using a Co$^{60}$ ${\gamma}$ -ray and ray up to 2000 kGy at a dose rate of 5 kGy/hr in the presence of air atmosphere at room temperature. After irradiation, samples were assessed fire retardancy with electrical properties and mechanical properties. Some considerations concerning the effects of the fire retardants added to chloroprene rubber on the radiation and thermal stability of chloroprene rubber are presented. From fire retardancy with electrical and mechanical property measurements, it was found that addition of magnesium hydroxide resulted in maximum fire retardant effect.

Epoxy/Montmorillonite 합성체의 연소 특성 평가 (Assessment of Combustion Property for Epoxy/Montmorillonite Composite)

  • 송영호;하동명;정국삼
    • 한국화재소방학회:학술대회논문집
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    • 한국화재소방학회 2008년도 춘계학술논문발표회 논문집
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    • pp.168-172
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    • 2008
  • The flame retardancy by the addition of clay was evaluated to present as the fundamental data to decrease the fire hazard of polymers and life losses. The flame retardancy was examined to increase flame retardancy and to decrease smoke yield of epoxy by the addition of clay such as montmorillonite. For this study, the experiments of flame retardancy were conducted as follows : the measurement of the limiting oxygen index(LOI), char yield, and smoke density. As MMT concentration increased, epoxy/MMT composite increased LOI and char yield with the decreased smoke density.

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합성섬유용 인산염계 유화방염제의 제조 및 방염거동에 관한 연구 (A Study on Preparation and Fire-retardant Behavior of Phosphate Type Emulsified Fire Proofing Agent for Synthetic Fibers)

  • 근장현;박홍수
    • 한국응용과학기술학회지
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    • 제11권1호
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    • pp.45-52
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    • 1994
  • For the purpose of producing emulsified fire proofing agent for synthetic fibers, 2,3-dibromopropylmonoamido orthophosphate[DP-AOP] and bis(2,3-dibromopropyl)monoamidoorthophosphate[$(DP)_{2}AOP$] were synthesized, and their structures were identified by instrumental analysis, respectively. Using three kinds of emulsifiers, O/W emulsified fire proofing agents, DPF and DPDPF, were obtained corresponding to DP-AOP and $(DP)_{2}-AOP$, respectively. Various synthetic textiles were fire-retardant treated by prepared DPF and DPDPF, and fire retardancy and tearing strength of the resulting products were tested. The results showed that as the concentration of fire proofing agents increased, fire retardancy increased, but the tearing strength much decreased, where the tendencies of DPDPF were deeper than those of DPF. But, since the fire retardancy appeared favorable in the range of $10{\sim}20wt%$ of DPDPF, DPDPF is proven to be a fire proofing agent useful for various synthetic textiles.

Montmorillonite 첨가에 의한 Epoxy Resin의 난연성 개선 (Improvement the Flame Retardancy of Epoxy Resin by the Addition of Montmorillonite)

  • 송영호;정국삼
    • 한국화재소방학회논문지
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    • 제22권3호
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    • pp.300-304
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    • 2008
  • 고분자 물질의 화재 위험성 및 화재시 인명 피해의 감소를 위한 기초자료로 제시하고자 점토질의 첨가에 의한 난연성 평가를 수행하였다. 본 연구에서는 에폭시 수지의 난연성 향상과 연기의 발생량을 감소시키기 위하여 점토질의 montmorillonite(MMT)와 같은 천연 물질을 삽입하여 연소 특성을 살펴보았다. 이 연구를 위하여 한계산소지수(limiting oxygen index, LOI), 탄화층 생성량(char yield), 연기 밀도(smoke density) 측정 둥의 난연성 실험을 실시하였다. Epoxy/MMT의 복합재료는 MMT의 농도가 증가할수록 한계산소지수 및 탄화층 생성량이 증가하여 난연성이 향상되었으나 연기 밀도는 오히려 증가하는 결과를 나타내었다.

Antimony Trioxide가 첨가(添加)된 내화도료(耐火塗料)의 도막(塗膜)이 목질(木質) 판상재료(板狀材料)의 내화성(耐火性)에 미치는 영향(影響) (Effects of Antimony Trioxide-containing Coating on Fire Retardancy of Wood-based Materials)

  • 윤영기;이필우
    • Journal of the Korean Wood Science and Technology
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    • 제20권2호
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    • pp.31-42
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    • 1992
  • In this study, the relative effectiveness of antimony trioxide-containing coat on fire retardancy of plywood, particleboard and medium density fiberboard was investigated and compared through ISO ignition test and inclined panel test with non-coated ones. The results obtained were summarized as fallows: Any treated materials was not ignited in inclined panel test with 5 minutes, but only particleboard among treated ones burned in ISO ignition test with fairly delayed time. The weight loss rate of plywood decreased with the increased addition level of fire-retardant and the least values were obtained in particleboard and MDF at addition level of 7% and 5% respectively. Carbonized area of wood based materials decreased with the increased addition level of fire retardant. The temperatures of back in plywood, particleboard treated with fire-retard ant coat containing 7% $Sb_2O_3$ showed the lowest but MDF did not show any effectiveness with the increased addition level. The first flash time of plywood treated with fire retardant coat containing 9% $Sb_2O_3$, MDF and particleboard treated with fire retardant coat containing 7% $Sb_2O_3$ were 257sec., 286.4sec., 165.4sec. respectively.

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Physical and Mechanical Properties and Fire-endurance Characteristics of Recycled Particleboards

  • Suh, Jin-Suk;Han, Tae-Hyung;Park, Joo-Saeng;Park, Jong-Young
    • 한국가구학회지
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    • 제19권6호
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    • pp.475-486
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    • 2008
  • In this study, fire-retardant chemicals were melt with mixed composition ratios of dibasic ammonium phosphate and each half of boric acid and borax in hot water, in which hammer-milled chips were immersed to increase swelling of waste particleboards. Also, fire-retardant treated particles from sawn lumber chip and recycled particleboard chip were composed in ratio of 70:30 in core layer to improve boards' properties. Retention ratio of fire-retardant chemicals for the particles for face layer was high due to high specific surface area, and that of sawn lumber chips was somewhat higher than that of recycled particleboard chips. The mixture of particles from sawn lumber chips and recycled PB of 70:30 in weight ratio exceeded bending strength of 100 $kgf/cm^2$. It seemed that the relatively greater portions of dibasic ammonium phosphate affected adversely to dimensional stability, however fire-retardants treatment resulted in distinct effect lowering formaldehyde emission such as $E_0$ type(0.5mg/$\ell$ or less) in KS F 3104. In fire-retardancy, the recycled boards with a mixed ratio of dibasic ammonium phosphate to boric acid borax(50:50 mixture) of 70% to 30% in weight satisfied fire-retardancy 3rd grade in KS F 2271, and also this composition from cone calorimeter test met same standard grade figuring total heat release of 4.6MJ/$m^2$.

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옥외 광고물 소재의 연소특성 평가 (Evaluation of Combustion Characteristics of Outdoor Advertisement Materials)

  • 엄상용;김경진;이수경
    • 한국화재소방학회논문지
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    • 제26권5호
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    • pp.79-84
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    • 2012
  • 상층 및 인접건물로의 연소확대 위험성이 있는 옥외 광고물 소재의 연소특성을 평가하였다. 본 연구에서는 UL 94와 ASTM D 2863에 따라 난연성과 한계산소지수를 평가하였다. 난연성 평가결과, 포멕스가 V-0의 높은 난연성을 보이는 반면 다른 시료들에서는 등급외의 난연성을 보였다. 한계산소지수 평가 결과에서도 포멕스의 한계산소지수가 가장 높았다. ISO 5660-1에 따라 콘칼로리미터를 이용하여 연소특성을 평가하였으며, 콘칼로리미터 시험결과 옥외 광고물 소재들은 화재확대 예방에 취약하다는 것을 알 수 있었다. 플렉스의 착화시간이 가장 빨랐으며, 특히 아크릴판은 최대 열방출율 뿐만 아니라 총 방출열량 또한 다른 소재들에 비해 높았다.