• Title/Summary/Keyword: fine silica

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A Study on the Coagulation of Wastewater Containing Fine Silica Particles with the Waste Slurry from Soda Ash Manufacturing Industries (소오다회 제조 공장의 폐슬러리를 이용한 미세 실리카 함유 폐수의 응집에 관한 연구)

  • Jun, Se Jin;Yim, Sung Sam
    • Applied Chemistry for Engineering
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    • v.10 no.7
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    • pp.1073-1078
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    • 1999
  • The objectives of this study are to examine the applicability of waste slurry from soda ash manufacturing industries as a coagulant for the treatment of wastewater containing fine silica particles, and to reduce the cost of wastewater treatment containing silica. Acceptable water quality can be obtained with a little dosing of waste slurry by gelation before the coagulation process so it could be concluded that the waste slurry from soda ash can be used as a coagulant. Based on the results of experiments, the optimum pH of gelation for silica in wastewater was around five and the treatment process with the gelation of silica could reduce the chemical dosage and waste sludge after coagulation. Dewatering and settling characteristics of the floc after coagulation with the waste slurry are better than those of the floc after coagulation with the lime milk only.

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Comparison of Enantioselective CEC Separation of OT-MIP Capillary Columns with Templates of Various Camphor Derivatives Made by the Pre-established General Preparation Protocol

  • Zaidi, Shabi Abbas;Lee, Seung-Mi;Lee, Ju-Young;Cheong, Won-Jo
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2934-2938
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    • 2010
  • Some open tubular (OT) molecule imprinted polymer (MIP) silica capillary columns with templates of camphor derivatives such as 10-camphorsulfonic acid (10-CSA), 10-camphorsulfonamide (10-CS) and camphor-p-tosyl hydrazone (CTH) have been successfully prepared by the prior generalized preparation protocol. The three MIP thin layers of different templates showed quite different morphologies. The chiral selectivity of each MIP column for the template enantiomers was optimized by changing eluent composition and pH. The optimization conditions were found to be different for the three MIPs. This work suggests prospective successful extension of the generalized preparation protocol for OT-MIP silica capillary columns toward templates of a variety of chemical groups.

An Experimental Study on the Flowing and Strength Properties of Mortar using Low Carbon Inorganic Binder by Sand Replacement Ratio (잔골재 치환율별 저탄소 무기결합재를 사용한 모르타르의 유동 및 강도 특성에 관한 실험적 연구)

  • Bae, Sang-Woo;Lee, Yun-Seong;Lee, Kang-Pil;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.05a
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    • pp.63-64
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    • 2011
  • This study is about the mortar in which fine aggregate is substituted by low-carbon eco-friendly inorganic composite prepared by addition of alkali accelerator in industrial by-products such as blast furnace slag, red mud and silica fume as a replacement for cement. Results of experiments on flow and strength properties in mortar of inorganic composite according to replacement rate of fine aggregate showed that amount of air and table flow decreased as replacement rate of fine aggregate about inorganic composite got higher. Also, it's shown that the compressive strength was the highest at replacement rate 50% of fine aggregate about inorganic composite.

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Preparation and Gas Permeation Properties of Silica Membranes on Porous Stainless Steel-Tube Supports (다공성 금속 지지체에 제조된 실리카 분리막의 기체 투과 특성)

  • Lee, Hye Ryeon;Seo, Bongkuk
    • Membrane Journal
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    • v.24 no.3
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    • pp.177-184
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    • 2014
  • Silica membranes with high permeability were prepared using colloidal and polymeric silica sols on a porous stainless steel-tube support by a DRFF and SRFF method. Silica sols were derived with tetraethylorthosilicate (TEOS) by sol-gel method and analyzed with DLS, FE-SEM, and $N_2$ adsorption. The coating of the intermediate layer with colloidal silica sol on the stainless steel-tube support led to a denser surface morphology of the membrane along with a considerable reduction in the number of surface defect. As the polymeric silica sol enclosed the colloidal silica sol with spherical particles during the SRFF method, the separation-layer-coated silica membrane showed a denser surface than the intermediate layer. Moreover, the silica membranes showed high hydrogen gas permeability of $(6.63-9.21){\times}10^{-5}mol{\cdot}m^{-2}{\cdot}s^{-1}{\cdot}Pa^{-1}$ with low $H_2/N_2$ perm-selectivity (2.9-3.1) at room temperatures.

A Flexural Strength Properties of Extruding Concrete Panel Using Stone Powder Sludge (석분슬러지를 이용한 압출성형 콘크리트 패널의 휨강도 특성)

  • Choi Hun-Gug;Jung Eun-Hye;Kawg Eun-Gu;Kang Cheol;Seo Jung-Pil;Kim Jin-Man
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.05a
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    • pp.115-118
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    • 2006
  • Nowadays the using of concrete is generalized, and construction material is demanded to be lightweight according to increasing the height and capacity of buildings. Therefore, it needs to develop the products having the great quality and various performance. Extruding concrete panel made of cement, silica source, and fiber, and it is a good lightweight concrete material in durability and thermostable. The silica of important ingredient is natural material with hish SiO2 contents and difficult in supply because of conservation of environment. On the other hand, the stone powder sludge discharged about 20-30% at making process of crushed fine aggregate and it is wasted. The stone powder sludge is valuable instead of silica ole because the stone powder sludge includes water of about 20-60%, SiO2 of about 64% and it has fine particles. This experiment is on the properties of extruding concrete panel using the stone powder sludge use instead of silica. From this experiment, we find that it is possible to replace the silica as stone power sludge up to 50%,

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Experimental study on rheology, strength and durability properties of high strength self-compacting concrete

  • Bauchkar, Sunil D.;Chore, H.S.
    • Computers and Concrete
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    • v.22 no.2
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    • pp.183-196
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    • 2018
  • The rheological behaviour of high strength self compacting concrete (HS-SCC) studied through an experimental investigation is presented in this paper. The effect of variation in supplementary cementitious materials (SCM) $vis-{\grave{a}}-vis$ four different types of processed crushed sand as fine aggregates is studied. Apart from the ordinary Portland cement (OPC), the SCMs such as fly ash (FA), ground granulated blast furnace slag (GGBS) ultrafine slag (UFS) and micro-silica (MS) are used in different percentages keeping the mix -paste volume and flow of concrete, constant. The combinations of rheology, strength and durability are equally important for selection of mixes in respect of high-rise building constructions. These combinations are referred to as the rheo-strength and rheo-durability which is scientifically linked to performance based rating. The findings show that the fineness of the sands and types of SCM affects the rheo-strength and rheo-durability performance of HS-SCC. The high amount of fines often seen in fine aggregates contributes to the higher yield stress. Further, the mixes with processed sand is found to offer better rheology as compared to that of mixes made using unwashed crushed sand, washed plaster sand, washed fine natural sand. The micro silica and ultra-fine slag conjunction with washed crushed sand can be a good solution for high rise construction in terms of rheo-strength and rheo-durability performance.

Preparation of Silica Sol by Partial Hydrolysis of TEOS and High Purity Silica Glass Fiber (TEOS의 부분가수분해에 의한 실리카 졸의 합성과 유리섬유 제조)

  • Yang, Hyun S.;Kwon, Oh H.;Lee, Jae D.;Rho, Jae S.;Kim, Young H.
    • Applied Chemistry for Engineering
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    • v.7 no.5
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    • pp.823-831
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    • 1996
  • At the ratio [$H_2O$]/[TEOS]=1.7, the silica sol was synthesized by partial hydrolysis in the presence of acid catalyst. After stabilizing the silica sol by trimethylsilylation, the molecular weight and viscosity of the sol obtained at various reaction times were examined to determine a best spinnability of the sol. Gel fibers were prepared from the sol solution after removing solvent in the solution, and the gel fibers were heated at $1,000^{\circ}C$. The prepared silica fibers were in the shape of circular cross-section and their tensile strength and $SiO_2$ purity were $83{\pm}20kg/mm^2$ and about 99.997%, respectively.

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Studies on the Synthesis of High Purity and Fine Mullite Powder (I) (고순도 초미립자 물라이트 분말 합성에 대한 연구 (I))

  • 김경용;김윤호;김병호;이동주
    • Journal of the Korean Ceramic Society
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    • v.26 no.5
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    • pp.682-690
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    • 1989
  • Fine mullite powder was prepared by colloidal sol-gel route. Boehmite as a starting material of Al2O3 and silica sol or fumed silica as a starting material of SiO2 were used. $\alpha$-Al2O3, TiO2 and ZrO2 were used as seeding materials. The combination of boehmite and silica was found to be the stoichiometric mullite powder. Techniques for drying used were spray drying, freeze drying, reduced pressure evaporation and drying in a oven. The gelled powder was heated at 130$0^{\circ}C$ for 100min and was attrition-milled for 1~3hrs. The mullite powder obtained was composed of submicrometer, uniform and spherical particles with a narrow size distribution. The mullite powder was characterized by BET, SEM, XRD and IR spectroscopy.

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Statistical flexural toughness modeling of ultra high performance concrete using response surface method

  • Mosabepranah, Mohammad A.;Eren, Ozgur
    • Computers and Concrete
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    • v.17 no.4
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    • pp.477-488
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    • 2016
  • This paper aims to model the effects of five different variables which includes: cement content (C), the steel fiber amount (F), the silica fume amount (SF), the superplasticizer (SP), the silica fume amount (SF), and the water to cementitious ratio (w/c) on 28 days flexural toughness of Ultra High Performance Concrete (UHPC) as well as, a study on the variable interactions and correlations by using analyze of variance (ANOVA) and response surface methodology (RSM). The variables were compared by fine aggregate mass. The model will be valid for the mixes with 0.18 to 0.32 w/c ratio, 4 to 8 percent steel fiber, 7 to 13 percent cement, 15 to 30 percent silica fume, and 4 to 8 percent superplasticizer by fine aggregate mass.