• 제목/요약/키워드: fine dispersion

검색결과 186건 처리시간 0.023초

준 실시간 측정시스템을 이용한 미세입자 원소성분 배출특성 조사 (Emission Characteristics of Elemental Constituents in Fine Particulate Matter Using a Semi-continuous Measurement System)

  • 박승식
    • 한국대기환경학회지
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    • 제26권2호
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    • pp.190-201
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    • 2010
  • Fine particulate matter < $1.8{\mu}m$ was collected as a slurry using the Semicontinuous Elements in Aerosol Sampler with time resolution of 30-min between May 23 and 27, 2002 at the Sydney Supersite, Florida, USA. Concentrations of 11 elements, i.e., Al, As, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Se, and Zn, in the collected slurry samples were determined off-line by simultaneous multi-element graphite furnace atomic absorption spectrometry. Temporal profiles of $SO_2$ and elemental concentrations combined with meteorological parameters such as wind direction and wind speed indicate that some transient events in their concentrations are highly correlated with the periods when the plume from an animal feed supplement processing facility influenced the Sydney sampling site. The peaking concentrations of the elemental species during the transient events varied clearly as the plume intensity varied, but the relative concentrations for As, Cr, Pb, and Zn with respect to Cd showed almost consistent values. During the transient events, metal concentrations increased by factors of >10~100 due to the influence of consistent plumes from an individual stationary source. Also the multi-variate air dispersion receptor model, which was previously developed by Park et al. (2005), was applied to ambient $SO_2$ and 8 elements (Al, As, Cd, Cr, Cu, Fe, Pb, and Zn) measurements between 20:00 May 23 and 09:30 May 24 when winds blew from between 70 and $85^{\circ}$, in which animal feed processing plant is situated, to determine emission and ambient source contributions rates of $SO_2$ and elements from one animal feed processing plant. Agreement between observed and predicted $SO_2$ concentrations was excellent (R of 0.99; and their ratio, $1.09{\pm}0.35$) when one emission source was used in the model. Average ratios of observed and predicted concentrations for As, Cd, Cr, Pb, and Zn varied from $0.83{\pm}0.26$ for Pb to $1.12{\pm}0.53$ for Cd.

Microstructural properties of Pt-doped $YBa_{2}Cu_{3}O_{7-x}$ high $T_c$ superconductor prepared by melting method.

  • Song, Jin-Tae
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 1992년도 추계학술발표강연 및 논문개요집
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    • pp.16-16
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    • 1992
  • We have studied the effect of platinum addition on the supercon ducting properties of YB $a_2$C $u_3$$O_{7-x}$ (123) compound and elucidated the mechanism of fine dispersion of $Y_2$BaCu $O_{5}$(211) particles in YB $a_2$C $u_3$$O_{7-x}$ superconductor prepared by melting method from the metallurgical point of view. In this study, BaCu $O_2$ and CuO-rich phase unreacted during the peritecitc reaction markedly decreased by the 211 powder addition. The 211 particle of Pt-fee sintered samples exhibited 8~10$\mu$m in size, but in 1wt%Pt-added sample, 211 particles were finely dispersed in 123 matrix and the size of 211 particle was about 1~2$\mu$m. And, the critical temperature( $T_{c. zero}$) of Pt doped samples was 91.5K and the transport critical current density ( $J_{c}$) of Pt-doped samples was much more than 10$^4$A/$\textrm{cm}^2$. The high $J_{c}$ and fine dispersion of 211 particles of Pt doped YB $a_2$C $u_3$$O_{7-x}$ superconductor are attributed to $Ba_4$CuP $t_2$ $O_{8}$ compounds formed during the partial melting, which were considered als nucleation sites of 211 particles, rather than Pt inself.han Pt inself.

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잔골재 조립률 및 굵은골재 입형이 초유동 콘크리트의 특성에 미치는 영향 (The Influence of Fineness Modulus of Pine Aggregate and Grain Shape of Coarse Aggregate on the Properties of High Flowing Concrete)

  • 정용욱;이승한;윤용호
    • 콘크리트학회논문집
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    • 제17권5호
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    • pp.785-792
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    • 2005
  • 본 연구는 굵은골재의 입형불량과 잔골재의 조립률 저하가 초유동콘크리트의 특성에 미치는 영향을 검토한 것이다. 이론 위해 잔골재 조립률을 2.0, 2.5, 3.0, 3.5로 변화시키고 굵은골재는 입형개선전$\cdot$후 골재를 사용하여 초유동콘크리트의 유동검 및 충전성능을 검토하였다. 또한 골재입자의 분산거리를 상대비교 함으로써 잔골재의 조립률 및 굵은골재의 입형이 골재입자의 분산거리에 미치는 영향을 검토하였다. 실험 결과 굵은골재와 잔골재 혼합시의 최소공극률은 골재 입형개선 유무에 관계없이 잔골재 조립률 3.0, 2.5, 2.0, 3.5 순으로 나타나 조립률 KS 규정 값 $2.3\~3.1$보다 작거나 클 경우 공극률을 증가시키는 것으로 나타났으며, 굵은골재의 입형은 구형율 0.69의 원반상에서 구형율 0.78의 구상으로 개선할 경우 최소공극률을 나타내는 잔골재율을 $47\%$에서 $41\%$$6\%$ 감소시키는 것으로 나타났다. 잔골재 조립률에 따른 28일 압축강도 특성은 조립률 2.0에서 2.5, 3.0으로 증가할수록 약 3MPa씩 증가하였으나, 조립률 3.5에서는 3.0에 비해 약 9MPa 정도 감소하였다. 또한 굵은골재의 입형개선과 잔골재 조립률의 증가는 유동성, 충전성 및 V로드 상대유하시간을 향상시키는 것으로 나타났으며, 잔골재 조립률은 KS 규정 값 $2.3\~3.1$을 만족하는 범위내에서 높은 값을 사용하는 것이 페이스트 용적비를 증가시키는 것으로 나타났다.

단순 전단변형에 의한 15Cr 산화물 분산강화 강의 미세조직 변화 (Microstructure Evolution of 15Cr ODS Steel by a Simple Torsion Test)

  • 진현주;강석훈;김태규
    • 한국분말재료학회지
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    • 제21권4호
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    • pp.271-276
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    • 2014
  • 15Cr-1Mo base oxide dispersion strengthened (ODS) steel which is considered to be as a promising candidate for high- temperature components in nuclear fusion and fission systems because of its excellent high temperature strength, corrosion and radiation resistance was fabricated by using mechanical alloying, hot isostatic pressing and hot rolling. Torsion tests were performed at room temperature, leading to two different shear strain routes in the forward and reverse directions. In this study, microstructure evolution of the ODS steel during simple shearing was investigated. Fine grained microstructure and a cell structure of dislocation with low angle boundaries were characterized with shear strain in the shear deformed region by electron backscattered diffraction (EBSD). Grain refinement with shear strain resulted in an increase in hardness. After the forward-reverse torsion, the hardness value was measured to be higher than that of the forward torsion only with an identical shear strain amount, suggesting that new dislocation cell structures inside the grain were generated, thus resulting in a larger strengthening of the steel.

The Biological Functionality of Electro-Galvanized Steels Coated with a Hybrid Composite Containing Pyrethroid

  • Jo, Du-Hwan;Kim, Myung-Soo;Kim, Jong-Sang;Oh, Hyun-Woo
    • Corrosion Science and Technology
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    • 제17권2호
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    • pp.74-80
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    • 2018
  • The electronic industries require environmentally-friendly and highly functional materials to enhance the quality of human life. Home appliances require insect repellent steels that work to protect household microwave ovens from incurring damage by insects such as fire ants and cockroaches in tropical regions. Thus, POSCO has developed new types of functional steels, coated with an array of organic-inorganic hybrid composites on the steel surface, to cover panels in microwave ovens and refrigerators. The composite solution uses a fine dispersion of hybrid solution with polymeric resin, inorganic and a pyrethroid additive in aqueous media. The hybrid composite solution coats the steel surface, by using a roll coater and is cured using an induction curing furnace on both the continuous galvanizing line and the electro-galvanizing line. The new steels were evaluated for quality performances, salt spray test for corrosion resistance and biological performance for both insect repellent and antimicrobial activity. The new steels with organic-inorganic composite coating exhibit extraordinarily biological functionalities, for both insect repellent and antimicrobial activities for short and long term tests. The composite-coating solution and experimental results are discussed and suggest that the molecular level dispersion of insecticide on the coating layer is key to biological functional performances.

디젤유분무의 초기분산과정에 관한 실험적 연구 (An experimental study on initial dispersion process of diesel fuel spray)

  • 허종철;구자왕;양옥룡
    • 오토저널
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    • 제13권2호
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    • pp.42-49
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    • 1991
  • This study is to investigate the dispersion characteristics of diesel fuel spray in the initial stage of the beginning of the injection under the condition of room temperature and atmospheric pressure. It is difficult to analyse that the diesel fuel spray in diesel engine has unsteady intermittent spray. So author installed a fuel accumulator and an electromagnetic controller in order to keep the constant fuel injection rate with the time variation. With this modified fuel injection system, spray tip penetration, spray angle and initial spray development process are investigated by instantaneous photographic method. The results obtained in this study are as follows : 1) The initial shape of injection of diesel fuel spray shows the form of non-disintegrated intact core, but the formation of ligaments increasingly grows as the time increases. It can also be shown that fine droplets become disintegrated out from the ligaments. 2) The slope of spray tip penetration was changed to two different tendencies with time. The transition point of the slope is shown at the time of around between 0.09 msec and 0.4 msec from the beginning of injection. This is transition time from non-disintegrated intact core to formation of ligaments.

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A Study on the Characteristics of Amorphous TiAl by P/M Processing

  • Han, Chang-Suk;Jeon, Seung-Jin
    • 열처리공학회지
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    • 제29권2호
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    • pp.51-55
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    • 2016
  • The P/M processing of titanium aluminide using amorphous TiAl is developed by which it is possible to overcome inherent fabricability problems and to obtain a fine microstructure. A high quality amorphous TiAl powder produced by reaction ball milling shows clear glass transition far below a temperature at the onset of crystallization in differential scanning calorimetry above a heating rate of 0.05 K/s. We obtained a fully dense compact of amorphous TiAl powders, encapsulated in a vacuumed can, via viscous flow by hot isostatic pressing (HIP). Isothermally annealing of HIP'ed amorphous compact under a pressure of 196 MPa shows a progressive growth of ${\gamma}-TiAl$ phase with ${\alpha}2$ ($Ti_3Al$), which is characterized by increasing sharpness of X-ray peaks with temperature. Fully dense HIP'ed compact of titanium aluminide TiAl shows a high hardness of 505 Hv, suggesting strengthening mechanisms by sub-micron sized grain of ${\gamma}-TiAl$ and particle-dispersion by second phase constituent, ${\alpha}2$.

열성층유동장에 놓인 원주후류의 특성에 대한 연구 (3) -선형열원으로부터의 난류확산- (Study on the Characteristics of Cylinder Wake Placed in Thermally Stratified Flow(III) - Turbulent Dispersion from a Line Heat Source-)

  • 김경천;정양범
    • 대한기계학회논문집
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    • 제19권5호
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    • pp.1300-1307
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    • 1995
  • The effect of thermal stratification on the turbulent dispersion from a fine cylindrical heat source was experimentally examined in a wind tunnel with and without a strong temperature gradient. A 0.5 mm dia. nichrome wire was used as a line heat source. Turbulent intensities, r.m.s. value of temperature and convective heat fluxes were measured by using a hot-wire and cold-wire combination probe. The results show that the peack value and the spread of the vertical turbulent intensity for the stratified case are far lower than those in the neutral case, which indicates that the stable temperature gradient suppresses the vertical velocity component. All of the third order moments including heat fluxes measured in the stable condition have very small values than those of the neutral case. This nature suggests that the decrease of scalar fluctuations in the stably stratified flow is mainly due to the suppression ofthe turbulent diffusion processes by the stable stratification. A simple gradient model with a composite timescale which has a simple weighted algebraic mean between dynamic and thermal time scale yields reasonably good numerical values in comparison with the experimental data.

Fiber Optics for Multilayered Optical Memory

  • Kawata, Yoshimasa;Tsuji, Masatoshi;Inami, Wataru
    • 정보저장시스템학회논문집
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    • 제7권2호
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    • pp.53-59
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    • 2011
  • We have developed a compact and high-power mode-locked fiber laser for multilayered optical memory. Fiber lasers have the potential to be compact and stable light sources that can replace bulk solid-state lasers. To generate high-power pulses, we used stretched-pulse mode locking. The average power and pulse width of the output pulse from the fiber laser that we developed were 109 mW and 2.1 ps, respectively. The dispersion of the output pulse was compensated with an external single-mode fiber of 2.5 m length. The pulse was compressed from 2.1 ps to 93 fs by dispersion compensation. The fiber laser we have developed is possible to use as a light source of multilayered optical memory. We also present a fiber confocal microscope as an alignment-free readout system of multilayered optical memories. The fiber confocal microscope does not require fine pinhole position alignment because the fiber core is used as the point light source and the pinhole, and both of which are always located at the conjugated point. The configuration reduces the required accuracy of pinhole position alignment. With these techniques we can present an all-fiber recording and readout system for multilayered memories.

액적 분급 장치를 적용한 분무열분해 공정으로부터 합성된 실리카 분말의 특성 (The Characteristics of Silica Powders Prepared by Spray Pyrolysis Applying Droplet Classification Apparatus)

  • 강윤찬;주서희;구혜영;강희상;박승빈
    • 한국재료학회지
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    • 제16권10호
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    • pp.633-638
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    • 2006
  • Silica powders with spherical shape and narrow size distribution were prepared by large-scale ultrasonic spray pyrolysis applying the droplet classification apparatus. On the other hand, silica powders prepared by large-scale ultrasonic spray pyrolysis without droplet classification apparatus had broad size distribution. Droplet classification apparatus used in this paper applied the principles of cyclone and dispersion plate with small holes. The droplets formed from the ultrasonic spray generator applying the droplet classification apparatus had narrow size distribution. The droplets with fine and large sizes were eliminated by droplet classification apparatus. The optimum flow rate of the carrier gas and diameter of the hole of the dispersion plate were studied to reduce the size distribution of the silica powders prepared by large-scale ultrasonic spray pyrolysis. The size distribution of the silica powders prepared by large-scale ultrasonic spray pyrolysis at the optimum preparation conditions was 0.76.