• 제목/요약/키워드: ferroelectricity

검색결과 75건 처리시간 0.024초

유전이력곡선 및 전류이력곡선을 통한 강유전성 확인 방법 (Measurement of Dielectric Hysteresis and Current Hysteresis for Determining Ferroelectricity)

  • 박재환;박재관;김윤호
    • 한국결정학회지
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    • 제12권2호
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    • pp.65-91
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    • 2001
  • Sawyer-Tower 회로를 이용한 강유전 이력곡선의 측정에서 직류 누설성분에 의한 오차요인을 검토하고 그 해결책을 제안하였다. 강유전체 시편에 존재하는 직류 누설성분에 의한 잔류분극과 항전계는 항상 과대 평가될 수 있는 위험성이 있음을 알 수 있었으며 이러한 오차는 직류누설성분이 크고 측정시간이 길수록 심화되었다. Sawyer-Tower 회로를 이용한 강유전 이력곡선과 함께 보완적으로 활용할 수 있는 전류이력곡선을 새롭게 제안하였다.

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temperature synthesis and ferroelectric properties of (117)-oriented $Bi_{3.25}La_{0.75}Ti_3O_{12}$ thin films on $LaNiO_3$ electrodes

  • Kim, Kyoung-Tae;Kim, Chang-Il
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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    • pp.264-267
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    • 2004
  • [ $Bi_{3.25}La_{0.75}Ti_3O_{12}$ ] (BLT) thin films were prepared by using metal organic decomposition method onto the $LaNiO_3$ (LNO) bottom electrode. Both the structure and morphology of the films were analyzed by x-ray diffraction (XRD) and atomic force microscope (AFM). Even at low temperatures ranging from 450 to $650^{\circ}C$, the BLT thinfilms were successfully deposited on LNO bottom electrode and exhibited (117) orientation. The BLT thin films annealed as low as $600^{\circ}C$ showed excellent ferroelectricity, higher remanent polarization and no significant degradation of switching charge at least up to $5{\times}10^9$ switching cycles at a frequency of 100 kHz and 5 V. For the annealing temperature of $600^{\circ}C$, the remanent polarization Pr and coercive field were $23.5\;C/cm^2$ and 120 kV/cm, respectively.

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Effect of Seeding Layers on Preparation of PLZT Thin Films by Sol-Gel Method

  • Hirano, Tomio;Kawai, Hiroki;Suzuki, Hisao;Kaneko, Shoji;Wada, Tatsuya
    • The Korean Journal of Ceramics
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    • 제5권1호
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    • pp.50-54
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    • 1999
  • $(Pb_xLa_{1-x}) (Zr_yTi_{1-y})O_3$ (PLZT) thin films with electrooptic effect are promising for the optical application such as display or light shutter. However, it is difficult to use inexpensive and transparent glass substrates because the conventional process for preparation of PLZT requires temperatures above $600^{\circ}C$. In order to deposit a perovskite PLZT thin films at low processing temperatures through alkoxide route, we have offered several seeding processes which reduce the activation energy for crystallization. In this study, we optimized the stacking structure of multilayered PLZT for obtaining single phase perovskite at lower temperatures. As a result, ferroelectric PLZT thin films with different compositions were successfully prepared at a temperature as low at $500^{\circ}C$.

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강유전 고분자 박막을 이용한 유기고분자 태양전지에서의 효율 증대 (Efficiency Enhancement in Organic Polymer Solar Cells with Ferroelectric Films)

  • 박자영;정치섭
    • 한국전기전자재료학회논문지
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    • 제30권2호
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    • pp.126-132
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    • 2017
  • The power conversion efficiency of organic polymer solar cells was enhanced by introducing a ferroelectric polymer layer at the interface between active layer and metal electrode. The power conversion efficiency was increased by 50% through the enhancement of the open circuit voltage. To investigate the role of the ferroelectric layer on the dissociation process of the excitons, non-radiative portion of the exciton decay was directly measured by using photoacoustic technique. The results show that the ferroelectric nature of the buffer layer does not play any roles on the dissociation process of the excitons, which indicates the efficiency enhancement is not due to the ferroelectricity of the buffer layer.

화학기계적 연마에 의한 리튬니오베이트의 광학 특성에 관한 연구 (Study on Optical Properties of Lithium Niobate Using CMP)

  • 정석훈;김영진;이현섭;정해도
    • 대한기계학회논문집A
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    • 제33권3호
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    • pp.196-200
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    • 2009
  • Lithium niobate ($LN:LiNbO_3$) is a compound of niobium, lithium and oxygen. The characteristics of LN are piezoelectricity, ferroelectricity and photoelectricity, and which is widely used in surface acoustic wave (SAW). To manufacture LN devices, the LN surface should be a smooth surface and defect-free because of optical property, but the LN material is processed difficult b traditional processes such as grinding and mechanical polishing (MP) because of its brittleness. To decrease defects, chemical mechanical polishing (CMP) was applied to the LN wafer. In this study, the suitable parameters such as down force and relative velocity, were investigated for the LN CMP process To improve roughness, the LN CMP was performed using the parameters that were the highest removal rate among process parameters. And, evaluation of optical property was performed by the optical reflectance.

Synthesis and Characterization of New Azomethine Polymers Containing Bent-Core Mesogen with Sharp Bend Angle

  • Kim, Eun-Chol;Choi, E-Joon;Ok, Chang-Woo;Zin, Wang-Choel
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.553-555
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    • 2007
  • Six azomethine polymers containing bent-core mesogen were synthesized with variation of a bent structure of central core (1,2-dioxyphenylene or 2,3-dioxynaphthylene), and a lateral halogen substituent (X = H, F or Cl ). The properties of the polymers were characterized by FT-IR, NMR spectroscopy, DSC, polarizing optical microscopy, and X-ray diffractometry.

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MFSFET의 신경회로망 응용을 위한 CUJT와 PUT 소자를 이용한 발진 회로에 관한 연구 (Study on Oscillation Circuit Using CUJT and PUT Device for Application of MFSFET′s Neural Network)

  • 강이구;장원준;장석민;성만영
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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    • pp.55-58
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    • 1998
  • Recently, neural networks with self-adaptability like human brain have attracted much attention. It is desirable for the neuron-function to be implemented by exclusive hardware system on account of huge quantity in calculation. We have proposed a novel neuro-device composed of a MFSFET(ferroelectric gate FET) and oscillation circuit with CUJT(complimentary unijuction transistor) and PUT(programmable unijuction transistor). However, it is difficult to preserve ferroelectricity on Si due to existence of interfacial traps and/or interdiffusion of the constitutent elements, although there are a few reports on good MFS devices. In this paper, we have simulated CUJT and PUT devices instead of fabricating them and composed oscillation circuit. Finally, we have resented, as an approach to the MFSFET neuron circuit, adaptive learning function and characterized the elementary operation properties of the pulse oscillation circuit.

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강유전 고분자를 첨가한 유기태양전지의 효율 특성 (The Efficiency Characteristics of the Ferroelectric Polymer Added Organic Solar-cells)

  • 박자영;정치섭
    • 한국전기전자재료학회논문지
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    • 제29권9호
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    • pp.589-594
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    • 2016
  • P3HT:PCBM bulk heterojunction solar cells added with ferroelectric polymer were fabricated and characterized. By incorporating P3HT:PCBM solar cell with P(VDF-TrFE) ferroelectric additive, the power conversion efficiency was increased up to nearly 50%. Photoacoustic analysis on this phenomena was carried out for the first time. Through this study, we find that the ferroelectricity of the polymer additive plays the key role in the enhancement of the power conversion efficiency of the organic solar cell by suppressing the non-radiative recombination of charge transfer exciton more effectively.

초박막 폴리머 강유전체 박막의 특성 (Characteristics of Ultra-thin Polymer Ferroelectric Films)

  • 김광호
    • 반도체디스플레이기술학회지
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    • 제19권4호
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    • pp.84-87
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    • 2020
  • The properties of ultra-thin two-dimensional (2D) organic ferroelectric Langmuir-Blodgett (LB) films of the poly(vinylidene fluoride-trifluoroethylene) [P(VDF-TrFE)] were investigated to find possible applicability in flexible and wearable electronics applications. In the C-V characteristics of the MFM capacitor of 2-monolayer of 5 nm films, a butterfly hysteresis curve due to the ferroelectricity of P(VDF-TrFE) was confirmed. Typical residual polarization value was measured at 2μC/㎠. When the MFM capacitor with ultra-thin ferroelectric film was measured by applying a 10 Hz bipolar pulse, it was shown that 65% of the initial polarization value in 105 cycles deteriorated the polarization. The leakage current density of the 2-monolayer film was maintained at about 5 × 10-8 A/㎠ for the case at a 5MV/cm electric field. The resistivity of the 2-monolayer film in the case at an electric field at 5 MV/cm was more than 2.35 × 1013 Ω·cm.

MFS 구조로 적층된 Yttrium Manganates의 기판 변화에 따른 특성 연구 (Properties of Yttrium Manganates with MFS Structure Fabricated on Various Substates)

  • 강승구
    • 한국세라믹학회지
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    • 제40권2호
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    • pp.206-211
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    • 2003
  • Sol-gel 공정으로 제조된 YMnO$_3$박막의 결정상과 강유전특성에 미치는 기판종류와 버퍼층의 영향에 대하여 고찰하였다. Si(1OO) 기판위에는 hexagonal YMnO$_3$이 형성되었으나 Pt(111)/TiO$_2$/SiO$_2$/Si 기판위에는 hexagonal과 orthorhombic YMnO$_3$이 함께 형성되었다. 기판위에 미리 $Y_2$O$_3$버퍼층을 형성시킨 경우에는 Si(100)와 Pt(111)/TiO$_2$/SiO$_2$/Si 두가지 기판 모두 단일 hexagonal YMnO$_3$이 성장하였으며, 특히 c-축 배향성이 향상되었다. 박막내에 hexagonal과 orthorhombic YMnO$_3$이 혼재된 시편보다는 hexagonal 단일상이 형성된 시편이, 또한 단일상 시편중에서도 c-축 우선배향성이 좋은 시편이 그렇지 않은 시편에 비해 누설전류밀도 특성이 우수하였다. YMnO$_3$박막의 잔류분극값은 Si(100)기판을 사용했을 경우, 버퍼층 없이 제조된 시편은 0.14, 버퍼층이 삽입된 시편은 0.24$\mu$C/$ extrm{cm}^2$의 값을 나타내었다 한편 Pt(111)/TiO$_2$/SiO$_2$/Si 기판의 경우, 버퍼층 없이 형성된 YMnO$_3$시편은 이력곡선을 보여주지 못하였고, 버퍼층이 삽입된 시편은 1.14$\mu$C/$\textrm{cm}^2$의 잔류분극값을 나타내었다. 이상의 연구를 통하여 기판의 종류와 $Y_2$O$_3$버퍼층 삽입으로 YMnO$_3$박막의 결정상과 배향성을 제어함으로서 박막시편의 누설전류밀도 특성 및 강유전특성을 제어할 수 있음을 확인하였다.