• Title/Summary/Keyword: excitation spectrum

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The Luminescent Properties of SrTiO$_3$ :Al, Pr Red Phosphor (Al과 Pr이 첨가된 SrTiO$_3$ 적색 형광체의 발광 특성)

  • 박정규;류호진;박희동;최승철
    • Journal of the Korean Ceramic Society
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    • v.36 no.5
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    • pp.478-482
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    • 1999
  • SrTiO3 :Al, Pr phosphor as an oxide compound phosphor is expect to be applied for a field emission display(FED). In this phosphor the excitation spectrum shows a different tendency according to an addition Al3+ and Pr3+ In this excitation spectrum the main peak at 359 nm represent excitation level of Pr3+(1S0longrightarrow1D2 transition) and the absorption characteristic according to Ti/Sr molar ratio is influenced by the structure symmetry. The emission spectrum exhibits the red luminescence with the radiative decay of the 1D2 states(1D2 longrightarrow3H4 transition) The concentration quenching phenomena at 1D2 state shows up as Al3+ and Pr3+ ion concentration increases.

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A Study on the Pitch Alteration Technique by Subband Scaling in Speech Signal (서브밴드 스케일링에 의한 음성신호의 피치변경법에 관한 연구)

  • Kim, Young-Kyu;Bae, Myung-Jin
    • Speech Sciences
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    • v.10 no.4
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    • pp.137-147
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    • 2003
  • Speech synthesis can classify by synthesis way, that is waveform coding, source coding and mixture coding. Specially, waveform coding is suitable for high quality synthesis. However, it is not desirable by synthesis techniques of syllable or phoneme unit because it do not separate and handles excitation and formant part. Therefore, there is a need for pitch alteration method applied in synthesis by the rule in waveform coding. This study propose about pitch alteration method that use spectrum scaling after do to flatten spectra by subband linear approximation to minimize spectrum distortion. This paper show evaluation whether show excellency of some measure compared with LPC, Cepstrum, lifter function and method that propose. estimation method seeks distribution of each flattened signal and measured degree of flattened spectra Signal flattened is normalized, So that highest point amounts to zero, and distribution of signal ,whose average is zero, is calculated. this show result that measure the spectrum distortion rate to estimate performance of method that propose. The average spectrum distortion rate was kept below the average 2.12%, so the method that propose is superiors than existent method.

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Application of Response Spectrum Analysis Method for the Estimation of the Vertical Vibration in Structures (구조물의 연직진동해석을 위한 응답 스펙트럼 해석법의 활용)

  • 이동근
    • Proceedings of the Earthquake Engineering Society of Korea Conference
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    • 1998.10a
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    • pp.12-19
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    • 1998
  • Response spectrum analysis method is widely used for seismic analysis of building structure. Analysis of structural vibration for equipment, machine and moving loads are executed by time history analysis. This method is very complex, difficult and tedious. In this study, maximum response of structure for this case are simply and fast. calculated by mode shape and response spectrum for excitation. At first, Response spectrum and time history analysis for some earthquake is carried and investigate the error of maximum displacement response for R. S. A. Secondly, The process for response spectrum analysis in excitation are calculated, and maximum model response are combined by CQC (Complete Quadratic Combination) methods. Finally, Combining maximum displacement response is compared with one of time history analysis.

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Estimation of Excitation Force and Noise of Drum Washing Machine at Dehydration Condition using Phase Reference Spectrum (위상 기준 스펙트럼을 이용한 드럼 세탁기 탈수 행정시의 가진력 및 방사소음 예측)

  • Kim, Tae Hyeong;Jung, Byung Kyoo;Heo, So Jung;Jeong, Weui Bong
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.23 no.7
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    • pp.617-623
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    • 2013
  • Accurate prediction of the radiated noise is important to reduce the noise of the washing machine. It is also necessary to predict the excitation force accurately because excitation force can induce noise. In order to predict the excitation force acting on the washing machine, this paper conducts source identification method by use of phase reference spectrum. In this method, the transfer function between the cabinet and the motor through FEM and the measured response from the surface of the cabinet is used. The analysis of the radiation noise from the identified exciting force has been investigated. The comparison between the predicted SPL and the measured SPL at 1m apart from the front side of the washing machine showed good tendency.

Dynamic Buckling Characteristics of Arch Structures by Sinusoidal Harmonic Excitation (정현형 조화하중에 의한 아치 구조물의 동적 좌굴 특성에 관한 연구)

  • 윤태영;김승덕
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.17 no.1
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    • pp.67-74
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    • 2004
  • The dynamic instability for snapping phenomena has been studied by many researchers. Few paper deal with the dynamic buckling under the load with periodic characteristics, and the behavior under periodic excitation is expected the different behavior against STEP excitation. We investigate the fundamental mechanisms of the dynamic instability when the sinusoidal shaped arch structures are subjected to sinusoidal harmonic excitation with pin-ends. By using Newmark- β method, we can get the nonlinear displacement response, and using this analyze characteristics of the dynamic instability through the running response spectrum by FFT(Fast Fourier Transform).

Photoluminescence and Long-phosphorescent Characteristics of SrAl2O4:Eu2+,Dy3+ Phosphor by Glycine-nitrate Combustion Method (글리신-질산염 연소법으로 합성된 SrAl2O4:Eu2+,Dy3+ 형광체의 발광 및 장잔광 특성)

  • Lee, Young-Ki;Kim, Jung-Yeul;Lee, You-Kee
    • Korean Journal of Materials Research
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    • v.20 no.7
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    • pp.364-369
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    • 2010
  • A $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor powder with stuffed tridymite structure was synthesized by glycine-nitrate combustion method. The luminescence, formation process and microstructure of the phosphor powder were investigated by means of X-ray diffraction (XRD), scanning electron microscopy (SEM) and photoluminescence spectroscopy (PL). The XRD patterns show that the as-synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor was an amorphous phase. However, a crystalline $SrAl_2O_4 $ phase was formed by calcining at $1200^{\circ}C$ for 4h. From the SEM analysis, also, it was found that the as-synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor was in irregular porous particles of about 50 ${\mu}m$, while the calcined phosphor was aggregated in spherical particles with radius of about 0.5 ${\mu}m$. The emission spectrum of as-synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor did not appear, due to the amorphous phase. However, the emission spectrum of the calcined phosphor was observed at 520 nm (2.384eV); it showed green emission peaking, in the range of 450~650 nm. The excitation spectrum of the $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor exhibits a maximum peak intensity at 360 nm (3.44eV) in the range of 250~480 nm. After the removal of the pulse Xe-lamp excitation (360 nm), also, the decay time for the emission spectrum was very slow, which shows the excellent longphosphorescent property of the phosphor, although the decay time decreased exponentially.

Determination excitation spectrum for the sinusoidal vibration test of the small satellite launch vehicle (소형 위성 발사체의 정현파 진동 시험을 위한 가진 입력 결정)

  • Park, S.H.;Youn, S.H.;Seo, S.H.;Jeong, H.K.;Jang, Y.S.
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2006.05a
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    • pp.193-196
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    • 2006
  • Vibration overtests have been common problems in aerospace industry. A test item can be overtested at its resonances when it is excited by the traditional spectrum enveloping peaks in the field acceleration spectrum. This paper introduces the method of modifying the excitation specification to alleviate the overtesting problem. A vibration analysis was performed to estimate interface forces and acceleration responses. A finite element model that was verified by an extensive modal test enabled us to shape the acceleration input accurately The produced notched input will be used in the sinusoidal vibration test of the small satellite launch vehicle.

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Laser-Induced Fluorescence Excitation Spectrum and $CF_3$ Torsional Potential Energy Function of 7-Amino-4-(trifluoromethyl)coumarin in Its $S_1$ Electrode Excited State

  • 추재범;김택수;최영식
    • Bulletin of the Korean Chemical Society
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    • v.17 no.5
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    • pp.461-463
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    • 1996
  • The laser-induced fluorescence excitation spectrum of 7-amino-4-(trifluoromethyl)coumarin in a supersonic jet has been recorded in the 340-352 nm region. The electronic band origin was observed at 28622.8 cm-1. Vibrational assignments for the three fundamental low-frequency modes and eight combination bands have been made for the S1 electronic excited state. The out-of-plane vibrations of this molecule have been characterized from the low-frequency assignments of the spectrum. The periodic potential energy function for the CF3 torsion, which satisfactorily fits the observed data, were also determined to be V(Φ)=95X(1-cos3Φ)-32X(1-cos6Φ) where Φ is the torsional angle. The relatively low torsional barrier of 99 cm-1 in S1 state could be explained by the small steric interactions between the functional groups attached to a bicyclic ring.

Luminescence, Excitation and Far-infrared Spectroscopy of cis-$\alpha$-Dichlorotriethyleneteraminechromium(III) Chloride

  • 최종하
    • Bulletin of the Korean Chemical Society
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    • v.19 no.5
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    • pp.575-579
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    • 1998
  • The 77 K luminescence and excitation spectra, and 298 K infrared and absorption spectra of $cis-{\Alpha}-[Cr(trien)Cl_2]Cl{\cdot}H_2O$ (trien=triethylenetetramine) have been measured. Ligand field electronic transitions due to spin-allowed and spin-forbidden are assigned. The zero-phonon line in the excitation spectrum splits into two components by $198\; cm^{-1}$, and the large $^2E_g$ splitting can be reproduced by the modern ligand field theory. It is confirmed that nitrogen atoms of the trien ligand have a strong σ-donor character, but chloride ligand has weak σ- and π -donor properties toward chromium(III) ion.

Oil Fluorescence Spectrum Analysis for the Design of Fluorimeter (형광 광도계 설계인자 도출을 위한 기름의 형광 스펙트럼 분석)

  • Oh, Sangwoo;Seo, Dongmin;Ann, Kiyoung;Kim, Jaewoo;Lee, Moonjin;Chun, Taebyung;Seo, Sungkyu
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.18 no.4
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    • pp.304-309
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    • 2015
  • To evaluate the degree of contamination caused by oil spill accident in the sea, the in-situ sensors which are based on the scientific method are needed in the real site. The sensors which are based on the fluorescence detection theory can provide the useful data, such as the concentration of oil. However these kinds of sensors commonly are composed of the ultraviolet (UV) light source such as UV mercury lamp, the multiple excitation/emission filters and the optical sensor which is mainly photomultiplier tube (PMT) type. Therefore, the size of the total sensing platform is large not suitable to be handled in the oil spill field and also the total price of it is extremely expensive. To overcome these drawbacks, we designed the fluorimeter for the oil spill detection which has compact size and cost effectiveness. Before the detail design process, we conducted the experiments to measure the excitation and emission spectrum of oils using five different kinds of crude oils and three different kinds of processed oils. And the fluorescence spectrometer were used to analyze the excitation and emission spectrum of oil samples. We have compared the spectrum results and drawn the each common spectrum regions of excitation and emission. In the experiments, we can see that the average gap between maximum excitation and emission peak wavelengths is near 50 nm for the every case. In the experiment which were fixed by the excitation wavelength of 365 nm and 405 nm, we can find out that the intensity of emission was weaker than that of 280 nm and 325 nm. So, if the light sources having the wavelength of 365 nm or 405 nm are used in the design process of fluorimeter, the optical sensor needs to have the sensitivity which can cover the weak light intensity. Through the results which were derived by the experiment, we can define the important factors which can be useful to select the effective wavelengths of light source, photo detector and filters.