• Title/Summary/Keyword: ethylene groups

Search Result 250, Processing Time 0.028 seconds

Clinicopathological Diagnosis of Gentamicin and Ethylene glycol Induced Acute Renal Failure in Dogs (개에서 Gentamicin과 Ethylene glycol에 임상병리학적 진단)

  • 김지현;이영재;이경갑
    • Journal of Veterinary Clinics
    • /
    • v.17 no.2
    • /
    • pp.327-333
    • /
    • 2000
  • The diagnostic method was, evaluated in experimentally induced acute renal failure in doges. Ten male dogs weighing from 5 to 10 kg were assigned to two groups(gentamicin & ethylene glycol treated group) al random. Gentamicin sulfate at 10 mg/kg of body weight, t.i.d., for 7 days and ethylene glycol at 3 ml/kg of body weight once used in a randomized complete block design with tee treatments in block. The samples(blood, urine) were collected before and 1,3,5,7,9 and l1th day after administration. The serum creatinine concentration and BUN(blood urea nitrogen) were sig- nificantly increased at the 7th day than before administration in gentamicin treated group (p<0.05), bolt there was significant increase at the 1st day than before administration in ethylene glycol treated group(p<0.05). The urine GGT(gramma glutamyl transpeptidase) and GGT/creatinine were significantly increased at the 1st (lay after administration in gentamicin treated group (p<0.05). But in ethylene glycol treated group, there was no significant changes. The value of FENa (fractional excretion of sodium) was significantly increased at the 3rd day after administration in gentamicin treated group and the 1 st day after administration in ethylene glycol treated group (p<0.05). These results suggest that FENa was a good parameter of renal function in dogs with acute renal failure.

  • PDF

Control of Molecular Weight and Terminal Groups of Poly(3-hydroxybutyrate) in Bio-synthesis (미생물 합성에 의한 poly(3-hydroxybutyrate)의 분자량과 말단관능기 제어)

  • Lee, Chan Woo
    • Textile Coloration and Finishing
    • /
    • v.30 no.2
    • /
    • pp.130-140
    • /
    • 2018
  • In the bio-synthesis of poly(3-hydroxybutyrate)(PHB), which is a kind of poly(3-hydroxyalkanoate)(PHA), aimed to control the low molecular weight of PHB and obtain a telechelic PHB. As a result of incubation of R. eutropha at $30^{\circ}C$ with ethylene glycol added as a chain transfer agent, PHB content on the dry cell weight increased up to 24h, however, it decreased after that, and the molecular weight of PHB increased from 9h to 12h, and then, decreased up to 72h. The decrease of the content and the molecular weight of PHB indicates that PHB was decomposed as an energy source in bacterial cells and was incorporated into metabolic pathways. $^1H-NMR$ of the obtained PHB after incubation for 72h was measured to determine the terminal groups of the PHB during incubation. As the results of $^1H-NMR$ measurement, the peaks derived from ethylene glycol in both terminals of PHB were observed. Which indicate that the terminal reaction was caused by the addition of ethylene glycol, and that telechelic PHB having hydroxyl group at the both terminals where molecular weight was controlled was successfully synthesized.

The Preparation and Electrochemical Properties of Pore-filled and Polystyrene-based Anion-exchange Membranes Using Poly(ethylene glycol)methyl Ether Methacrylate (Poly(ethylene glycol)methyl Ether Methacrylate를 이용한 세공충전 폴리스티렌계 음이온 교환막의 제조 및 전기화학적 특성)

  • Mun, Hye Jin;Choi, Jae Hak;Hong, Young Taik;Chang, Bong Jun
    • Membrane Journal
    • /
    • v.25 no.6
    • /
    • pp.515-523
    • /
    • 2015
  • While commercial polystyrene-based ion exchange membranes have simple manufacturing processes, they also possess poor durability due to their brittleness. Poly(ethylene glycol)methyl ether methacrylate with hydrophilic side chains of poly(ethylene glycol) was used as a co-monomer to make the membranes have improved flexibility. Hydrophilicity/hydrophobicity of the anion exchange membranes were able to be adjusted by varying the chain lengths of the poly(ethylene glycol). For the preparation of the anion exchange membranes, a porous PE substrate was immersed into monomer solutions and thermally polymerized. The prepared membranes were subsequently reacted with trimethylamine to produce anion exchange functional groups, Quaternary ammonium salts. The prepared pore-filled anion exchange membranes were evaluated in terms of ion exchange capacity, electric resistance, elongation at break and water uptake.

Stability Assessment on Materials of Cultural Property by Fumigants Containing Ethylene Oxide (Ethylene oxide계 훈증 약제에 의한 문화재 재질의 안정성 연구)

  • Jeong, Soyoung;Kim, Young-hee;Lee, Jeung-min
    • Korean Journal of Heritage: History & Science
    • /
    • v.48 no.3
    • /
    • pp.46-59
    • /
    • 2015
  • This study was conducted focusing on the stability on materials of cultural property when the fumigant containing ethylene oxide was applied among some kinds of fumigant. Four kinds of specimens from paper, textile, metal and pigment were prepared to compare color difference, weight, surface condition before and after treatment and FT-IR analysis was carried out on specimens of paper and textile. In the case of fumigation treatment, it was conducted by two groups : one is made up of specimens with the non-fumigation as control groups, the other is made up of specimens treated with ethylene oxide + $HFC_{134a}$ and ethylene oxide + $CO_2$ as experimental groups. The result of color difference showed that there were color differences on the specimens of Hanji(Korean traditional paper), silver, cotton, ramie and yellow pigment. Especially, it was found out there was color change more than 6.0 on average from the silver specimen. However, in the silver specimen's case, color change in the non-fumigated specimen was relatively higher than those of fumigant-treated specimens, therefore, it is judged that fumigant doesn't have a decisive effect on color change in specimens, but required caution while fumigating. The result of weight measurement, there were totally 0~2% weight changes and the slightest change was found in the metal specimen, the biggest change in the papers. The result of microscopic observation on the surface of specimens showed color changes and especially, the biggest change on the silver specimen was observed. But no change in components was identified from FT-IR analysis of papers and textiles.

Gas Separation Properties of Poly(ethylene oxide) and Poly(ethylene-co-vinyl acetate) Blended Membranes (Poly(ethylene oxide)와 Poly(ethylene-co-vinyl acetate)의 혼합막에 대한 기체분리 특성)

  • Lee, Hyun Kyung;Kang, Min Ji
    • Membrane Journal
    • /
    • v.27 no.2
    • /
    • pp.147-153
    • /
    • 2017
  • In this study, we investigated permeation properties of single gas ($N_2$, $O_2$, $CO_2$) through membranes composed of poly(ethylene oxide) (PEO) and poly(ethylene-co-vinyl acetate) (EVA) blend. The prepared membranes showed no new absorbance peaks, which indicate the physical blending of PEO and EVA by FT-IR analysis. SEM observation showed that the crystalline phase of PEO decreased with increasing EVA content in the PEO/EVA mixed matrix. DSC analysis showed that the crystallinity of the PEO/EVA blend membrane decreased with increasing EVA content. Gas permeation experiment was performed with various feed pressure (4~8 bar). The permeability increased in the following order: $N_2$ < $O_2$ < $CO_2$. The permeability of $CO_2$ in PEO/EVA blend membranes were increased with increasing feed pressure, However, the permeability of $N_2$ and $O_2$ were independent of feed pressure. On the other hand, the permeability of all the gases in PEO/EVA blend membranes increased with increasing amorphous EVA content in semi-crystalline PEO. In particular, the blend membrane with 40 wt% EVA showed $CO_2$ permeability of 64 Barrer and $CO_2/N_2$ ideal selectivity of 61.5. The high $CO_2$ permeability and $CO_2/N_2$ ideal selectivity are attributed to strong affinity between the polar ether groups of PEO or the polar ester groups of EVA and polar $CO_2$.

Improvement of Solar Cell Efficiency by Modification of Cellulose Acetate Propionate for Ag paste (전극용 Ag Paste의 Cellulose Acetate Propionate(CAP) 개질에 따른 태양전지 효율 향상)

  • Kim, Dong Min;Lim, Jong Chan;Kim, Jin Hyun;Cha, Sang-Ho;Lee, Jong-Chan
    • Korean Journal of Materials Research
    • /
    • v.28 no.4
    • /
    • pp.227-234
    • /
    • 2018
  • We investigate the effect of the modification of cellulose acetate propionate as an organic vehicle for silver paste on solar cell efficiency. For the modification of cellulose acetate propionate, poly(ethylene glycol) is introduced to the hydroxyl groups of a cellulose acetate propionate backbone via esterification reaction. The chemical structure and composition of poly(ethylene glycol) functionalized cellulose acetate propionate is characterized by Attenuated total reflectance Fourier transform infrared, $^1H$ nuclear magnetic resonance, differential scanning calorimetry and thermogravimetric analysis. Due to the effect of structural change for poly(ethylene glycol) functionalized cellulose acetate propionate on the viscosity of silver paste, the solar cell efficiency increases from 18.524 % to 18.652 %. In addition, when ethylene carbonate, which has a structure similar to poly(ethylene glycol), is introduced to cellulose acetate propionate via ring opening polymerization, we find that the efficiency of the solar cell increases from 18.524 % to 18.622 %.

Effects of Ethylene Oxide and Gamma Energy on the Flavor-Related Components of Mushrooms (Lentinus edodes) (표고버섯의 향미관련 성분에 대한 에틸렌옥시드와 감마에너지의 영향)

  • 권중호;변명우;정신교;조한옥
    • Journal of Food Hygiene and Safety
    • /
    • v.7 no.1
    • /
    • pp.7-14
    • /
    • 1992
  • Flavor-related components were analyzed for dried oak mushrooms (Lentinus edodes) when subjected to ethylene oxide and gamma energy. Volatile flavor components identified by GC and GC-MS were composed primarily of l-oden-3-ol (72.8%), 3-octanone (11.5%) and dimethyl disulfide (6.7%). Most of volatile components were shown labile to the standard cycle of ethylene oxide and 5 kGy-gamma energy, while insignificant changes were observed in the contents of free sugars (mannitol, arabitol, trehalose) and free amino acids. Instrumental analysis have shown, however, that the deterimental effects on flavor-related components were more apparent in EO-fumigated groups than in gamma-irradiated ones, even though the organo-leptic test revealed no significant differences between treated samples and the corresponding control.

  • PDF

Preparation of Poly(ethylene terephthalate) fibers containing Pely(hydroxy ether of bisphenol A) (Poly(hydroxy ether of bisphenol A)를 함유한 PET섬유 제조)

  • Lim, Sang Kyu;Park, Kwang Hyun;Son, Tae Won;Song, Jae Soo
    • Textile Coloration and Finishing
    • /
    • v.9 no.2
    • /
    • pp.17-24
    • /
    • 1997
  • PET/PHE blends were prepared by the mixing of poly(ethylene terephthalate) and poly(hydroxyether of bisphenol A) at melt state above PET melting temperature and modified PET fibers having less than 5 wt% of PHE were also prepared by the melt spinning of the PET/PHE blends. The PET/PHE blends were able to prepare by means of physical mixing concept, except the chemical interaction between hydroxyl groups of PHE and ester groups of PET. It has been revealed that the modified PET fibers have some hydrophilic properties such as low contact angle and easy-dyeable characters.

  • PDF

Fluorescence and Laser Light Scattering Studies of Modified Poly(ethylene-co-methylacrylate0 Ionomers on the Formation of Stable Colloidal Nanoparticles in Aqueous Solution

  • 여상인;우규환
    • Bulletin of the Korean Chemical Society
    • /
    • v.19 no.10
    • /
    • pp.1054-1059
    • /
    • 1998
  • Fluorescence and dynamic light scattering measurements were applied to the study of formation and structure of aggregated colloidal particles in modified poly(ethylene-co-methylacrylate) ionomers in aqueous solution. Both 8-anillino-l-naphthalene-sulfonic acid (ANS) and pyrene were used as fluorescence probe to obtain the information on the structure of particle surface and inside, respectively. Three different ionomers used in this study started to aggregate at very dilute concentration, 3-8 x 10-6 g/mL. In this study, we demonstrate that the polyethylene ionomers can form stable nanoparticles. The hydrophobic core made of the polyethylene backbone chains is stabilized by the ionic groups on the particle surface. Such a formed stable nanoparticles have a relatively narrow size distribution with an average radius in the range of 27-48 nm, depending on the kind of ionic groups. Once the stable particles are formed, the particle size distributions were nearly constant. This study shows another way to prepare surfactant-free polyethylene nanoparticles.