• Title/Summary/Keyword: ethylene contents

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The Compressive Strength and Durability Properties of Polypropylene Fiber Reinforced EVA Concrete (폴리프로필렌 섬유 보강 EVA 콘크리트의 압축강도 및 내구성)

  • Nam, Ki Sung;Sung, Chan Yong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.57 no.4
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    • pp.11-19
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    • 2015
  • The important properties of EVA (ethylene vinyl acetate) redispersible polymer was waterproof, densification of internal pore space of concrete and ball bearing and micro filler. Also, the significant role of polypropylene(PP) fiber was crack control and blockade of movement for deterioration factors. The most studies for EVA were limited in the field of mortar and PP fiber reinforced concrete had been studied in the state of being restricted unit water content, rich mix and mixing much of the fiber without considering construction site. Therefore, the control mix design were applied in ready mixed concrete using 10 % fly ash of total cement weight used in batch plant. On the basis of control mix design, EVA contents ranging from 0 % to 10 % of total cement weight and PP fiber contents ranging from 0 % to 0.5 % of EVA concrete volume were used in the mix designs. The results showed the maximum compressive strength value was measured at EVA 5.0 % and PP fiber 0.1 %, the minimum water absorption ratio was at EVA 10 % and PP fiber 0 %, the durability factor for freezing and thawing resistance was at EVA 5.0 % and PP fiber 0.3 % and the minimum weight reduction ratio of resistance to sulfuric acid attack was at EVA 10 % and PP fiber 0.5 % after curing age 42days. Meanwhile, From these results, PP fiber reinforced EVA concrete would be very benefit, if each optimal mix types were used in hydraulic structures, underground utilities and agricultural structures.

Enhancement of Skin Color by Postharvest UV Irradiation in 'Fuyu' Persimmon Fruits (수확 후 자외선 조사에 의한 '부유' 단감의 과피 착색 증진)

  • Choi, Seong-Jin
    • Horticultural Science & Technology
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    • v.29 no.5
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    • pp.441-446
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    • 2011
  • The effects of UV irradiation, as a hormetic stimulus, on the postharvest persimmon fruits (Diospyros kaki cv. Fuyu) were investigated in regards to the change of carotenoid contents and flesh softening, when the UV irradiation was combined with or without the pretreatment of 1-methylcyclopropene (1-MCP) as an ethylene action inhibitor. The major carotenoid pigments in persimmon fruits were ${\beta}$-carotene, lycopene and ${\beta}$-cryptoxanthin. Of them, the lycopene was a pigment, which increased markedly after harvest. UV irradiation increased the contents of ${\beta}$-carotene and lycopene, enhancing the skin color to scarlet. The treatment accelerated however also the softening of fruit flesh. But the softening of UV irradiated fruits could be delayed significantly by pretreatment with 1-MCP without reducing the advantageous effect of UV irradiation on the carotenoid increase.

Synthesis of Polyurethane/Epoxy Hybrid Resin used for Damper of Loudspeaker (스피커용 댐퍼에 사용되는 폴리우레탄/에폭시 하이브리드 수지의 합성)

  • Choi, Hyun-Seuk;Choi, Dong-Ho;Huh, Man-Woo
    • Textile Coloration and Finishing
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    • v.28 no.1
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    • pp.40-47
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    • 2016
  • As a coating material for loudspeaker dampers, resilient polyurethane/epoxy hybrid resins were synthesized to replace conventional phenol resin and examined the physical properties, which are not only environmentally friendly but also not harmful to human. Five types of polyurethane resins were synthesized in the step-shot method using methylene diisocyanate, three polyols such as poly tetramethylene ether glycol(PTMEG, MW:2000), poly(1,4-buthylene adipate(PBAP, MW:2000), and poly carbonatediol(PCD, MW:2000), and three chain extenders such as ethylene glycol(EG), neopentyl glycol(NPG), and 1,4-buthandiol(1,4-BD). The five types of synthesized polyurethane resins and commercially available bisphenol A type epoxy resin were blended in weight ratios of 90:10, 70:30, and 50:50 to synthesize 15 types of polyurethane/epoxy hybrid resins. Among the polyurethane resins, the one that was synthesized using PCD and 1,4-BD showed excellent tensile strength, 100% modulus, low extension, and relatively high viscosity. Polyurethane/epoxy hybrid resins with higher epoxy resin contents showed better thermal properties and water resistance while those with higher polyurethane contents showed higher flexibility. The polyurethane/epoxy hybrid resin made by blending the polyurethane based on PCD and 1,4-BD with a bisphenol A type epoxy resin in a weight ratio of 70:30 was identified to be the most suitable to be used in speaker dampers.

Carotenoids pigment extraction from a wasted persimmon peel (폐기 감 과피를 이용한 Carotenoids색소의 추출)

  • 오상룡;차원섭;박준희;조영제;홍주헌;이원영
    • Food Science and Preservation
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    • v.8 no.4
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    • pp.456-461
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    • 2001
  • To develop the use of natural pigment for food, carotenoids from wasted persimmon peel were extracted with seven organic solvents. Among the solvents, acetone was a high yielding solvent of carotenoids. Extraction trends depending on process variables(temperature, time, solvent ratio to persimmon peel) were explained through response surface which was made by central composite experimental design. Carotenoid contents were increased with the extraction time and solvent ratio but it decreaed in the higher experimental design. Carotenoid contents were increased with the extraction time and solvent ratio but it decreased in the higher extraction temperature. The optimum conditions of extraction process variables were predicted as 29$\^{C}$, 93min. at fixed solvent ratio(1:27).

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Linear Low Density Polyethylene Preparation by Titanium-Based Ziegler-Natta Catalysts (티탄이 기본인 Ziegler-Natta 촉매에 의한 선형저밀도폴리에틸렌의 제조)

  • Dong-Ho Lee;Kyung-Eun Min;Cha-Ung Kim
    • Journal of the Korean Chemical Society
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    • v.31 no.1
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    • pp.110-117
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    • 1987
  • For the preparation of linear low density polyethylene (LLDPE), the copolymerization of ethylene and 1-butene was carried out with various catalysts of titanium alkoxidealkylaluminum compound in slurry phase. The effects of catalyst components, aging time, concentration of catalyst components, polymerization time and temperature on the catalytic activity and copolymer composition were examined. The properties of copolymer obtained were also considered with the correlation to the 1-butene contents. It has been found that the titanium tetra-n-butoxide-diethylaluminum chloride catalyst system was the most suitable for the production of LLDPE with higher catalytic activity, more 1-butene content and less soluble parts. The density, glass transition temperature, melting point and heat of fusion of copolymer were decreased with increasing 1-butene contents.

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Evaluation of Fundamental Properties of Warm-mix Recycled Asphalt Concretes (준고온 재생 아스팔트 콘크리트의 기본특성 평가)

  • Kim, Nam-Ho;Kim, Jin-C.;Hong, Jun-P.;Kim, Kwang-W
    • International Journal of Highway Engineering
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    • v.12 no.4
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    • pp.111-120
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    • 2010
  • This study evaluated strength properties of recycled asphalt concretes using warm-mix technology. Granite with maximum size of 13mm and penetration grade of 80-100 virgin binder were used for mixing in recycled mixtures. Mix design was performed using 20% and 30% RAP(coarse : fine= 6 : 4) contents. GPC, penetration, absolute viscosity and kinematic viscosity were measured for determining ratio of two warm-mix additives (Evotherm and Sasobit). Low-density polyethylene(LD) used as asphalt modifier for improving stiffness of recycled WMA mixtures in this study. Therefore, a total of 11 mixtures were prepared in this study; 8 warm-mix recycled mixtures(2 RAP contents${\times}$2 warm-mix additives${\times}$2 modifiers), 2 hot-mix recycled mixtures and 1 HMA virgin mixture(control). Deformation strength, indirect tensile strength, moisture sensitivity, permanent deformation by wheel tracking tests were measured out for evaluating fundamental properties of recycled asphalt concretes using warm-mix technology.

Melting Behavior of Uni-Axially Deformed Polyethylenes Containing Comonomers as Studied by in-situ Small and Wide Angle X-ray Scattering (실시간 소각 밑 광각 X-선 산란을 이용한 일축 변형된 공단량체 함유 폴리에틸렌의 용융 거동)

  • Cho, Tai-Yon;Jeon, Hye-Jin;Ryu, Seok-Gn;Song, Hyun-Hoon
    • Polymer(Korea)
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    • v.33 no.2
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    • pp.183-188
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    • 2009
  • Structural rearrangements of uni-axially deformed polyethylenes containing 1-octene comonomer and HDPE upon heating were investigated by time-resolved small and wide angle X-ray scattering techniques. During heating, structural changes including crystal transformation and lamellar rearrangement noted were very different depending on the comonomer contents. At low comonomer content below 2 wt%, inverse martensitic transformation of crystal lattice from monoclinic to orthorhombic cell and the rearrangement of broken lamellar units into more ordered and perfect lamellar stacks were noted with the temperature increase. At high contents above 9.5 wt%, however, polyethylene copolymers showed neither the crystal transformation nor lamellar rearrangement that can be attributed to low crystallinity and high content of branch units.

Effects of natural calcium-coated package papers on the fruit quality and storage life of 'Hongro' apple. (수확 한 사과 '홍로'에서 천연칼슘이 코팅된 포장지 적용이 과실품질 및 저장성에 미치는 영향)

  • Moonm, B.W.;Lee, Y.C.;Jung, H.W.;Chung, T.S.
    • Journal of Practical Agriculture & Fisheries Research
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    • v.12 no.1
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    • pp.53-62
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    • 2010
  • This study was designed to examine whether 'Hongro' apples packaged with natural calcium-coated package papers was fresher maintained than fruit held in not-packaged tray, and whether postharvest physiology of the fruits was affected by calcium-coated papers, or not. The summarized results were as follows; Soluble solids contents and firmness of fruit were higher room temperature(20~25℃) after 4 week and 14 week in cold storage(0~1℃) by calcium-coated package papers. but total acid contents in juice and Hunter a value of peel were trended to decrease in room temperature and cold storage. Weight loss of fruit, decay fruit and CO2 evolution were decreased by calcium and wax-coated package papers in room temperature storage condition. Also, excellent fruits increased. Ethylene evolution in fruit were not different by package paper and storage condition.

Fruit Quality and Storability by Harvest Time at 'Fuji'/M.9 Apple Orchard Located in the Area with a High Air Temperature during the Fall Season (가을철 기온이 높은 지역에 위치한 '후지'/M.9 사과원의 수확시기에 따른 과실품질과 저장성)

  • Sagong, Dong-Hoon;Kweon, Hun-Joong;Song, Yang-Yik;Park, Moo-Yong;Kang, Seok-Beom;Yoon, Tae-Myung
    • Horticultural Science & Technology
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    • v.31 no.4
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    • pp.437-446
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    • 2013
  • This study was conducted for three years (2007, 2009, and 2010) to investigate the changes in fruit quality during maturation, and the quality and storage ability of fruits harvested at different times of 'Fuji' apple in Daegu region with a high air temperature during the fall season. Changes in apple fruit quality during the maturation period were investigated from 120-135 days to 183-198 days after full bloom. In comparing quality and storage ability of fruits harvested at different times, fruits harvested more than 180 days after full bloom were used. During the maturation period, poor coloring was the problem for 'Fuji' apple in Daegu region by the high air temperature about $20^{\circ}C$. In comparing quality of fruits harvested at different times, the soluble solid contents and hunter a value were increased by the extended harvest time. Fruit weight during harvest was not affected by different harvest time, while the fruit firmness and titratable acidity during harvest were decreased critically when the freezing damage happened. Ethylene production, fruit firmness, and titratable acidity during cold storage for twenty weeks did not differ according to the different harvest time. Soluble solid contents of fruits harvested at 216 days after full bloom in 2009 were similar at the time of harvest and cold storage. For fruits harvested at 201 days after full bloom, soluble solid content during cold storage was higher than during harvest time. However fruit firmness, soluble solid content, and titratable acidity after cold storage of fruit harvested after freezing damage was lower than those of the fruit harvested before freezing damage. The results show that the extended harvest time of 'Fuji' apples about 2-4 weeks from 180-200 days after full bloom in area with above-air temperature during fall season was seemed to be beneficial to enhancing soluble solid contents and fruit red color, but harvesting after the middle of November was dangerous because minimum air temperature began to fall under $-3.0^{\circ}C$.

Oxidation and Surface Functional Group Analyses under Ozone Treatment of Carbon Black (오존처리에 의한 카본 블랙의 산화와 표면 작용기 분석)

  • Yang, Se-In;Kim, Ki-Yeo;Rhyoo, Hae-Yoon;Cho, Sang-Je;Yoon, Kwang-Eui
    • Elastomers and Composites
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    • v.40 no.3
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    • pp.188-195
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    • 2005
  • Chemical and physical changes and the contents of functional groups in the carbon black surface after the ozone treatment was investigated using elemental analysis, pH, tint strength, DBP, $N_2SA$, IA, and acid-base reaction. As the treatment time was increased, surface structure, particle size and surface area of carbon black did not change, while surface oxygen contents increased, and pH decreased and then saturated after $1{\sim}2$ hour. The contents of carboxylic, lactone, hydroxyl, and carbonyl groups were analyzed with four bases such as $NaHCO_3,\;Na_2CO_3,\;NaOH$, and $NaOC_2H_5$. Before oxidation, the carbonyl group was dominantly present on the surface, but by increasing the treatment time, the contents of the carboxylic and carbonyl groups increased to a saturated level after $1{\sim}2$ hour. Before and after the oxidation, the lactone and hydroxyl groups were nearly absent. These results showed that the reaction mechanism of carbon black and ozone is similar to that of ethylene and ozone. Weight of oxidized carbon black was increased after treating AIBN, while free radical was slightly decreased by ESR analysis. When carbon black was treated with organic compounds containing mercapto- groups, the results of ESR showed that free radical peak intensity was almost diminished compared to original carbon black.