• Bulletin of the Korean Chemical Society
• /
• v.12 no.3
• /
• pp.334-342
• /
• 1991

To investigate the phase equilibria and structural properties of microemulsions, we study a simple phenomenological model on the basis of the cubic lattice cell with which the oil- and water-filled cells are connected one another, respectively. The surfactant is assumed to be insoluble in both oil and water, and to be adsorbed at the oil-water interface. The Schulman condition, according to which the lateral pressure of the surfactant layer is compensated by the oil-water interfacial tension, is found to hold to good approximation in the middle-phase microemulsion. Our results show that the oil- and water-filled domains in that microemulsion are about 50-150 $\AA$ across, and depend sensitively on the curvature parameters. The phase diagram is not symmetric in this model. It may be asymmetrized intrinsically by non-equivalency of oil and water. The two- and tree-phase equilibria including critical points and critical endpoints are found.

• Asian Journal of Atmospheric Environment
• /
• v.7 no.2
• /
• pp.72-84
• /
• 2013

In the study, pollution levels of indoor polycyclic aromatic hydrocarbons (PAHs) in public facilities (vapor phase or particulate phase) were evaluated, and a health risk assessment (HRA) was carried out based on exposure scenarios. Public facilities in Korea covered by the law, including underground subway stations, funeral halls, child care facilities, internet cafes (PC-rooms), and exhibition facilities (6 locations for each type of facility, for a total of 48 locations), were investigated for indoor assessment. For the HRA, individual excess cancer risk (ECR) was estimated by applying main toxic equivalency factor (TEF) values suggested in previous studies. Among the eight public facilities, internet cafes showed the highest average $PM_{2.5}$ concentration at $110.0{\mu}g/m^3$ (range: $83.5-138.5{\mu}g/m^3$). When assuming a risk of facility exposure time based upon the results of the surveys for each public facility, the excess cancer risk using the benzo(a)pyrene indicator assessment method was estimated to be $10^{-7}-10^{-6}$ levels for each facility. Based on the risk associated with various TEF values, the excess cancer risk based upon the seven types cancer EPA (1993) and Malcolm & Dobson's (1994) assessment method was estimated to be $10^{-7}-10^{-5}$ for each facility. The excess cancer risk estimated from the TEF EPA (2010) assessment was the highest: $10^{-7}-10^{-4}$ for each facility. This is due to the 10-fold difference between the TEF of dibenzo(a,e)fluoranthene in 2010 and in 1994. The internet cafes where smoking was the clear pollutant showed the highest risk level of $10^{-4}$, which exceeded the World Health Organization's recommended risk of $1{\times}10^{-6}$. All facilities, with the exception of internet cafes, showed a $10^{-6}$ risk level. However, when the TEFs values of the US EPA (2010) were applied, the risk of most facilities in this study exceeded $1{\times}10^{-6}$.

• The KIPS Transactions:PartA
• /
• v.18A no.3
• /
• pp.109-114
• /
• 2011

We describe a technique for automatically proving compiler optimizations sound, meaning that their transformations are always semantics-preserving. As is well known, IR (Intermediate Representation) optimization is an important step in a compiler backend. But unfortunately, it is difficult to detect and debug the IR optimization errors for compiler developers. So, we introduce a C level error check system for detecting the correctness of these IR transformation techniques. In our system, we first create an IR-to-C converter to translate IR to C code before and after each compiler optimization phase, respectively, since our technique is based on the Memory Comparison-based Clone(MeCC) detector which is a tool of detecting semantic equivalency in C level. MeCC accepts only C codes as its input and it uses a path-sensitive semantic-based static analyzer to estimate the memory states at exit point of each procedure, and compares memory states to determine whether the procedures are equal or not. But MeCC cannot guarantee two semantic-equivalency codes always have 100% similarity or two codes with different semantics does not get the result of 100% similarity. To increase the reliability of the results, we describe a technique which comprises how to generate C codes in IR-to-C transformation phase and how to send the optimization information to MeCC to avoid the occurrence of these unexpected problems. Our methodology is illustrated by three familiar optimizations, dead code elimination, instruction scheduling and common sub-expression elimination and our experimental results show that the C level error check system is highly reliable.

• Nuclear Engineering and Technology
• /
• v.52 no.6
• /
• pp.1120-1130
• /
• 2020

The CREOLE experiment performed In the EOLE critical facility located In the Nuclear Center of CADARACHE - CEA have allowed us to get interesting and complete experimental information on the temperature effects in the light water reactor lattices. To analyze these experiments with accuracy an elaborate calculation scheme using the Monte Carlo method implemented in the MCNP6.1 code and the ENDF/B-VII.1 cross section library has been developed. We have used the ENDF/B-VII.1 data provided with the MCNP6.1.1 version in ACE format and the Makxsf utility to handle the data in the specific temperatures not available in the MCNP6.1.1 original library. The main purpose of this analysis is the qualification of the ENDF/B-VII.1 nuclear data for the prediction of the Reactivity Temperature Coefficient while ensuring the ability of the MCNP6.1 system to model such a complex experiment as CREOLE. We have analyzed the case of UO₂ lattice with 1166 ppm of boron in ordinary water moderator in specified temperatures. A detailed comparison of the calculated effective multiplication factors with the reference ones [1] in room temperature presented in this work shows a good agreement demonstrating the validation of our 3D calculation model. The discrepancies between calculations and the differential measurements of the Reactivity Temperature Coefficient for the analyzed configuration are relatively small: the maximum discrepancy doesn't exceed 1,1 pcm/℃. In addition to the analysis of direct differential measurements of the reactivity temperature coefficient performed in the poisoned UO₂ lattice configuration, we have also analyzed integral measurements in UO₂ clean lattice configuration using equivalency of the integral temperature reactivity worth with the driver core fuel reactivity worth and soluble boron reactivity worth. In this case both of the ENDF/B-VII.1 and JENDL.4 libraries were used in our analysis and the obtained results are very similar.

• Explosives and Blasting
• /
• v.41 no.4
• /
• pp.1-8
• /
• 2023

On August 4, 2020, 2750 tons of ammonium nitrate stored in a storage warehouse at the Port of Beirut exploded. This explosion is said to be the largest ammonium nitrate explosion ever. By applying the TNT equivalency method, TNT equivalent amount corresponding to the explosion energy of 2750 tons of ammonium nitrate was calculated, and it is found to be 856 tons. Overpressure and impulse were calculated in a range up to 3600 m from the blast using the Kingery-Bulmash explosion parameter calculator tool. As the distance from the explosion center increases, the overpressure and impulse decrease exponentially, but the overpressure decreases more significantly, showing that overpressure is more affected by distance than the impact. As a result of applying the damage criteria to evaluate the effects of overpressure and impulse on the structure, the critical distances at which partial collapse, major damage, and minor damage to the structure occur are found to be approximately 500, 800, and 2200 m from the center of the explosion, respectively. The probit function was applied to evaluate the probability of damage to structures and human body. The points where the probability of collapse, major damage, minor damage, and breakage of window-panes to structures are greater than 50% are found to be approximately 500, 810, 2200, and 3200 m, respectively. For people within 200 m from the center of the explosion, the probability of death due to lung damage is more than 99%, and the 50% probability of eardrum rupture is approximately 300 m. The points with a 100% probability of death due to skull rupture and whole body impact due to whole body displacement are evaluated to be 300 and 100 m, respectively.

• Design & Manufacturing
• /
• v.6 no.2
• /
• pp.84-89
• /
• 2012

In recent years, technology of press plastic working having made remarkable progress. We can say this because it facilitates mass production and have superior performances in machining speed and equivalency of quality than other processing methods. In characteristics of press plastic working, mold manufacturing according to characteristics of each product should be preceded before processing and it has a great influence on machining speed and quality of products and etc according to manufacturing method. Therefore, mold design technology is a critical technology in press plastic working. There are lots of variables in press plastic working according to worked material, mold materials, conditions of heat treatment, clearance and so on. Abrasion of mold depends on these kind of conditions and sheared surface which is crucial for quality of product also depends on them. In this study, we conduct research on abrasion loss of mold according to 8, 10 and 12% of clearance for thickness of 1.0mm of worked material out of mold design variables of the products whose worked materials are high carbon steel and carbon tool steel by a practical experiment.

• Journal of Korean Society of Transportation
• /
• v.28 no.6
• /
• pp.65-74
• /
• 2010

This study aims at developing a method for estimating passenger car equivalency (PCE) values for various vehicle types that could be considered in estimating capacity and delay at intersections without traffic signals, especially at modern small 3-leg roundabouts. Unlike signalized intersections, the PCE value has not yet been treated explicitly in traffic operations involving unsignalized intersections. Both empirical and theoretical approaches for determining the PCE values at modern small 3-leg roundabouts were evaluated. As a result, the PCEs derived in this study were highly correlated with those of field measurements.

• Journal of the Korea Safety Management & Science
• /
• v.2 no.4
• /
• pp.33-43
• /
• 2000

The consequence analysis for the unconfined vapor cloud explosion(UVCE) accident by the continuous release of butane vapor was performed and effects of process parameters on consequences were analyzed in standard conditions. For the case of continuous release(87.8 kg/s) of butane vapor at 8 m elevated height in the debutanizing process of tile naphtha cracking plant operating at 877 kPa ＆ 346.75 K, we found that combustion ranges of dispersed vapor estimated by HMP model were 11.2~120.2 m and overpressures estimated by TNT equivalency model at 200 m were about 37.35~55.1 kPa. Also, overpressures estimated by Model UVCE I based on advective travel time to $X_{LFL}$ were smaller than those estimated by Model UVCE IIbased on real travel time between $X_{UFL}$ and $X_{LFL}$. At the same time, damage intensities at 200 m and effect ranges by overpressure could be predicted. Furthermore, simulation results showed that effects of operating pressures on consequences were larger than those of operating temperatures and results of accidents were increased with increasing operating pressures. At this time, sensitivities of overpressures for UVCE accident by the continuous release were about 5 kPa/atm.

• International Journal of Concrete Structures and Materials
• /
• v.7 no.3
• /
• pp.203-214
• /
• 2013

This study investigates quantitative methods for assessment of infrared analysis of concrete admixtures using correlation coefficients by performing IR scans following the ASTM C494/C494M-11 specifications. In order to achieve this goal, numerous IR scans were performed on specimens supplied by the manufacturer from different batches to ensure uniformity and equivalency. These scans were then analyzed to create correlation coefficients for each admixture. The correlation coefficients were used to quantitatively evaluate and interpret IR Scans of job samples. The study focused on 23 most commonly used concrete admixtures by the New Jersey Department of Transportation (NJDOT). They include air-entrainers, accelerators, retarders, water reducers, and other combinations of these admixtures. Their correlation coefficients were established by analyzing a total of 12 scans of each admixture from three different batches supplied by the manufacturer at different time intervals. In order to validate the obtained correlation coefficients and establish a target correlation, job samples were tested and compared to the obtained correlations. The study also evaluated the effects of drying time and using different types of KBr on correlation coefficients.

• ALGAE
• /
• v.26 no.1
• /
• pp.51-60
• /
• 2011

Similar to other species of Gigartinaceae Chondrus crispus has an alternation of perennial, isomorphic gametophytic and sporophytic generations. As these two generations co-exist independently within populations and obtain their resources in a similar manner, intraspecific competition is expected. In populations within the southern Gulf of St. Lawrence, fronds of both generations of C. crispus occur in similar numbers. This equivalency can be related to substratum instability, where the population is dynamic with a high turn-over rate of genets. These observations support a stochastic hypothesis to account for distribution of gametophytes and sporophytes in this area. Along the Atlantic coast of Nova Scotia, where the substratum is stable, gametophytes are overwhelmingly predominant. Gametophytic predominance is greatest in the lower littoral zone where C. crispus is abundant and space is limited. Under the fucoid canopy where "free-space" exists, the gametophyte to sporophyte ratio is lower. Gametophytic and sporophytic fronds are distributed equally among different size-classes and size-distribution is not considered a competitive factor. Previous studies have shown that sporophytic fronds of C. crispus are more susceptible to infections by endophytic algae and other pathogens, and are more heavily grazed by herbivores than are gametophytic fronds. Thus, mechanistic factors are strongly implied in the selection of gametophytes in the Atlantic population.