• Title/Summary/Keyword: equilibrium analysis

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Studies on Complex Formation in Aqueous Solution by Caffeine and Nicotinamide Interaction of Caffeine and Nicotinamide with Lidocaine and Saccharin (수용액중 Caffeine 또는 Nicotinamide 에 의한 Complex 형성에 대한 연구 Lidocaine 또는 Saccharin에 대한 Caffeine 또는 Nicotinamide의 상호작용)

  • 채동규
    • YAKHAK HOEJI
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    • v.7 no.1
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    • pp.1-7
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    • 1963
  • This investigation is the studies on the solubility analysis for several pharmaceuticals. The equilibrium reactions leading to complex formation of Caffeine and Nicotinamide with Lidocaine and Saccharin have been studied. The equilibrium constant of each complexes have also been calculated. It is shown that complex formation may lead to an increase in the solubilities of the reactants, and that Nicotinamide has more complexing activity than Caffeine. The influence of chemical structure of each components on interaction is also discussed.

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GLOBAL EXPONENTIAL STABILITY OF BAM NEURAL NETWORKS WITH IMPULSES AND DISTRIBUTED DELAYS

  • Shao, Yuanfu;Luo, Zhenguo
    • Journal of applied mathematics & informatics
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    • v.29 no.1_2
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    • pp.103-117
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    • 2011
  • By using an important lemma, some analysis techniques and Lyapunov functional method, we establish the sufficient conditions of the existence of equilibrium solution of a class of BAM neural network with impulses and distributed delays. Finally, applications and an example are given to illustrate the effectiveness of the main results.

Oscillatory modes generated by Hopf bifurcations in coupled four oscillators

  • Kitajima, Hiroyuki;Kawakami, Hiroshi
    • Proceedings of the IEEK Conference
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    • 2002.07c
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    • pp.1634-1637
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    • 2002
  • We examine the oscillatory modes generated by the Hopf bifurcations of non-origin equilibrium points in the four-coupled oscillator system. The Hopf bifurcations of the equilibrium points and the generated oscillatory modes are classified. By numerical bifurcation analysis we observe various interesting synchronized states caused by symmetry-breaking bifurcations.

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Computable General Equilibrium Analysis of Energy Markets with Imperfect Competition and Scale Economy (불완전경쟁 및 규모의 경제가 에너지 산업에 미치는 영향)

  • Park, Chang Won;Kim, Gene Uhc
    • Environmental and Resource Economics Review
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    • v.11 no.2
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    • pp.291-319
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    • 2002
  • This Paper investigates imperfect competition and economy of scale on Korean energy markets based on computable general equilibrium model. Some industries like energy sector have exhibited that their economies have strong economies of scale and imperfect competition. Thus these industrial organization facts should be incorporated into CGE model. In our model, non-competitive markets are adopted and compare these results with convention perfect competition model.

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CONVERGENCE ANALYSIS OF THE EAPG ALGORITHM FOR NON-NEGATIVE MATRIX FACTORIZATION

  • Yang, Chenxue;Ye, Mao
    • Journal of applied mathematics & informatics
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    • v.30 no.3_4
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    • pp.365-380
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    • 2012
  • Non-negative matrix factorization (NMF) is a very efficient method to explain the relationship between functions for finding basis information of multivariate nonnegative data. The multiplicative update (MU) algorithm is a popular approach to solve the NMF problem, but it fails to approach a stationary point and has inner iteration and zero divisor. So the elementwisely alternating projected gradient (eAPG) algorithm was proposed to overcome the defects. In this paper, we use the fact that the equilibrium point is stable to prove the convergence of the eAPG algorithm. By using a classic model, the equilibrium point is obtained and the invariant sets are constructed to guarantee the integrity of the stability. Finally, the convergence conditions of the eAPG algorithm are obtained, which can accelerate the convergence. In addition, the conditions, which satisfy that the non-zero equilibrium point exists and is stable, can cause that the algorithm converges to different values. Both of them are confirmed in the experiments. And we give the mathematical proof that the eAPG algorithm can reach the appointed precision at the least iterations compared to the MU algorithm. Thus, we theoretically illustrate the advantages of the eAPG algorithm.

Modified Ammonia Removal Model Based on Equilibrium and Mass Transfer Principles

  • Shanableh, A.;Imteaz, M.
    • Bulletin of the Korean Chemical Society
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    • v.31 no.7
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    • pp.1920-1926
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    • 2010
  • Yoon et $al.^1$ presented an approximate mathmatical model to describe ammonia removal from an experimental batch reactor system with gaseous headspace. The development of the model was initially based on assuming instantaneous equilibrium between ammonia in the aqueous and gas phases. In the model, a "saturation factor, $\beta$" was defined as a constant and used to check whether the equilibrium assumption was appropriate. The authors used the trends established by the estimated $\beta$ values to conclude that the equilibrium assumption was not valid. The authors presented valuable experimental results obtained using a carefully designed system and the model used to analyze the results accounted for the following effects: speciation of ammonia between $NH_3$ and $NH^+_4$ as a function of pH; temperature dependence of the reactions constants; and air flow rate. In this article, an alternative model based on the exact solution of the governing mass-balance differential equations was developed and used to describe ammonia removal without relying on the use of the saturation factor. The modified model was also extended to mathematically describe the pH dependence of the ammonia removal rate, in addition to accounting for the speciation of ammonia, temperature dependence of reactions constants, and air flow rate. The modified model was used to extend the analysis of the original experimental data presented by Yoon et $al.^1$ and the results matched the theory in an excellent manner.

ANALYSIS ON STEAM CONDENSING FLOW USING NON-EQUILIBRIUM WET-STEAM MODEL (비평형 습증기 모델을 적용한 증기 응축 유동 해석)

  • Kim, C.H.;Park, J.H.;Ko, D.G.;Kim, D.I.;Kim, Y.S.;Baek, J.H.
    • Journal of computational fluids engineering
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    • v.20 no.3
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    • pp.1-7
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    • 2015
  • When the steam is used as working fluid in fluid machinery, different from other gases as air, phase transition (steam condensation) can occur and it affects not only the flow fields, but also machine performance & efficiency. Therefore, considering phase transition phenomena in CFD calculation is required to achieve accurate prediction of steam flow and non-equilibrium wet-steam model is needed to simulate realistic steam condensing flow. In this research, non-equilibrium wet-steam model is implemented on in-house code(T-Flow), the flow fields including phase transition phenomena in convergent-divergent nozzle are studied and compared to results of advance researches.

Analysis of Contaminants in a $CH_4-O_2$ Vitiated Air Heater ($CH_4-O_2$ Vitiated 공기가열기에서의 오염도 분석)

  • Na, Jae-Jeong;Lee, Jung-Min;Lim, Jin-Shik
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.447-450
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    • 2010
  • This study was conducted to explore the flow contamination in the $CH_4-O_2$ vitiated air heater. Non-equilibrium and equilibrium calculation were made of the flow processes in the heater and nozzle assuming the inviscid and one dimensional flow. The results were compared with the measurement data. The overall results of this study showed additional non-equilibrium calculation should be considered to assess the presence of NO, which species could yield the combustion delay or no reaction, as a contaminant.

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