• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.03b
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• pp.30-30
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• 2010

In order to prepare a epoxy/multilayered silicate nanocomposite, various mixing processes were tried and it was found that the silicate could not be fully exfoliated in the epoxy matrix through various mechanical mixing process. In this study, a new AC electric application method was developed to prepare epoxy/multilayered silicate nanocomposite. The exfoliation of the silicate was confirmed by XRD (X-Ray Diffraction) and TEM observation.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.99-99
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• 2010

Polymer nanocomposite has been attracting much attention as a new insulation material, since homogeneous dispersion of nm-sized inorganic fillers can improve various properties significantly. In this paper, various kinds of epoxy based nanocomposites were made and AC breakdown strength of Nano-TiO2 and micro-silica filler mixture of epoxy based composites were studied by sphere to sphere electrode. Moreover, nano- and micro-filler combinations were adopted as an approach toward practical application of nanocomposite insulation materials. Nano-TiO2 particle size is about 10nm and composites ratio was resin (100) : hardener (82) : accelerator (1.5). AC breakdown test was performed at room temperature (25 [$^{\circ}C$], 80 [$^{\circ}C$] and 100 [$^{\circ}C$] in the vicinity of Tg (90[$^{\circ}C$]). And thermal conductivity were measured by ASTM-D5470.

• Macromolecular Research
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• v.14 no.6
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• pp.610-616
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• 2006

An azoinitiator linked to an epoxy oligomer, which could easily diffuse into the organoclay gallery and swell it, was used as an initiator to enhance the delamination of an organoclay, Cloisite 25A, in a matrix of styrenic polymers, poly(styrene-co-acrylonitrile) and polystyrene, during the preparation of a nanocomposite via an in-situ polymerization method. X-ray diffraction results and transmission electron microscopic observation of the morphology showed that the epoxy segment enhanced not only the delamination but also the extrication of ammonium cations from the organoclay gallery into the polymer matrix. The latter phenomenon induced the structural change of the alkyl group of ammonium cations in the gallery from a bilayer to monolayer structure, and also decreased the glass-rubber transition temperature as measured by a differential scanning calorimeter and dynamic mechanical analyzer.

• Transactions on Electrical and Electronic Materials
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• v.12 no.4
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• pp.160-163
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• 2011

Polymer nanocomposite has been attracting more attention as a new insulation material because homogeneous dispersion of nano-sized inorganic fillers can improve various properties significantly. In this paper, various kinds of epoxy-based nanocomposites were made, and the AC breakdown strengths of Nano filler and micro-$SiO_2$ filler mixtures of epoxy-based composites were analyzed using sphere-to-sphere electrodes. Moreover, nano- and microfiller combinations were investigated as an approach to practical application of nanocomposite insulation materials. Its composition ratio was 100 (resin):82 (hardener):1.5 (accelerator). AC breakdown tests were performed at room temperature ($25^{\circ}C$), $80^{\circ}C$, and $100^{\circ}C$ in the vicinity of $T_g$ ($90^{\circ}C$). Thermal conductivity was measured using TC-30.

• Macromolecular Research
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• v.17 no.2
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• pp.121-127
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• 2009

The cure kinetics of the epoxy-layered, silicate nanocomposites were studied by differential scanning calorimetry under isothermal and dynamic conditions. The materials used in this study were o-cresol novolac epoxy resin and phenol novolac hardener, with organically modified layered silicates. Various kinetic parameters, including the reaction order, activation energy, and kinetic rate constants, were investigated, and the storage stability of the epoxy-layered silicate nanocomposites was measured. To synthesize the epoxy-layered silicate nanocomposites, the phenolic hardener underwent pre-intercalation by layered silicate. From the cure kinetics analyses, the organically modified layered silicate decreased the activation energy during cure reaction in the epoxy/phenolic hardener system. In addition, the storage stability of the nanocomposite with the pre-intercalated phenolic hardener was significantly increased compared to that of the nanocomposite with direct mixing of epoxy, phenolic hardener, and layered silicate. This was due to the protective effect of the reaction between onium ions and epoxide groups.

• Korean Chemical Engineering Research
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• v.46 no.5
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• pp.945-948
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• 2008

Nanocomposite materials provides efficient reinforcement, thermal endurance, and many other advantages depending on the additives used, with applications in the aerospace, automotive, and biomedical industries. Here, epoxy based nanocomposites were synthesized in the presence of Cloisite 15A and characterized with TEM, XRD, TGA, and DMA. To determine the effect of the clay d-spacing, Cloisite 20A was also used to synthesize the nanocompostes. In addition to the traditional hot plate method, an ultrasonicator was used to investigate the effect of different types of mixing on the properties of the nanocomposite; no significant effect was found. An examination of the nanocomposite morphology revealed that all the nanocomposites synthesized yielded an intercalated structure. When 5 wt% of Cloisite 15A was used with 20 min sonication time, the storage modulus increased 10% over the neat(no clay) nanocomposite. In general, the presence of Cloisite 15A produced a better storage modulus than Cloisite 20A.

• Transactions on Electrical and Electronic Materials
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• v.14 no.5
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• pp.278-281
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• 2013

The effects of electric field frequency on the AC electrical treeing phenomena in an epoxy/layered silicate (1.5 wt%) were investigated in a needle-plate electrode arrangement. A layered silicate was exfoliated in an epoxy-base resin with AC electric field apparatus. To measure the treeing initiation and propagation- and the breakdown rate, a constant alternating current (AC) of 10 kV with three different electric field frequencies (60, 500, and 1,000 Hz) was applied to the specimen in the needle-plate electrode specimen in an insulating oil bath at $130^{\circ}C$. At 60 Hz, the treeing initiation time was 12 min, the propagation rate was $0.24{\times}10^{-3}$ mm/min, and the morphology was a dense branch type. As the electric field frequency increased, the treeing initiation time decreased and the propagation rate increased. At 1,000 Hz, the treeing initiation time was 5 min, the propagation rate was $0.30{\times}10^{-3}$ mm/min, and the morphology was a dense bush type.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.84-84
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• 2010

Nano particles (10nm SiO2) were silane-treated in order to modify the surface characteristics in a epoxy nanocomposite. Then. micro particles ($3{\mu}m$ SiO2) were poured into the epoxy nanocomposite using various mixing process and epoxy/ micro-and-nano- mixed composites (EMNC) were prepared. The thermal (Tg) and mechanical (tensile and flexural strength) properties were measured by DMA and UTM and the data was estimated by Weibull plot.

• Carbon letters
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• v.16 no.2
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• pp.101-106
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• 2015

We report a covalent functionalization of graphene nanoparticles (GnPs) employing 2,3,4-Tri-O-acetyl-${\beta}$-D-xylopyranosyl azide followed by fabrication of an epoxy/functionalized graphene nanocomposite and an evaluation of its thermo-mechanical performance. Successful functionalization of GnP was confirmed via thermal and spectroscopic study. Raman spectroscopy indicated that the functionalization was on the edge of the graphene sheets; the basal plane was not perturbed as a result of the functionalization. The epoxy/functionalized GnP composite system exhibited an increase in flexural modulus (~18%) and glass transition temperature (${\sim}10^{\circ}C$) compared to an un-functionalized GnP based epoxy composite.

• Advances in nano research
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• v.16 no.4
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• pp.353-363
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• 2024

The incorporation of nanoplatelets in composite and polymeric materials represents a recent and innovative approach, holding substantial promise for diverse property enhancements. This study focuses on the application of nanocomposites in the production of sports equipment, particularly soccer balls, aiming to bridge the gap between theoretical advancements and practical implications. Addressing the longstanding challenge of suboptimal interaction between carbon nanofillers and epoxy resin in epoxy composites, this research pioneers inventive solutions. Furthermore, the investigation extends into unexplored territory, examining the integration of glass fiber/epoxy composites with nanoparticles. The incorporation of nanomaterials, specifically expanded graphite and graphene, at a concentration of 25.0% by weight in both the epoxy structure and the composite with glass fibers demonstrates a marked increase in impact resistance compared to their nanomaterial-free counterparts. The research transcends laboratory experiments to explore the practical applications of nanocomposites in the design and production of sports equipment, with a particular emphasis on soccer balls. Analytical techniques such as infrared spectroscopy and scanning electron microscopy are employed to scrutinize the surface chemical structure and morphology of the epoxy nanocomposites. Additionally, an in-depth examination of the thermal, mechanical, viscoelastic, and conductive properties of these materials is conducted. Noteworthy findings include the efficacy of surface modification of carbon nanotubes in preventing accumulation and enhancing their distribution within the epoxy matrix. This optimization results in improved interfacial interactions, heightened thermal stability, superior mechanical properties, and enhanced electrical conductivity in the nanocomposite.