• International Journal of Concrete Structures and Materials
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• v.2 no.2
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• pp.99-105
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• 2008

Southern exposure test specimens were used to evaluate corrosion performance of epoxy-coated reinforcing bars in chloride contaminated concrete by electrochemical impedance spectroscopy method. The test specimens with conventional bars, epoxy-coated bars and corrosion inhibitors were subjected 48 weekly cycles of ponding with sodium chloride solution and drying. The polarization resistance obtained from the Nyquist plot was the key parameter to characterize the degree of reinforcement corrosion. The impedance spectra of specimens with epoxy-coated bars are mainly governed by the arc of the interfacial film and the resistance against the charge transfer through the coating is an order of magnitude higher than that of the reference steel bars. Test results show good performance of epoxy-coated bars, although the coatings had holes simulating partial damage, and the effectiveness of corrosion-inhibiting additives. The corrosion rate obtained from the impedance spectroscopy method is equivalent to those determined by the linear polarization method for estimating the rate of corrosion of reinforcing steel in concrete structures.

• Corrosion Science and Technology
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• v.13 no.5
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• pp.163-169
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• 2014

The corrosion resistance of epoxy-coated carbon steel was evaluated. The carbon steel surface was subjected to different treatment methods such as steel grit blasting and power tool treatment as well as contamination of water soluble salt. To study the effect of the surface treatments and contamination, the topology of the treated surface was observed by confocal microscopy and a pull-off adhesion test was conducted. The corrosion resistance of the epoxy-coated carbon steel was further examined by electrochemical impedance spectroscopy (EIS) combined with immersion test of 3.5 wt% of NaCl solution. Consequently, the surface contamination by sodium chloride with $16mg/m^2$, $48mg/m^2$ and $96mg/m^2$ didn't affect the adhesion strength for current epoxy coated carbon steel and blister and rust were not observed on the surface of epoxy coating contaminated by various concentration of sodium chloride after 20 weeks of immersion in 3.5 wt% NaCl aqueous solutions. In addition, the results of EIS test showed that the epoxy-coated carbon steel treated with steel grit blasting and power tool showed similar corrosion protection performance and surface cleanness such as Sa 3 and Sa 2.5 didn't affect the corrosion protectiveness of epoxy coated carbon steel.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2004.10a
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• pp.96-99
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• 2004

Silica fillers were coated by plasma polymer coatings of 1,3-diaminopropane, allylamine, pyrrole, 1,2-epoxy-5-hexene, allyl mercaptan and allyl alcohol using RF plasma (13.56 MHz). The coated fillers were then mixed with biphenyl epoxy, phenol novolac (curing agent) and/or triphenylphosphine (catalyst), and subjected to DSC analyses in order to elucidate the chemical reaction between functional moieties in the plasma polymer coatings and the epoxy resin. Only the samples with 1,3-diaminopropane and allylamine plasma polymer coated silica fillers showed heat of reaction peaks when they were mixed with biphenyl epoxy resin only, while these samples as well as the samples with 1,3-diaminopropane, allylamine and pyrrole plasma polymer coated silica fillers exhibited heat of reaction peaks when mixed with both biphenyl epoxy and phenol novolac (curing agent).

• Corrosion Science and Technology
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• v.11 no.5
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• pp.165-172
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• 2012

The corrosion resistance of epoxy-coated carbon steel was evaluated. The carbon steel surface was subjected to different treatment methods such as steel grit blasting with different size, steel shot ball blasting and power tool treatment. To study the effect of the treatments, the topology of the treated surface was observed by optical 3D microscopy and a pull-off adhesion test was conducted. The corrosion resistance of the epoxy-coated carbon steel was further examined by electrochemical impedance spectroscopy (EIS) combined with hygrothermal cyclic testing. The results of EIS indicated that the epoxy-coated carbon steel treated with steel grit blasting showed an improved corrosion resistance compared to untreated epoxy-coated surfaces or surfaces subjected to shot ball blasting and power tool treatments.

• International Journal of Concrete Structures and Materials
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• v.18 no.1E
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• pp.3-9
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• 2006

Five slab specimens with predefined cracks are examined to evaluate the corrosion behavior of epoxy-coated bars in chloride contaminated concrete, using linear polarization method. The test specimens were subjected to alternating weekly cycles of ponding in a salt solution and drying for 48 weeks. Test results show that the current density of the specimen of normal steel bars becomes 0.715 ${\mu}A/cm^2$ indicating that the steel bars are in moderate or high corrosion condition. However, the corrosion rates of the specimens with damaged epoxy-coated bars are significantly below 0.1 ${\mu}A/cm^2$ and the bars appears to be in passive condition. The damaged epoxy-coated bars with a corrosion inhibitor of calcium nitrite showed a corrosion rate of 0.110 ${\mu}m/year$ or 56 percents of the corrosion rate of damaged epoxy-coated specimen without such an inhibitor, 0.195 ${\mu}m/year$. However, the corrosion rates of specimens containing the other two corrosion inhibitors, a combination of amines and esters or mixtures of organic alkenyl dicarboxyl acid salts are quite equivalent to the control specimen. The research technique of linear polarization resistance method has proven itself to be useful in measuring corrosion rates of reinforcement in concrete.

• Proceedings of the Korea Concrete Institute Conference
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• 1994.04a
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• pp.158-162
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• 1994

Test results to evaluate the mechanical properties of epoxy-coated bars and corrosion protection characteristics of epoxy coating on the bars are described. The results show good adhesion and abrasion resistance satisfying the requirements in relevant standards. The test results also show that for a coating thickness ranging from 150${\mu}{\textrm}{m}$ to 300${\mu}{\textrm}{m}$, satisfactory results are obtained regarding bendability. Cautions shall be required when bending epoxy-coated bars at a high bending degree and at a low temperature. The results of accelerated corrosion tests show good corrosion resistance. However, surface defects from the steel itself and insufficient blast-clean process form weak points resulting blistering or disbonding of the coating. The use of epoxy-coated bars is expected to help protect corrosion of reinforcement and extend the service life of reinforced concrete structures.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.3
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• pp.298-304
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• 2017

The corrosion of reinforcements embedded in concrete causes some durability problems in reinforced and prestressed concrete structures. The epoxy coated reinforcements are one of the effective and reliable methods to prevent corrosion of reinforcements. However, it has been known that the epoxy coating reduces the bond capacity of reinforcement to concrete. This paper investigates the bond behaviors of epoxy coated reinforcements experimentally using direct pull-out test. Bond behaviors of epoxy coated bars for various reinforcement diameters of 10, 19 and 29mm and thicknesses of cover concrete of 1, 2, 3, and $4.5c/d_b$ (ratio of cover to bar diameter) are examined. Total 66 specimens were manufactured and tested according to the RILEM standard method. As the diameters of the epoxy coated reinforcements increase, the difference of bond strength between epoxy coated reinforcements and uncoated bars also increases. Epoxy coated bars showed more than 85% bond performance compared to those of uncoated bars. A new formular for estimating basic development length of epoxy coated reinforcement based on equilibrium equation is proposed using this experimental result.

• Corrosion Science and Technology
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• v.8 no.5
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• pp.203-207
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• 2009

Electrochemical methods have been widely used to study the performances and mechanisms for the degradation of organic and inorganic coatings. In this study, EN(Electrochemical noise) measurement was applied to the protective properties and review the parameters analyzed noise signals in the time and in the frequency domain for epoxy resin based coated steels during exposure to hot sea water($40^{\circ}C$) and salt spray for 200 days. It was also found that $R_n$(Noise resistance), $R_{sn}$($f_{min}$)(Spectral noise resistance) and 2H(Hurst exponent) represented the performance of epoxy coated steels. $R_n$ can be determined as the ratio of the standard deviations of potential and current noise signals and is decreased to exposure time. Data qualities can be easily checked by PSD(Power Spectral Density) plot and $V_{psd}$, $I_{psd}$ and $R_{sn}$($f_{min}$) is useful to research the protective performances and mechanisms of coated steels. Hurst exponent represents the degradation of coated steels. But, it is difficult to directly apply the protective criterion to the evaluation of epoxy coated steels used the shipbuilding processes.

• Computers and Concrete
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• v.19 no.3
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• pp.243-256
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• 2017

Epoxy-coated reinforcing bars are widely used to protect the corrosion of the reinforcing bars in the RC elements under their in-service environments and external loads. In most field surveys, it was reported that the corrosion resistance of the epoxy-coated reinforcing bars is typically better than the uncoated bars. However, from the experimental tests conducted in the labs, it was reported that, under the same loads, the RC elements with epoxy-coated reinforcing bars had wider cracks than the elements reinforced with the ordinary bars. Although this conclusion may be true considering the bond reduction of the reinforcing bar due to the epoxy coating, the maximum service loads used in the experimental research may be a main reason. To answer these two phenomena, service performance of 15 RC beam specimens with uncoated and epoxy-coated reinforcements under different fatigue loads was experimentally studied. Influences of different coating thicknesses of the reinforcing bars, the fatigue load range and load upper limit as well as fatigue load cycles on the mechanical performance of RC test specimens are discussed. It is concluded that, for the test specimens subjected to the comparatively lower load range and load upper limit, adverse effect on the service performance of test specimens with thicker epoxy-coated reinforcing bars is negligible. With the increments of the coating thickness and the in-service loading level, i.e., fatigue load range, load upper limit and fatigue cycles, the adverse factor resulting from the thicker coating becomes noticeable.

• Magazine of the Korea Concrete Institute
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• v.6 no.6
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• pp.173-179
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• 1994

Epoxy coated bars protecting reinforcing bars from corrosion and enhancing durability of reinforced concrete structures are tested to evaluate corrosion protection properties. Tests are performed based on the relevant sta.ndards of KS and ASTM, such as chenical resistance, salt water spray, salt crock test and chloride ermeability test. with the main varlable of the coating thlckness. Test results show good chemical protection property and chloride permeability. The results of the salt water spray and the salt crock test show that epoxy coating well protects the reinforcing bars from corrosion, cornparing to the biack bars without epoxy coatmg. However, several spots on the coated bars are rusted at the pinholes or un the bars with coating thickness less thar $200{\mu}M$. Special cautions are required i n the process of blast cleanmg when applying the usion-bonded epoxy coating.