• Title/Summary/Keyword: environmental-friendly organic

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Residue Patterns of Active Ingredients Derived from Melia Azedarach, Nerium Ndicum, and Coptis Chinensis in Rice Using LC-MS/MS (LC-MS/MS를 이용한 멀구슬, 협죽도, 황련 유래 활성성분의 벼 중 잔류양상 연구)

  • Park, Joon-Seong;Nam, Hyo-Song;Kim, Yong-Hwan;Kim, Do-ik;Kim, Sun-Am
    • Korean Journal of Environmental Agriculture
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    • v.34 no.2
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    • pp.128-133
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    • 2015
  • BACKGROUND: Plant extracts have been used as environment friendly agricultural materials for organic farming in South Korea. However safety evaluation on the plant extracts was not properly tested. The aim of this study was to evaluate safety of the extracts from Melia azedarach, Nerium indicum and Coptis chinensis on cultivating rice. METHODS AND RESULTS: Pant extarcts 300-fold diluted were treated on rice, and residues of M. azedarach, N. indicum and C. chinensis were determined. The analytes from the rice samples were detected by liquid chromatography coupled with tandem mass spectrometry (LC-MS/MS). The method was validated, and good linearities ($r^2=0.995-0.998$), specificity, and recoveries were obtained. Limits of detection were 0.01 mg/kg for all of the target compounds. Recoveries were 79.3-118.3% at 0.1 mg/kg and 75.2-111.5% at 0.5 mg/kg. The residue levels were below 0.030 mg/kg for azadirachtin, 0.320 mg/kg for oleandrin and 1.460 mg/kg for berberine. CONCLUSION(S): The extracts of M. azedarach, N. indicum and C. chinensis contained azadirachtin, oleandrin and berberine as an active ingredient, respectively. The residue of three active ingredients dramatically decreased after treatment in all fruits, stems and roots of rice.

Evaluation of Some Insecticides and Environmental Friendly Agricultural Materials against Winter Cherry Bug, Acanthocoris sordidus (Coreidae, Hemiptera) (꽈리허리노린재(Acanthocoris sordidus, Coreidae, Hemiptera)에 대한 몇 가지 살충제와 친환경농자재의 활성평가)

  • Kang, Chan-Yeong;Ryu, Tae-Hee;Kwon, Hye-Ri;Yu, Yong-Man;Youn, Young-Nam
    • The Korean Journal of Pesticide Science
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    • v.20 no.2
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    • pp.159-164
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    • 2016
  • The winter cherry bug (Acanthocoris sordidus Thunberg, Coreidae, Hemiptera) is a insect pest that have a piercing sucking type mouthpart, and it is injured to solanaceous plants including pepper plant. For the control of the winter cherry bug, 20 organic synthetic insecticides and 7 environmental friendly agricultural materials (EFAMs) were selected with single formulation. Fenitrothion, fenthion and phenthoate were significantly higher mortality to adults and 3rd instar nymphs of winter cherry bug as over 95 and 100 % after 72 hours with treatment. Otherwise, in case of EFAMs, there is no significantly higher effective materials to adults and 3rd instar nymphs of winter cherry bug. Eighty percentage of Sophora flavescens was showed only around 50% mortality with the high variation after 72 hours with treatment against adult of the winter cherry bug.

Development of Environmental-friendly Cleaning Agents Utilizing Organic Acids for Removal of Scale on the Wall of Cleaning Beds and Distribution Reservoirs in the Waterworks (유기산을 이용한 상수도 정수장 및 배수지 벽면 스케일 세척용 친환경 세정제 개발)

  • Lee, Jae-Ryoung;Yoon, Hee-Keun;Bae, Jae-Heum;Shin, Hyun-Duk
    • Clean Technology
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    • v.18 no.3
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    • pp.272-279
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    • 2012
  • In this study, an environmental-friendly cleaning agent utilizing organic acids and various additives has been developed and applied to the field for removal of scale deposited on the cleaning beds or distribution reservoirs of the waterworks. As an analytical result of scale on the cleaning beds, we found that it consists of mainly metallic oxides such as $SiO_2$, $Al_2O_3$, $Fe_2O_3$, and MnO. Malic acid, malonic acid, and citric acid showed relatively better solvency on $Al_2O_3$, $Fe_2O_3$, and MnO except $SiO_2$ among various organic acids. Mixed organic acid solutions of malic acid, malonic acid, and citric acid were prepared with certain weight ratios and their solvencies on mixed metal oxides of $Al_2O_3$, $Fe_2O_3$, and MnO were investigated. The experimental results showed that an 10% mixed organic acid solution prepared with weight ratio of malic acid : malonic acid : citric acid = 6 : 2 : 2 were found to have best scale solvency power of about 29%. The formulated cleaning agents with a small amount of nonionic surfactant showed much better solvency on mixed oxides than mixed organic solution alone. Especially, the formulated cleaning agent with 0.2 wt% LA-7 surfactant appeared to have best scale removal efficiency of about 35%. However, the formulated cleaning agent with disinfectants such as NaClO, $H_2O_2$ and $Ca(ClO)_2$ showed poor solvency on mixed oxides. It is inferred that surfactants are able to improve scale removal efficiency due to their capability of emulsification, and disinfectants cause to degrade scale solvency in water because of their oxidation. Based on these basic experimental results, formulated cleaning agents have been prepared with mixed organic acid solution, nonionic surfactants, and disinfectants and successfully applied to removal of scales on the cleaning beds and distribution reservoir at city D waterworks.

Fabrication of Environmental-friendly Materials Using Atomic Layer Deposition (원자층 증착을 이용한 친환경 소재의 제조)

  • Kim, Young Dok
    • Applied Chemistry for Engineering
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    • v.23 no.1
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    • pp.1-7
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    • 2012
  • In this article, I will introduce recent developments of environmental-friendly materials fabricated using atomic layer deposition (ALD). Advantages of ALD include fine control of the thin film thickness and formation of a homogeneous thin fim on complex-structured three-dimensional substrates. Such advantages of ALD can be exploited for fabricating environmental-friendly materials. Porous membranes such as anodic aluminum oxide (AAO) can be used as a substrate for $TiO_2$ coating with a thickness of about 10 nm, and the $TiO_2$-coated AAO can be used as filter of volatile organic compound such as toluene. The unique structural property of AAO in combination with a high adsorption capacity of amorphous $TiO_2$ can be exploited in this case. $TiO_2$ can be also deposited on nanodiamonds and Ni powder, which can be used as photocatalyst for degradation of toluene, and $CO_2$ reforming of methane catalyst, respectively. One can produce structures, in which the substrates are only partially covered by $TiO_2$ domains, and these structures turns out to be catalytically more active than bare substrates, or complete core-shell structures. We show that the ALD can be widely used not only in the semiconductor industry, but also environmental science.

Estimation of N Mineralization Potential and N Mineralization Rate of Organic Amendments in Upland Soil

  • Shin, Jae-Hoon;Lee, Sang-Min;Lee, Byun-Woo
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.6
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    • pp.751-760
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    • 2015
  • Management of renewable organic resources is important in attaining the sustainability of agricultural production. However, nutrient management with organic resources is more complex than fertilization with chemical fertilizer because the composition of the organic input or the environmental condition will influence organic matter decomposition and nutrient release. One of the most effective methods for estimating nutrient release from organic amendment is the use of N mineralization models. The present study aimed at parameterizing N mineralization models for a number of organic amendments being used as a nutrient source for crop production. Laboratory incubation experiment was conducted in aerobic condition. N mineralization was investigated for nineteen organic amendments in sandy soil and clay soil at $20^{\circ}C$, $25^{\circ}C$, and $30^{\circ}C$. N mineralization was facilitated at higher temperature condition. Negative correlation was observed between mineralized N and C:N ratio of organic amendments. N mineralization process was slower in clay soil than in sandy soil and this was mainly due to the delayed nitrification. The single and the double exponential models were used to estimate N mineralization of the organic amendments. N mineralization potential $N_p$ and mineralization rate k were estimated in different temperature and soil conditions. Estimated $N_p$ ranged from 28.8 to 228.1 and k from 0.0066 to 0.6932. The double exponential model showed better prediction of N mineralization compared with the single exponential model, particularly for organic amendments with high C:N ratio. It is expected that the model parameters estimated based on the incubation experiment could be used to design nutrient management planning in environment-friendly agriculture.

Ternary Blend Organic Solar Cells Trends based on PM6:Y6 (PM6:Y6를 기반으로 한 삼중 혼합 유기 태양전지 동향)

  • Dong Hwan Yun;Gwang Yong Shin;Yun Hye Jung;YeongWoo Ha;Gi-Hwan Kim
    • Current Photovoltaic Research
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    • v.11 no.3
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    • pp.79-86
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    • 2023
  • As we strive to mitigate the environmental impact caused by the use of fossil fuels, the exploration of alternative energy sources has gained significant attention. Solar energy, in particular, has emerged as a promising solution due to its eco-friendly nature and virtually limitless availability. Among the various types of solar cells that harness this abundant energy source, organic solar cells have garnered considerable interest. Organic solar cells feature a photo-active layer composed of organic semiconductors, offering a range of appealing advantages such as cost-effectiveness, flexibility, translucency, and the ability to produce customizable colors. However, the commercialization of organic solar cells has been impeded by certain challenges, notably their relatively low efficiency and stability. To overcome these obstacles and pave the way for wider adoption, researchers have been exploring innovative approaches, including the implementation of ternary blend organic solar cells. This strategy involves introducing a third component into the photo-active layer alongside the organic semiconductors, with the aim of enhancing the overall performance of the solar cell. In this paper, we delve into the issues associated with organic solar cells and focus on one potential solution: ternary blend organic solar cells. Specifically, we examine the application of this approach to PM6:Y6, which stands as one of the most popular combinations of organic semiconductors. By investigating the potential of ternary blends, particularly utilizing PM6:Y6, we aim to accelerate the commercialization of organic solar cells.

Remediation of heavy metal-contaminated soils using eco-friendly nano-scale chelators

  • Lim, Heejun;Park, Sungyoon;Yang, Jun Won;Cho, Wooyoun;Lim, Yejee;Park, Young Goo;Kwon, Dohyeong;Kim, Han S.
    • Membrane and Water Treatment
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    • v.9 no.3
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    • pp.137-146
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    • 2018
  • Soil washing is one of the most frequently used remediation technologies for heavy metal-contaminated soils. Inorganic and organic acids and chelating agents that can enhance the removal of heavy metals from contaminated soils have been employed as soil washing agents. However, the toxicity, low removal efficiency and high cost of these chemicals limit their use. Given that humic substance (HS) can effectively chelate heavy metals, the development of an eco-friendly, performance-efficient and cost-effective soil washing agent using a nano-scale chelator composed of HS was examined in this study. Copper (Cu) and lead (Pb) were selected as target heavy metals. In soil washing experiments, HS concentration, pH, soil:washing solution ratio and extraction time were evaluated with regard to washing efficiency and the chelation effect. The highest removal rates by soil washing (69% for Cu and 56% for Pb) were achieved at an HS concentration of 1,000 mg/L and soil:washing solution ratio of 1:25. Washing with HS was found to be effective when the pH value was higher than 8, which can be attributed to the increased chelation effect between HS and heavy metals at the high pH range. In contrast, the washing efficiency decreased markedly in the low pH range due to HS precipitation. The chelation capacities for Cu and Pb in the aqueous phase were determined to be 0.547mmol-Cu/g-HS and 0.192mmol-Pb/g-HS, respectively.

The technical transfer on manufacture technique of environmental-friendly leather for improved effluent quality in beamhouse process (피혁 폐수의 오염 저감을 위한 피혁 준비 공정 기술 보급(Carbonate계 Nitrogen-free deliming agent 합성 및 적용연구))

  • Yun, Jong-Kuk;park, Jae-Hyung;Cho, Do-kwang;Paik, In-Kyu;Kim, Han-Do
    • Journal of the Korea Organic Resources Recycling Association
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    • v.12 no.3
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    • pp.134-139
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    • 2004
  • A study was made on the synthesis of a carbonate base nitrogen-free deliming agent using a non-phosgene compound applicable to the deliming process, which is one of the biggest sources of pollutant increasing the T-N concentration in the effluent from the leather making processes. And also studied on the possibility of using the agent in the deliming process. Through measurement of T-N, BOD, COD and SS in the effluent after the agent is used, contents of Ca and Cr and TS in the leather after the deliming process were measured, by which deliming efficiency, influences to the physical properties of the chromium tanned leather and reducing effects of T-N, BOD, COD and SS concentrations in the effluent could be confirmed. Thus an eco-friendly study has been conducted.

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Assessment of Energy Efficiency and Nutrient Balance in Organic Rice Farming Area (벼유기농업단지 에너지효율 및 양분수지 평가)

  • Gil, Geun-Hwan;Kang, Jong-Gook;Lee, Kyung-Do;Lee, Jang-Hee;Lee, Kyeong-Bo;Kim, Jae-Duk
    • Korean Journal of Environmental Agriculture
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    • v.27 no.3
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    • pp.267-273
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    • 2008
  • Energy efficiency and nutrient balance are good methods for environmental assessment of the environmentally-friendly agriculture. The objectives of this study were 1) to estimate the energy efficiency and nutrient balance of the organic rice farming, and 2) to suggest a solution to improvement the energy efficiency and nutrient balance. The set of estimation was performed at the organic rice farming area (8.9 ha) in Wanju-gun during the paddy cultivation period from 2006 to 2007. The organic farming complex consists of four weeding methods using 1) duck, 2) apple snail, 3) duck and apple snail and 4) hands and machinery. Results from this estimation should that the organic rice farming area was less efficient than conventional rice farming. The efficiency of organic farming area in 2006 was higher than in 2007. For the calculation of the nutrient balance, the N, P and K contents of input materials (cattle manure, milk vetch, mixed oilcake, rice bran, rice straw and barley straw) and output (farm products) were analysed. Annual environmental loads of N, $P_2O_5$ and $K_2O$ were estimated at 4.4 kg/10a, 13.8 kg/10a and 14.5 kg/10a, respectively. Cattle manure had the largest portion among the inputs items and nutrient concentration of cattle manure was high. Thus energy efficiency and nutrient balance depend on cattle manure input. Therefore it is necessary to control the manure input to improve the efficiency of organic rice farming.

A Study on the State of Affairs of Green Fashion Marketing (그린 패션 마케팅 현황에 관한 연구)

  • Park, Song-Ae
    • Journal of the Korea Fashion and Costume Design Association
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    • v.13 no.2
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    • pp.121-131
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    • 2011
  • Green Marketing, a response to the serious environment problems of the 21st century, is an important point for trends in both art and fashion. It is a strategy for reminding consumers of the threatening environment problems and to recognize that everyone must take responsibility for these problems. Green marketing is a concept that is the point at issue and social reform movement. The purpose of this study was to find examples of Green Marketing in fashion and classify them into four groups. The results of this study were as follows. First, the terms related to green marketing as related to fashion can be categorized into four areas: 1. Eco-friendly product marketing: product merchandising that usually uses organic materials and green manufacturing processes. 2. Green-communication marketing: PR strategies that use green slogans through deep impression advertising or special promotional events relating reducing, reusing and recycling, etc., with the brand's name. 3. Green environmental-marketing: marketing strategies that is an enlightenment campaign for environmental preservation and sustainable fashion design such as reusing, recycling, and reducing. 4. Cause-related marketing: marketing plans that return profits to society and that take an active part in the causes of the community. It was expected that these types of green marketing strategies would yield positive effects in enhancing brand value and consumer confidence as well as increasing profits.

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