• Title/Summary/Keyword: entropy change

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Free Energy and Hydration Free Energy of N-acetyl-N'-methylalaninamide

  • Young Kee Kang;Mu Shik Jhon
    • Bulletin of the Korean Chemical Society
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    • v.12 no.5
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    • pp.495-499
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    • 1991
  • The changes in the free energy and hydration free energy of N-acetyl-N'-methylalaninamide in the unhydrated and hydrated states were calculated with ECEPP/2 and the hydration shell model. The configurational entropy change of each conformation in both states were computed by a harmonic method. To understand the hydration structure of each hydrated conformation, the hydration-shell coordination numbers of functional. groups of the molecule were estimated from water-accessible volumes, and the contributions of water-accessible volume and polarization of each group to the hydration free energy were analyzed. The results show a reasonable agreement with those of recent theoretical studies and experiments.

The Pressure Effect on the Ionization of m-Chloroanilinium Ion in Sodiumacetate Buffer Solution

  • Jee ,Jong-Gi;Lee, Young-Hwa;Kwak, Young-Jik
    • Bulletin of the Korean Chemical Society
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    • v.6 no.5
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    • pp.266-269
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    • 1985
  • The dissociation constants(K) of m-chloroanilinium ion in water-ethanol mixture, where the volume percentage of water is 89.5%, were evaluated by UV-spectroscopic method at $20{\sim}50^{\circ}C$, up to 1500 bars with changing ionic strength from 0.04 to 0.10 mol $kg^{-1}$ by use of acetate buffer. K values enhance with increasing ionic strength and temperature, but decrease with elevating pressure. From K values, we obtained the partial molar volume change and some other thermodynamic parameters. From the values of enthalpy, entropy and isoequilibrium temperature (649 K), we concluded that the dissociation of m-chloroanilinium ion mentioned above is controlled by enthalpy.

A novel framework for the construction of cryptographically secure S-boxes

  • Razi Arshad;Mudassir Jalil;Muzamal Hussain;Abdelouahed Tounsi
    • Computers and Concrete
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    • v.34 no.1
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    • pp.79-91
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    • 2024
  • In symmetric cryptography, a cryptographically secure Substitution-Box (S-Box) is a key component of a block cipher. S-Box adds a confusion layer in block ciphers that provide resistance against well-known attacks. The generation of a cryptographically secure S-Box depends upon its generation mechanism. In this paper, we propose a novel framework for the construction of cryptographically secure S-Boxes. This framework uses a combination of linear fractional transformation and permutation functions. S-Boxes security is analyzed against well-known security criteria that include nonlinearity, bijectiveness, strict avalanche and bits independence criteria, linear and differential approximation probability. The S-Boxes can be used in the encryption of any grayscale digital images. The encrypted images are analyzed against well-known image analysis criteria that include pixel changing rates, correlation, entropy, and average change of intensity. The analysis of the encrypted image shows that our image encryption scheme is secure.

Consequences of land use change on bird distribution at Sakaerat Environmental Research Station

  • Trisurat, Yongyut;Duengkae, Prateep
    • Journal of Ecology and Environment
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    • v.34 no.2
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    • pp.203-214
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    • 2011
  • The objectives of this research were to predict land-use/land-cover change at the Sakaerat Environmental Research Station (SERS) and to analyze its consequences on the distribution for Black-crested Bulbul (Pycnonotus melanicterus), which is a popular species for bird-watching activity. The Dyna-CLUE model was used to determine land-use allocation between 2008 and 2020 under two scenarios. Trend scenario was a continuation of recent land-use change (2002-2008), while the integrated land-use management scenario aimed to protect 45% of study area under intact forest, rehabilitated forest and reforestation for renewable energy. The maximum entropy model (Maxent), Geographic Information System (GIS) and FRAGSTATS package were used to predict bird occurrence and assess landscape fragmentation indices, respectively. The results revealed that parts of secondary growth, agriculture areas and dry dipterocarp forest close to road networks would be converted to other land use classes, especially eucalyptus plantation. Distance to dry evergreen forest, distance to secondary growth and distance to road were important factors for Black-crested Bulbul distribution because this species prefers to inhabit ecotones between dense forest and open woodland. The predicted for occurrence of Black-crested Bulbul in 2008 covers an area of 3,802 ha and relatively reduces to 3,342 ha in 2020 for trend scenario and to 3,627 ha for integrated-land use management scenario. However, intact habitats would be severely fragmented, which can be noticed by total habitat area, largest patch index and total core area indices, especially under the trend scenario. These consequences are likely to diminish the recreation and education values of the SERS to the public.

Prediction of Landslides Occurrence Probability under Climate Change using MaxEnt Model (MaxEnt 모형을 이용한 기후변화에 따른 산사태 발생가능성 예측)

  • Kim, Hogul;Lee, Dong-Kun;Mo, Yongwon;Kil, Sungho;Park, Chan;Lee, Soojae
    • Journal of Environmental Impact Assessment
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    • v.22 no.1
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    • pp.39-50
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    • 2013
  • Occurrence of landslides has been increasing due to extreme weather events(e.g. heavy rainfall, torrential rains) by climate change. Pyeongchang, Korea had seriously been damaged by landslides caused by a typhoon, Ewiniar in 2006. Moreover, the frequency and intensity of landslides are increasing in summer due to torrential rain. Therefore, risk assessment and adaptation measure is urgently needed to build resilience. To support landslide adaptation measures, this study predicted landslides occurrence using MaxEnt model and suggested susceptibility map of landslides. Precipitation data of RCP 8.5 Climate change scenarios were used to analyze an impact of increase in rainfall in the future. In 2050 and 2090, the probability of landslides occurrence was predicted to increase. These were due to an increase in heavy rainfall and cumulative rainfall. As a result of analysis, factors that has major impact on landslide appeared to be climate factors, prediction accuracy of the model was very high(92%). In the future Pyeongchang will have serious rainfall compare to 2006 and more intense landslides area expected to increase. This study will help to establish adaptation measure against landslides due to heavy rainfall.

Robust Stereo Matching under Radiometric Change based on Weighted Local Descriptor (광량 변화에 강건한 가중치 국부 기술자 기반의 스테레오 정합)

  • Koo, Jamin;Kim, Yong-Ho;Lee, Sangkeun
    • Journal of the Institute of Electronics and Information Engineers
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    • v.52 no.4
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    • pp.164-174
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    • 2015
  • In a real scenario, radiometric change has frequently occurred in the stereo image acquisition process using multiple cameras with geometric characteristics or moving a single camera because it has different camera parameters and illumination change. Conventional stereo matching algorithms have a difficulty in finding correct corresponding points because it is assumed that corresponding pixels have similar color values. In this paper, we present a new method based on the local descriptor reflecting intensity, gradient and texture information. Furthermore, an adaptive weight for local descriptor based on the entropy is applied to estimate correct corresponding points under radiometric variation. The proposed method is tested on Middlebury datasets with radiometric changes, and compared with state-of-the-art algorithms. Experimental result shows that the proposed scheme outperforms other comparison algorithms around 5% less matching error on average.

Predicting the Suitable Habitat of Invasive Alien Plant Conyza bonariensis based on Climate Change Scenarios (기후변화 시나리오에 의한 외래식물 실망초(Conyza bonariensis)의 서식지 분포 예측)

  • Lee, Yong-Ho;Oh, Young-Ju;Hong, Sun-Hea;Na, Chea-Sun;Na, Young-Eun;Kim, Chang-Suk;Sohn, Soo-In
    • Journal of Climate Change Research
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    • v.6 no.3
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    • pp.243-248
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    • 2015
  • This study was conducted to predict the changes of potential distribution for invasive alien plant, Conyza bonariensis in Korea. C. bonariensis was found in southern Korea (Jeju, south coast, southwest coast). The habitats of C. bonariensis were roadside, bare ground, farm area, and pasture, where the interference by human was severe. Due to the seed characteristics of Compositae, C. bonariensis take long scattering distance and it will easily spread by movement of wind, vehicles and people. C. canadensis in same Conyza genus has already spread on a national scale and it is difficult to manage. We used maximum entropy modeling (MaxEnt) for analyzing the environmental influences on C. bonariensis distribution and projecting on two different RCP scenarios, RCP 4.5 and RCP 8.5. The results of our study indicated annual mean temperature, elevation and temperature seasonality had higher contribution for C. bonariensis potential distribution. Area under curve (AUC) values of the model was 0.9. Under future climate scenario, the constructed model predicted that potential distribution of C. bonariensis will be increased by 338% on RCP 4.5 and 769% on RCP 8.5 in 2100s.

Magnetic properties and magnetocaloric effect of Sr-doped Pr0.7Ca0.3MnO3 compounds

  • Yen, Pham Duc Huyen;Dung, Nguyen Thi;Thanh, Tran Dang;Yu, Seong-Cho
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1280-1288
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    • 2018
  • In this work, we pointed out that Sr substitution for Ca leads to modify the magnetic and magnetocaloric properties of $Pr_{0.7}Ca_{0.3-x}Sr_xMnO_3$ compounds. Analyzing temperature dependence of magnetization, M(T), proves that the Curie temperature ($T_C$) increased with increasing Sr content (x); $T_C$ value is found to be 130-260 K for x = 0.0-0.3, respectively. Using the phenomenological model and M(T,H) data measured at several applied magnetic field, the magnetocaloric effect of $Pr_{0.7}Ca_{0.3-x}Sr_xMnO_3$ compounds has been investigated through their temperature and magnetic field dependences of magnetic entropy change ${\Delta}S_m$(T,H) and the change of the specific heat change ${\Delta}C_P$(T,H). Under an applied magnetic field change of 10 kOe, the maximum value of $-{\Delta}S_m$ is found to be about $3J/kg{\cdot}K$, and the maximum and minimum values of ${\Delta}C_P$(T) calculated to be about ${\pm}60J/kg{\cdot}K$ for x = 0.3 sample. Additionally, the critical behaviors of $Pr_{0.7}Ca_{0.3-x}Sr_xMnO_3$ compounds around their $T_C$ have been also analyzed. Results suggested a coexistence of the ferromagnetic short- and long-range interactions in samples. Moreover, Sr-doping favors establishing the short-range interactions.

Classification of the Core Climatic Region Established by the Entropy of Climate Elements - Focused on the Middle Part Region - (기후요소의 엔트로피에 의한 핵심 기후지역의 구분 - 중부지방을 중심으로 -)

  • Park, Hyun-Wook;Chung, Sung-Suk;Park, Keon-Yeong
    • Journal of the Korean earth science society
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    • v.27 no.2
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    • pp.159-176
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    • 2006
  • Geographic factors and mathmatical location of the Korean Peninsula have great influences on the variation patterns and appearances over a period of ten days of summer precipitation. In order to clarify the influence of several climate factors on precise climate classification in the middle part region of the Korea, weather entropy and the information ratio were calculated on the basis of information theory and of the data of 25 site observations. The data used for this study are the daily precipitation phenomenon over a period of ten days of summer during the recent thirteen years (1991-2003) at the 25 stations in the middle part region of the Korea. It is divided into four classes of no rain, $0.1{\sim}10.0mm/day,\;10.1{\sim}30.0mm/day$, 30.1mm over/day. Their temporal and spatial change were also analyzed. The results are as follows: the maximum and minimum value of calculated weather entropy are 1.870 bits at Chuncheon in the latter ten days of July and 0.960 bits at Ganghwa during mid September, respectively. And weather entropy in each observation sites tends to be larger in the beginning of August and smaller towards the end of September. The largest and smallest values of weather representative ness based on information ratio were observed at Chungju in the beginning of June and at Deagwallyeong towards the end of July. However, the largest values of weather representativeness came out during the middle or later part of September when 15 sites were adopted as the center of weather forecasting. The representative core region of weather forecasting and climate classification in the middle part region of the Korea are inside of the triangle region of the Buyeo, Incheon, and Gangneung.