• Title/Summary/Keyword: entropies

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The Vacancies-in-Solid Model Applied to Sublimation Pressure, Enthalpies and Entropies of Sublimation, and Enthalpies and Entropies of Solid Krypton and Xenon

  • Ko, Seuk-Beum;Kim, Wan-Kyue
    • Bulletin of the Korean Chemical Society
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    • v.2 no.1
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    • pp.17-24
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    • 1981
  • Thermodynamic properties such as sublimation pressures, enthalpies and entropies of sublimation, enthalpies and entropies of solid krypton and xenon are calculated from $0{\circ}K$ to the triple point, using the vacancies-in-solid model. The Mie-Lennard-Jones 12,6 potential in uniform potential field is used. The results are compared with the calorimetric and sublimation pressure values, and are in a good agreement with the available calorimetric and sublimation pressure values.

INEQUALITIES FOR QUANTUM f-DIVERGENCE OF CONVEX FUNCTIONS AND MATRICES

  • Dragomir, Silvestru Sever
    • Korean Journal of Mathematics
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    • v.26 no.3
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    • pp.349-371
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    • 2018
  • Some inequalities for quantum f-divergence of matrices are obtained. It is shown that for normalised convex functions it is nonnegative. Some upper bounds for quantum f-divergence in terms of variational and ${\chi}^2-distance$ are provided. Applications for some classes of divergence measures such as Umegaki and Tsallis relative entropies are also given.

TOPOLOGICAL ENTROPY OF SWITCHED SYSTEMS

  • Huang, Yu;Zhong, Xingfu
    • Journal of the Korean Mathematical Society
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    • v.55 no.5
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    • pp.1157-1175
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    • 2018
  • For a switched system with constraint on switching sequences, which is also called a subshift action, on a metric space not necessarily compact, two kinds of topological entropies, average topological entropy and maximal topological entropy, are introduced. Then we give some properties of those topological entropies and estimate the bounds of them for some special systems, such as subshift actions generated by finite smooth maps on p-dimensional Riemannian manifold and by a family of surjective endomorphisms on a compact metrizable group. In particular, for linear switched systems on ${\mathbb{R}}^p$, we obtain a better upper bound, by joint spectral radius, which is sharper than that by Wang et al. in [42,43].

Transmuted new generalized Weibull distribution for lifetime modeling

  • Khan, Muhammad Shuaib;King, Robert;Hudson, Irene Lena
    • Communications for Statistical Applications and Methods
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    • v.23 no.5
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    • pp.363-383
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    • 2016
  • The Weibull family of lifetime distributions play a fundamental role in reliability engineering and life testing problems. This paper investigates the potential usefulness of transmuted new generalized Weibull (TNGW) distribution for modeling lifetime data. This distribution is an important competitive model that contains twenty-three lifetime distributions as special cases. We can obtain the TNGW distribution using the quadratic rank transmutation map (QRTM) technique. We derive the analytical shapes of the density and hazard functions for graphical illustrations. In addition, we explore some mathematical properties of the TNGW model including expressions for the quantile function, moments, entropies, mean deviation, Bonferroni and Lorenz curves and the moments of order statistics. The method of maximum likelihood is used to estimate the model parameters. Finally the applicability of the TNGW model is presented using nicotine in cigarettes data for illustration.

Theoretical Studies on the Hydrogen Atom Transfer Reaction (III) (수소원자 전달반응에 관한 이론적 연구 (제 3 보))

  • Ikchoon Lee;Chang Hyun Song;Byung Seo Park
    • Journal of the Korean Chemical Society
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    • v.30 no.2
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    • pp.166-171
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    • 1986
  • Hydrogen atom transfer reactions, $RNH_2+CH_3{\to}RNH+CH_4\;where\;R=H\;and\;CH_3$, were studied by MINDO/3 MO method. It is expected that stable complex may exist between $CH_3\;and\;NH_3$. Transition state characteristics and activation parameters including activation entropies have been determined. In cases of absolute and activation entropies, results are found to agree in general with ab initio and experimental values, wherever comparisions are possible.

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Entropy and Average Mutual Information for a 'Choseong', a 'Jungseong', and a 'Jongseong' of a Korean Syllable (한글 음절의 초성, 중성, 종성 단위의 발생확률, 엔트로피 및 평균상호정보량)

  • 이재홍;오상현
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.26 no.9
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    • pp.1299-1307
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    • 1989
  • A Korean syllable is regarded as a random variable according to its probabilistic property in occurrence. A Korean syllable is divided into a 'choseong', a 'jungseong', and a 'jongseong' which are regarded as random variables. From the cumulative freaquency of a Korean syllable all possible joint probabilities and conditional probabilities are computed for the three ramdom variables. From the joint probabilities and the conditional probabilities all possible joint entropies and conditional entropies are computed for the three random varibles. Also all possible average mutual informations are calculated for the three random variables. Average mutual informatin between two random variables hss its biggest value between choseong and jungseong. Average mutual information between a random variable and other two random variables has its biggest value between jungseong and choseong-jongseong.

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The Probabilities and Entropies of HANGUL Elements including the sopace (공백소를 포함한 한글 자소발생 확률과 엔트로피)

  • 안수길;안지환
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.17 no.2
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    • pp.23-28
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    • 1980
  • The foundation of information theory mainly established by C. E. Shannon , opened the way to profuse studies on the linguistics of various languages. The statistics of Korean letters composed of elements and space are analyzed. The Korean alphabetic elements including the space have their probabilities . And information techniques can be applied to them. This paper extended the previous statistics of Korean letters to include the space. We have also calculated the entropies and redundancy for the case. The result can be used to modify the evaluation of Korean letter information processing devices and used as the basis for letter coding method for eventual future information processors.

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ONLINE TEST BASED ON MUTUAL INFORMATION FOR TRUE RANDOM NUMBER GENERATORS

  • Kim, Young-Sik;Yeom, Yongjin;Choi, Hee Bong
    • Journal of the Korean Mathematical Society
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    • v.50 no.4
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    • pp.879-897
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    • 2013
  • Shannon entropy is one of the widely used randomness measures especially for cryptographic applications. However, the conventional entropy tests are less sensitive to the inter-bit dependency in random samples. In this paper, we propose new online randomness test schemes for true random number generators (TRNGs) based on the mutual information between consecutive ${\kappa}$-bit output blocks for testing of inter-bit dependency in random samples. By estimating the block entropies of distinct lengths at the same time, it is possible to measure the mutual information, which is closely related to the amount of the statistical dependency between two consecutive data blocks. In addition, we propose a new estimation method for entropies, which accumulates intermediate values of the number of frequencies. The proposed method can estimate entropy with less samples than Maurer-Coron type entropy test can. By numerical simulations, it is shown that the new proposed scheme can be used as a reliable online entropy estimator for TRNGs used by cryptographic modules.

High Temperature Thermodynamics of Aqueous electrolyte Solutions (전해질 수용액의 고온 열역학)

  • Lee, Man Seung
    • Resources Recycling
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    • v.27 no.2
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    • pp.63-67
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    • 2018
  • Gibbs free energy is a measure of relative stability among substances. Since the nature of the ions in aqueous solution is diverse, their thermodynamic data at extensive experimental conditions is scarce. In this work, the calculation procedure was introduced to obtain the absolute and conventional standard molar enthalpies and entropies of hydration of ions from the standard enthalpies and entropies of formation of hydrated ions. The application of correspondence principle to estimate thermodynamic data at high temperature was explained.

Calculation of Data Reliability with Entropy for Fuzzy Sets

  • Wang, Hongmei;Lee, Sang-Hyuk
    • International Journal of Fuzzy Logic and Intelligent Systems
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    • v.9 no.4
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    • pp.269-274
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    • 2009
  • Measuring uncertainty for fuzzy sets has been carried out by calculating fuzzy entropy. Fuzzy entropy of fuzzy set is derived with the help of distance measure. The distance proportional value between the fuzzy set and the corresponding crisp set is designed as the fuzzy entropy. The usefulness is verified by proving the proposed entropy. Generally, fuzzy entropy contains the complementary characteristics that the fuzzy entropies of fuzzy set and complementary fuzzy set have the same entropies. Discrepancy that low fuzzy entropy did not guarantee the data certainty was overcome by modifying fuzzy entropy formulation. Obtained fuzzy entropy is analyzed and discussed through simple example.