• 대한기계학회논문집B
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• 제34권2호
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• pp.203-212
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• 2010

수분류 스프레이 냉각은 많은 산업적인 응용분야에 넓게 사용되고 있다. 본 연구는 수분류 스프레이가 표면거칠기가 주어진 $900^{\circ}C$ 고온강판의 표면에 충돌하는 경우, 열유속 및 열전달계수의 정량적인 측정을 통해 표면거칠기가 수분류 스프레이 냉각에 미치는 영향을 고찰하였다. 이 때의 국소 열유속은 시편, 카트리지히터, 열전대의 조합으로 고안된 고유의 열유속게이지를 제작하여 엄밀하게 측정되었다. 평균 표면거칠기 높이를 기준으로 40, 60, $80{\mu}M$의 3 가지 표면과 매끈한 표면에 대한 수분류 스프레이 냉각 의 열전달 현상이 비교 및 평가되었다. 표면거칠기가 주어진 표면에서의 돌출물은 얇은 열 경계층두께를 통과할 수 있기 때문에 표면거칠기가 주어진 경우에 열전달은 뚜렷하게 증가하였고, 표면거칠기의 의한 열전달 향상 기구는 서로 다른 비등영역에 대해 구분하여 조사되었다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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• pp.225.1-225.1
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• 2010

Within recent years attention has been focused on the method of hydrogen storage using metal hydride reactor due to its high energy density, durability, safety and low operating pressure. In this paper, a numerical study is carried out to investigate the coupled heat and mass transfer process for absorption in a cylindrical metal hydride hydrogen storage reactor using a newly developed model. The simulation results demonstrate the evolution of temperature, equilibrium pressure, H/M atomic ratio and velocity distribution as time goes by. Initially, hydrogen is absorbed earlier from near the wall which sets the cooling boundary condition owing to that absorption process is exothermic reaction. Temperature increases rapidly in entire region at the beginning stage due to the initial low temperature and enough metal surface for hydrogen absorption. As time goes by, temperature decreases slowly from the wall region due to the better heat removal. Equilibrium pressure distribution appears similarly with temperature distribution for reasons of the function of temperature. This work provides a detailed insight into the mechanism and corresponding physicochemical phenomena in the reactor during the hydrogen absorption process.

• Journal of electromagnetic engineering and science
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• 제16권4호
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• pp.219-224
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• 2016

In this paper, coupled-mode theory (CMT) is used to obtain a transient solution analytically for a wireless power transfer system (WPTS) when unit energy is applied to one of two resonators. The solutions are compared with those obtained using equivalent circuit-based analysis. The time-domain CMT is accurate only when resonant coils are weakly coupled and have large quality factors, and the reason for this inaccuracy is outlined. Even though the time-domain CMT solution does not describe the WPTS behavior precisely, it is accurate enough to allow for an understanding of the mechanism of energy exchange between two resonators qualitatively. Based on the time-domain CMT solution, the critical coupling coefficient is derived and a criterion is suggested for distinguishing inductive coupling and magnetic resonance coupling of the WPTS.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2006년도 추계학술대회논문집
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• pp.950-953
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• 2006

The floor impact noise of concrete structures in apartments buildings is affected from the flexural wave propagation characteristics. Accordingly, the measurement of wave propagation characteristics is required for suggestion of efficient method to reduce the impact noise. The purpose of this article is to propose an experimental technique to measure dynamic properties of concrete structures. The method was proposed using the flexural wave propagation characteristics. Wave speeds, bending stiffness and their loss factors are estimated from which the vibration dissipation capabilities are investigated. Several different concrete beam structures were custom-built for measurement. The damping treatments using viscoelastic materials for reducing noise generation are also tested. The beam transfer function of the damped beam is predicted using the compressional damping model from which the mechanism of the vibration energy dissipation is investigated.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2002년도 학술대회지
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• pp.655-658
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• 2002

The present paper investigated the effect of ultrasonic vibrations on the melting process of a phase-change material (PCM). Furthermore, the present study considered constant heat-flux boundary conditions unlike many of the previous researches, which had adopted constant wall-temperature conditions. Therefore in the study, modified dimensionless numbers such as Stefan and Rayleigh were adopted to represent heat transfer results. The experimental results revealed that ultrasonic vibrations accompanied the effects like agitation, acoustic streaming, cavitation, and oscillating fluid motion, accelerating the melting process as much as 2.5 times, compared with the result of natural melting (i. e., the case without ultrasonic vibration). Such effects are believed to be a prime mechanism in the overall melting process when ultrasonic vibrations were applied. Subsequently, energy could be saved by applying the ultrasonic vibrations to the natural melting In addition, various time-wise dimensionless numbers provided a conclusive evidence of the important role of the ultrasonic vibrations on the melting phenomena of the PCM.

• 공업화학
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• 제8권3호
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• pp.416-424
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• 1997

본 연구에서는 고밀집 섬유체에 의한 정적 액-액 접촉기에 대한 이론적 모델링을 통하여 섬유체 접촉기 내부에서의 물질 이동과정과 각 상에서의 축 방향 농도분포 해석이 수행되었고, 여러 운전 조건하에서 출구 농도를 예측하여 실험치와 비교하였다. 본 섬유체 액-액 추출기는 그 구조적 특성 때문에 축 방향 분산이 없는 플러그 흐름 모델로 완벽하게 묘사될 수 있었으며 data fitting을 통해 결정되어 모델식에 적용된 물질전달 계수와 섬유체 추출기 축 방향 반위 길이 당 물질전달 면적의 곱의 항인 $k_a{\sigma}$은 그 섬유체 추출기의 고유 특성 값으로 사용될 수 있었고, 그 값은 약 0.0327cm2/sec이었다.

• 한국태양에너지학회 논문집
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• 제34권5호
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• pp.73-80
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• 2014

This study introduces and analyzes the geothermal energy availability in Non-active volcanic region. Jeju island in Korea is situated in non-active volcanic region. The island is composed of rock with high pore and clinker, scoria geological layer formed by volcanic activity about two million ago. Volcanic geological layers with porous characteristics have air, vapor, water and a underground structure through which air or water can move easily. For this reason, it is probable that the mechanism of energy acquisition is by convective heat transfer. For this presumption, the availability of underground air as energy source has been studied here through theoretical analysis and experimental data. The energy output of our system ranged from 2,485,076 kJ/day to 4,060,978 kJ/day monitored using variable velocity air flow controller. Our system has capability to be a reliable energy source irrespective of environmental changes. Consequently, underground air can be utilized for energy source and provide the optimal design of heating/cooling system.

• Bulletin of the Korean Chemical Society
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• 제35권9호
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• pp.2717-2722
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• 2014

The reaction mechanism between azacyclopropenylidene and epoxypropane has been systematically investigated employing the second-order M${\o}$ller-Plesset perturbation theory (MP2) method to better understand the reactivity of azacyclopropenylidene with four-membered ring compound epoxypropane. Geometry optimization, vibrational analysis, and energy property for the involved stationary points on the potential energy surface have been calculated. It was found that for the first step of this reaction, azacyclopropenylidene can insert into epoxypropane at its C-O or C-C bond to form spiro intermediate IM. It is easier for the azacyclopropenylidene to insert into the C-O bond than the C-C bond. Through the ring-opened step at the C-C bond of azacyclopropenylidene fragment, IM can transfer to product P1, which is named as pathway (1). On the other hand, through the H-transferred step and subsequent ring-opened step at the C-N bond of azacyclopropenylidene fragment, IM can convert to product P2, which is named as pathway (2). From the thermodynamics viewpoint, the P2 characterized by an allene is the dominating product. From the kinetic viewpoint, the pathway (1) of formation to P1 is primary.

• Bulletin of the Korean Chemical Society
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• 제35권2호
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• pp.483-488
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• 2014

The nucleophilic substitution reactions of Y-aryl methyl (8) and Y-aryl propyl (10) chlorothiophosphates with X-pyridines are studied kinetically in acetonitrile at $35.0^{\circ}C$. The Hammett and Bronsted plots with X in the nucleophiles for both substrates exhibit biphasic concave upwards with a break region between X = 3-Me and H. The obtained values of the cross-interaction constants (${\rho}_{XY}$) are negative with 8 while positive with 10 despite the same free energy correlations with X for both substrates. A stepwise mechanism with a rate-limiting bond formation is proposed with 8, whereas a stepwise mechanism with a rate-limiting leaving group departure from the intermediate is proposed with 10 based on the sign of ${\rho}_{XY}$, negative and positive with 8 and 10, respectively. A frontside nucleophilic attack is proposed with strongly basic pyridines based on the considerably great magnitudes of ${\rho}_X$ and ${\beta}_X$ values while a backside attack is proposed with weakly basic pyridines based on the relatively small magnitudes of ${\rho}_X$ and ${\beta}_X$ for both substrates.

• Bulletin of the Korean Chemical Society
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• 제33권3호
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• pp.1042-1046
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• 2012

The kinetics and mechanism of the pyridinolysis ($XC_5H_4N$) of diethyl isothiocyanophosphate are investigated in acetonitrile at $55.0^{\circ}C$. The Hammett and Bronsted plots for substituent X variations in the nucleophiles exhibit the two discrete slopes with a break region between X = 3-Ac and 4-Ac. These are interpreted to indicate a mechanistic change at the break region from a concerted to a stepwise mechanism with rate-limiting expulsion of the isothiocyanate leaving group from a trigonal bipyramidal pentacoordinated intermediate. The relatively large ${\beta}_x$ values with more basic and less basic pyridines imply much greater fraction of frontside nucleophilic attack TSf than that of backside attack TSb.