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Appraisal of Concrete Performance and Plan for Stable Use of EAF Oxidizing Slag as Fine Aggregate of Concrete (전기로 산화슬래그 잔골재를 사용한 콘크리트의 성능 평가)

  • Cho, Bong-Suk;Lee, Hoon-Ha;Yang, Seung-Kyu;Lee, Woong-Jong;Um, Tai-Sun
    • Journal of the Korea Concrete Institute
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    • v.21 no.3
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    • pp.367-375
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    • 2009
  • Recently, more focus is shift to imbalances in aggregate market supply and demand and an exhaustion of natural resources. In this situation, Electric arc furnace oxidizing slag (EAF slag) has high application possibility as aggregate for concrete due to similar property with general aggregate. However, it is inherent the problem which causes pop-out by free-CaO contained in slag In this study, we've got the plan to assure the chemical stability of EAF slag, and then experimentally tested the mechanical performance and durability for the fine aggregate used EAF slag. On this test result, we suggest the application plan. At the result of this study, it shows that EAF slag would reduce the surface defect such as pop-out due to natural aging for the fixed hour and adjustment the grain size of EAF slag. And mechanical performance and durability according to the replacement rate of concrete service, were revealed more than equal or equal compare to general aggregate. Hereafter, quality control must precede not to impede the beauty of concrete surface as assure the safety for aging and processing. And, to establish the environmental resource recycling system for by-products of steel, it should be made development of various application and guideline of quality control for the EAF slag aggregate. Moreover, it must be constantly studied all kind of engineering performance and durability for related to this study.

Graphene Oxide (GO) Layered Structure Ion Exchange Membrane Application for Vanadium Redox Flow Battery (VRB) System Study (산화그라핀 (Graphene Oxide, GO)이 코팅된 양이온 교환막을 용한 바나듐 레독스 흐름 전지 (Vanadium Redox Flow attery, VRB) 시스템에 관한 연구)

  • Lee, Kwan Ju;Chu, Young Hwan
    • Journal of the Korean Electrochemical Society
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    • v.17 no.2
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    • pp.94-102
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    • 2014
  • Cation exchange membrane (Nafion) was modified to reduce the vanadium ion permeation through the membrane and to increase the vanadium redox flow battery (VRB) system performance by coating the graphene oxide (GO) which has nano-plate like morphology. Modified membrane properties were studied by measuring the ion exchange capacity (I.E.C), water uptake and proton conductivity. The thickness of the coated layer on the surface of the Nafion membrane was observed as $0.93{\mu}m$ by SEM. Proton conductivity and vanadium ion permeability of the modified membrane were decreased to 27% and 25% compared to that of the commercial Nafion membrane respectively. VRB single cell performance test was performed to compare the system performance of the VRB applied with commercial Nafion membrane and modified membrane. VRB system applied with modified membrane showed higher coulombic efficiency and energy efficiency than the VRB system applied with the commercial Nafion membrane due to the reduction of the vanadium ion permeation. From these result, we could suggest that the membrane modification by coating the GO on the surface of the Nafion membrane could be one of the promising strategies to reduce the vanadium ion permeation and to increase the VRB system performance effectively.

Sources of Carbonaceous Materials in the Airborne Particulate Matter of Dhaka

  • Begum, Bilkis A.;Hossain, Anwar;Saroar, Golam;Biswas, Swapan K.;Nasiruddin, Md.;Nahar, Nurun;Chowdury, Zohir;Hopke, Philip K.
    • Asian Journal of Atmospheric Environment
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    • v.5 no.4
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    • pp.237-246
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    • 2011
  • To explore the sources of carbonaceous material in the airborne particulate matter (PM), comprehensive PM sampling was performed (3 to 14 January 2010) at a traffic hot spot site (HS), Farm Gate, Dhaka using several samplers: AirMetrics MiniVol (for $PM_{10}$ and $PM_{2.5}$) and MOUDI (for size fractionated submicron PM). Long-term PM data (April 2000 to March 2006 and April 2000 to March 2010 in two size fractions ($PM_{2.2}$ and $PM_{2.2-10}$) obtained from two air quality-monitoring stations, one at Farm Gate (HS) and another at a semi-residential (SR) area (Atomic Energy Centre, Dhaka Campus, (AECD)), respectively were also analyzed. The long-term PM trend shows that fine particulate matter concentrations have decreased over time as a result of government policy interventions even with increasing vehicles on the road. The ratio of $PM_{2.5}/PM_{10}$ showed that the average $PM_{2.5}$ mass was about 78% of the $PM_{10}$ mass. It was also found that about 63% of $PM_{2.5}$ mass is $PM_1$. The total contribution of BC to $PM_{2.5}$ is about 16% and showed a decreasing trend over the years. It was observed that $PM_1$ fractions contained the major amount of carbonaceous materials, which mainly originated from high temperature combustion process in the $PM_{2.5}$. From the IMPROVE TOR protocol carbon fraction analysis, it was observed that emissions from gasoline vehicles contributed to $PM_1$ given the high abundance of EC1 and OC2 and the contribution of diesel to $PM_1$ is minimal as indicated by the low abundance of OC1 and EC2. Source apportionment results also show that vehicular exhaust is the largest contributors to PM in Dhaka. There is also transported $PM_{2.2}$from regional sources. With the increasing economic activities and recent GDP growth, the number of vehicles and brick kilns has significantly increased in and around Dhaka. Further action will be required to further reduce PM-related air pollution in Dhaka.

Identification and Quantification of Glucosinolates in Rapeseed (Brassica napus L.) Sprouts Cultivated under Dark and Light Conditions

  • Lee, Min-Ki;Arasu, Mariadhas Valan;Chun, Jin-Hyuk;Seo, Jeong Min;Lee, Ki-Teak;Hong, Soon-Taek;Kim, In Ho;Lee, Yong-Hwa;Jang, Young-Seok;Kim, Sun-Ju
    • Korean Journal of Environmental Agriculture
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    • v.32 no.4
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    • pp.315-322
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    • 2013
  • BACKGROUND: This study was performed for the identification and quantification of glucosinolate (GSL) contents in seven varieties of rapeseed (Brassica napus L.) sprouts cultivated under dark and light conditions. METHODS AND RESULTS: Crude glucosinolates (GSLs) were desulfated by treating with aryl sulfatase and purified using diethylaminoethyl sepharose (DEAE) anion exchange column. Individual GSLs were quantified using high-performance liquid chromatography (HPLC) with electrospray ionization-tandem mass spectrometry (ESI-MS/MS). Eleven GSLs including six aliphatic (progoitrin, sinigrin, glucoalyssin, gluconapoleiferin, gluconapin, and glucobrassicanapin), four indolyl (4-hydroxyglucobrassicin, glucobrassicin, 4-methoxyglucobrassicin, and neoglucobrassicin) and one aromatic (gluconasturtiin) were identified based on the fragmentation patterns of MS spectrum. Aliphatic GSLs were noted as the predominant group with average 85.2% of the total contents. The most abundant GSLs were progoitrin which was ranged at $8.14-118.68{\mu}mol/g$ dry weight (DW). The highest total GSL amounts were documented in 'Hanra' ($146.02{\mu}mol/g$ DW) under light condition and 'Mokpo No. 68' ($86.67{\mu}mol/g$ DW) in dark condition, whereas the lowest was in 'Tamra' (30.13 and $14.50{\mu}mol/g$ DW) in both conditions. The sum of aliphatic GSLs attributed > 80% in all varieties, except 'Tamra' (67.7% and 64.9% in dark and light conditions, respectively) in the total GSL accumulation. Indolyl GSLs were ranged $2.41-15.73{\mu}mol/g$ DW, accounted 2.78-33.6% of the total GSLs in rapeseed varieties. CONCLUSION(S): These results provide valuable information regarding potential beneficial GSL contents individually. This study attempts to contribute to knowledge of the nutritional properties of the different varieties of rapeseed plants. These results may be useful for the evaluation of dietary information.

Effects of different levels of crude protein and protease on nitrogen utilization, nutrient digestibility, and growth performance in growing pigs

  • Kim, Yong Ju;Kim, Tae Heon;Song, Min Ho;An, Ji Seon;Yun, Won;Lee, Ji Hwan;Oh, Han Jin;Lee, Jun Soeng;Kim, Gok Mi;Kim, Hyeun Bum;Cho, Jin Ho
    • Journal of Animal Science and Technology
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    • v.62 no.5
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    • pp.659-667
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    • 2020
  • This study was conducted to evaluate the effects of different levels of crude protein (CP) and protease on nitrogen (N) utilization, nutrient digestibility, and growth performance in growing pigs. A total of six crossbred ([Landrace × Yorkshire] × Duroc) barrows were individually accepted in 1.2 m × 0.7 m × 0.96 m stainless steel metabolism cages. The pigs (average initial body weight of 27.91 ± 1.84 kg) randomly assigned to six diets with six weeks (6 × 6 Latin square design). The experiment was carried out in an environment with a temperature of 23 ± 1.5℃, a relative humidity of 83 ± 2.3% and a wind speed of 0.25 ± 0.03 m/s. The dietary treatments were arranged in a 2 × 3 factorial design with two levels of CP (15.3% or 17.1%) and three levels of protease (0 ppm, 150 ppm, or 300 ppm). The average daily gain and gain to feed ratio (G:F) tended to increase (p = 0.074) with increasing amounts of protease. The low CP level diet reduced (p < 0.050) urinary and fecal N concentrations, the total N excretion in feces, and increased (p < 0.050) N retention. Different protease levels in the diet did not affect (p > 0.05) at N intake, but supplementation of the diets with 300 ppm protease decreased (p < 0.050) the N concentration in urine and feces and tended to increase (p = 0.061) the percentage of N retention retained of the total N intake. The dietary CP level did not affect (p > 0.050) the apparent total tract digestibility (ATTD) of dry matter, digestible energy (DE), and metabolic energy (ME), but diet supplementation with 300 ppm protease showed higher (p < 0.050) ATTD of DE and ME than in the protease-free diet. Therefore, a low protein diet with protease could improve the utilization of nitrogen, thereby reducing the negative effect of N excretion into the environment while maintaining or increasing growth performance compared to a high protein diet.

Learning Wind Speed Forecast Model based on Numeric Prediction Algorithm (수치 예측 알고리즘 기반의 풍속 예보 모델 학습)

  • Kim, Se-Young;Kim, Jeong-Min;Ryu, Kwang-Ryel
    • Journal of the Korea Society of Computer and Information
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    • v.20 no.3
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    • pp.19-27
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    • 2015
  • Technologies of wind power generation for development of alternative energy technology have been accumulated over the past 20 years. Wind power generation is environmentally friendly and economical because it uses the wind blowing in nature as energy resource. In order to operate wind power generation efficiently, it is necessary to accurately predict wind speed changing every moment in nature. It is important not only averagely how well to predict wind speed but also to minimize the largest absolute error between real value and prediction value of wind speed. In terms of generation operating plan, minimizing the largest absolute error plays an important role for building flexible generation operating plan because the difference between predicting power and real power causes economic loss. In this paper, we propose a method of wind speed prediction using numeric prediction algorithm-based wind speed forecast model made to analyze the wind speed forecast given by the Meteorological Administration and pattern value for considering seasonal property of wind speed as well as changing trend of past wind speed. The wind speed forecast given by the Meteorological Administration is the forecast in respect to comparatively wide area including wind generation farm. But it contributes considerably to make accuracy of wind speed prediction high. Also, the experimental results demonstrate that as the rate of wind is analyzed in more detail, the greater accuracy will be obtained.

Current States of the Global Water Market and Considerations for the Groundwater Industry in South Korea (물 시장의 현주소와 지하수 산업에 대한 고찰)

  • Kim, Byung-Woo;Koh, Yong-Kwon;Choi, Doo-Houng;Kim, Deog-Geun;Kim, Gyoo-Bum
    • The Journal of Engineering Geology
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    • v.24 no.3
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    • pp.431-440
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    • 2014
  • Since the establishment of the Groundwater Act in Korea in 1993, the national policy on groundwater has focused on the preservation and management of groundwater, which should be used only as a subsidiary water resource. However, population growth, increased water demand, climate change, and the need for uniform water distribution have brought changes to groundwater policy, and have led to the prioritization of development projects such as groundwater dams and river bank filtration. Population growth, changes to the water environment, and increased water risks have all played a role in triggering rapid growth within the water industry; the size of the investment in water resources will also continue to increase worldwide. Until now, private wells and bottled mineral water have led the groundwater industry in South Korea. However, a new area of the groundwater industry, which includes the health and medical sciences, employs groundwater properties derived from regional geology, and is growing. This requires the advancement of groundwater research and technical development connected with ICT (Information and Communication Technology) and medical science, and that the public development of groundwater and its various applications is expanded through locating groundwater in the core of the water industry cluster.

Study on Efficient Carbonizing Conditions When Carbonizing Fish Offal (어류폐기물의 탄화처리시 효율적 탄화조건에 관한 연구)

  • Jeong, Byung Gon
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.17 no.4
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    • pp.268-273
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    • 2014
  • Experiments on carbonization were conducted using fish offal generated from fish market for the purpose of resource recycling. Elemental composition of fish offal and effect of carbonation temperature on the overall yield were investigated. Carbon and hydrogen contents of fish offal were 51.1% and 7.6%, respectively in view of elemental composition. Particularly, nitrogen and sulfur contents were as high as 9.8% and 1.0%, respectively. These values suggests that odor problem of fish offal can be serious. Comparing elemental composition of fish offal with other waste materials, it is thought that carbon and hydrogen contents are considerably high. These implies that thermal disposal will be the best option for final disposal method of fish offal. As a results of carbonization experiments on Mackerel, Hairtail, Croaker and mixed sample of Mackerel, Hairtail and Croaker, carbonization patterns were quite similar irrespective of fish species. Carbonization yield was varied significantly depending on carbonization temperature at the carbonization time of 5 minutes and 10 minutes. When the carbonization time was maintained longer than 30 minutes, yield variation depending on time variation at each temperature was insignificant. Thus, it can be concluded that effect of carbonization time on overall yield was minor when the carbonization time was maintained longer than 30 minutes. Primary vaporization in carbonization conducted at the temperature of $400^{\circ}C$ was minor. Thus, difference of yield between temperature of $500^{\circ}C$ and $400^{\circ}C$ was appeared greatly. It can be concluded that yield difference depending on carbonization temperature can be neglected if the carbonizing temperature exceed $600^{\circ}C$ and carbonizing time exceed 10 minutes at the same time.

Prediction of Pulse Pressure and Pulse Interval of Change in Operation Conditions of a Pulse Air Jet Bag Filter (충격기류식 여과집진장치의 운전조건 변화에 따른 적정 탈진주기 및 탈진압력 설정)

  • Lee, Deok-Gi;Lim, Woo-Taik;Cho, Jae-Hwan;Choi, Kum-Chan;Shin, Hyun-Moo;Jang, Seong-Ho;Suh, Jeong-Min
    • Journal of Environmental Science International
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    • v.27 no.6
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    • pp.349-358
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    • 2018
  • In this study, using coke dust from ironwork, the pulse pressure on a pulse air jet bag filter was investigated considering the influence of the pressure loss due to filtration velocity and pressure intervals. The research on the optimal pulse pressure prediction of a pulse air jet type bag filter using coke dust showed the following results. Pressure loss volatility produced by the pulse pressure under low dust concentration(0.5, $1g/m^3$) and low face velocity(1.25 m/min) was less than $10mmH_2O$. This suggests that the pulse pressure has a low impact on the pressure loss. In contrast, pressure loss volatility under high dust concentration($3g/m^3$) and high face velocity(1.75 m/min) was $25mmH_2O$. Therefore, pulse pressure with high dust concentration and high face velocity has a strong influence on the pressure loss volatility, compared to the condition of low dust concentration and low face velocity. The optimal pulse pressure of inlet dust concentration($0.5g/m^3$) was $6kg/cm^2$ under the same face velocity(1.75 m/min). As concentration increased from 1 to $2g/m^3$, the pulse pressure gradually reached $5kg/cm^2$ thus indicating that the pulse pressure($5kg/cm^2$) is pertinent at a high concentration($3g/m^3$). The pulse intervals: 20, 25 and 30 sec, which are relatively longer than 10 and 15 sec, corresponded to high pressure loss volatility produced by the pulse pressure. Furthermore, low pressure loss volatility was noted at $5kg/cm^2$ of the overall pulse pressure.

A Study on Biogas Production from Low Rank Coal in a Column Experiment (저품위 석탄을 충전한 칼럼실험에서의 바이오가스 생산에 관한 연구)

  • Yoon, Seok-Pyo;Lim, Hak-Sang;Yun, Yeo-Myeong
    • Journal of the Korea Organic Resources Recycling Association
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    • v.25 no.1
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    • pp.57-65
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    • 2017
  • In a column experiment with low rank coal, rice straw was additionally supplied to induce methane gas generation by microorganisms in the state of supplying microorganisms and nutrients, and long-term biogas production characteristics were observed. When the weight ratio of the rice straw to coal was 0.04 or less, there was no significant gas generation. At 0.08, the biogas was generated for about 90 days. However, the methane gas generation was only 5% compared with the vial test result at optimum condition. Therefore, in order to produce biogas in the coal deposit in situ, a reactor that operates at COD concentration of 2000 mg/L or more at a ratio of 1:3 or more of rice straw to coal should be installed on the ground or under the ground. Liquid from the column filled with coal and rice straw and a liquid from vial containing rice straw were analyzed by microbial community analysis using pyrosequencing method, and compared the dominant microbial species among the two samples. In terms of the uniformity and diversity of the bacteria, the coal-filled column showed various species distribution, which has shown to be a disadvantageous microbial distribution to methane production.