• Title/Summary/Keyword: energy ratios

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Hydrogen Production from Splitting of Methanol/Water Solution Using Perovskite Structured NbxSrTi1-xO3 Photocatalyts (Perovskite NbxSrTi1-xO3 광 촉매를 이용한 메탄올/물 분해로부터 수소제조)

  • Kim, Dongjin;Han, Gi Bo;Park, No-Kuk;Lee, Tae Jin;Kang, Misook
    • Korean Chemical Engineering Research
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    • v.51 no.4
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    • pp.513-517
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    • 2013
  • This study focused on the synthesis of $Nb_xSrTi_{1-x}O_3$ photocatalysts which partially inserted Nb ions with excellent ability of fluorescence into the perovskite structured $SrTiO_3$ frameworks and their photocatalytic hydrogen productions from methanol/water splitting corresponding to the molar ratios of Ti and Nb. The characteristics of the synthesized $SrTiO_3$ and $Nb_xSrTi_{1-x}O_3$ powders were analyzed by X-ray diffraction (XRD), energy dispersive X-ray spectrometer (EDS), and UV-Visible spectrometer. The hydrogen evolution from methanol/water photo-splitting was enhanced over $Nb_{0.05}SrTi_{0.95}O_3$ compared to those over $SrTiO_3$ and another $Nb_xSrTi_{1-x}O_3$; 4.9 mL of hydrogen gases was collected after 8 h when 0.5g of $Nb_{0.05}SrTi_{0.95}O_3$ catalyst was used in pH 10.

Seismic Traveltime Tomography in Inhomogeneous Tilted Transversely Isotropic Media (불균질 횡등방성 매질에서의 탄성파 주시토모그래피)

  • Jeong, Chang-Ho;Suh, Jung-Hee
    • Geophysics and Geophysical Exploration
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    • v.10 no.4
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    • pp.229-240
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    • 2007
  • In this study, seismic anisotropic tomography algorithm was developed for imaging the seismic velocity anisotropy of the subsurface. This algorithm includes several inversion schemes in order to make the inversion process stable and robust. First of all, the set of the inversion parameters is limited to one slowness, two ratios of slowness and one direction of the anisotropy symmetric axis. The ranges of the inversion parameters are localized by the pseudobeta transform to obtain the reasonable inversion results and the inversion constraints are controlled efficiently by ACB(Active Constraint Balancing) method. Especially, the inversion using the Fresnel volume is applied to the anisotropic tomography and it can make the anisotropic tomography more stable than ray tomography as it widens the propagation angle coverage. The algorithm of anisotropic tomography is verified through the numerical experiments. And, it is applied to the real field data measured at limestone region and the results are discussed with the drill log and geological survey data. The anisotropic tomography algorithm will be able to provide the useful tool to evaluate and understand the geological structure of the subsurface more reasonably with the anisotropic characteristics.

Boundary conditions for Time-Domain Finite-Difference Elastic Wave Modeling in Anisotropic Media (이방성을 고려한 시간영역 유한차분법 탄성파 모델링에서의 경계조건)

  • Lee, Ho-Yong;Min, Dong-Joo;Kwoon, Byung-Doo;Lim, Seung-Chul;Yoo, Hai-Soo
    • Geophysics and Geophysical Exploration
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    • v.11 no.2
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    • pp.153-160
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    • 2008
  • Seismic modeling is used to simulate wave propagation in the earth. Although the earth's subsurface is usually semi-infinite, we cannot handle the semi-infinite model in seismic modeling because of limited computational resources. For this reason, we usually assume a finite-sized model in seismic modeling. In that case, we need to eliminate the edge reflections arising from the artificial boundaries introducing a proper boundary condition. In this study, we changed three kinds of boundary conditions (sponge boundary condition, Clayton and Engquist's absorbing boundary condition, and Higdon's transparent boundary condition) so that they can be applied in elastic wave modeling for anisotropic media. We then apply them to several models whose Poisson's ratios are different. Clayton and Engquist's absorbing boundary condition is unstable in both isotropic and anisotropic media, when Poisson's ratio is large. This indicates that the absorbing boundary condition can be applied in anisotropic media restrictively. Although the sponge boundary condition yields good results for both isotropic and anisotropic media, it requires too much computational memory and time. On the other hand, Higdon's transparent boundary condition is not only inexpensive, but also reduce reflections over a wide range of incident angles. We think that Higdon's transparent boundary condition can be a method of choice for anisotropic media, where Poisson's ratio is large.

Effects of Gamma Irradiation on the Survival and Development of the Multicolored Asian Ladybird Beetle, Harmonia axyridis (Coccinellidae; Coleoptera) (감마선이 무당벌레의 생존과 발육에 미치는 영향)

  • Seo, Mi-Ja;Lee, Hee-Jin;Kang, Eun-Jin;Kang, Si-Yong;Yu, Yong-Man;Youn, Young-Nam
    • Korean journal of applied entomology
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    • v.50 no.4
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    • pp.335-342
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    • 2011
  • The effects of gamma irradiation on the survival, development, fecundity, and sex ratio of the multicolored Asian ladybird beetle (Harmonia axyridis) were investigated. A dose of more than 50 Gy dose of irradiation on eggs completely inhibited hatch, and 1st and 3rd instar larva irradiated with over 40 Gy almost died. Adverse effects of gamma irradiation over 70 Gy were also observed in the survival and development of pupae and adults. Although irradiated individuals usually survived, they had longer periods of larval and pupal development than untreated individuals. Slight female-biased sex ratios were observed in some treatments. However, sex ratio differences soon equilibrated. Generally, inherited harmful effects of gamma irradiation were observed in F1 and F2 generations. Comet tail indicating DNA damage was showed in survival individuals exposed to gamma irradiation.

The Analysis of the Breakdown Voltage according to the Change of JTE Structures and Design Parameters of 4H-SiC Devices (4H-SiC 소자의 JTE 구조 및 설계 조건 변화에 따른 항복전압 분석)

  • Koo, Yoon-Mo;Cho, Doo-Hyung;Kim, Kwang-Soo
    • Journal of IKEEE
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    • v.19 no.4
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    • pp.491-499
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    • 2015
  • Silicon Carbide(SiC) has large advantage in high temperature and high voltage applications because of its high thermal conductivity and large band gap energy. When using SiC to design power semiconductor devices, edge termination techniques have to be adjusted for its maximum breakdown voltage characteristics. Many edge termination techniques have been proposed, and the most appropriate technique for SiC device is Junction Termination Extension(JTE). In this paper, the change of breakdown voltage efficiency ratio according to the change of doping concentration and passivation oxide charge of each JTE techniques is demonstrated. As a result, the maximum breakdown voltage ratio of Single Zone JTE(SZ-JTE), Double Zone JTE(DZ-JTE), Multiple Floating Zone JTE(MFZ-JTE), and Space Modulated JTE(SM-JTE) is 98.24%, 99.02%, 98.98%, 99.22% each. MFZ-JTE has the smallest and SZ-JTE has the largest sensitivity of breakdown voltage ratios according to the change of JTE doping concentration. Additionally the degradation of breakdown voltage due to the passivation oxide charge is analyzed, and the sensitivity is largest in SZ-JTE and smallest in MFZ-JTE, too. In this paper, DZ-JTE and SM-JTE is the best efficiency JTE techniques than MFZ-JTE which needs large doping concentration in short JTE width.

Ordinary Magnetoresistance of an Individual Single-crystalline Bi Nanowire (자발 성장법으로 성장된 단결정 Bi 단일 나노선의 정상 자기 저항 특성)

  • Shim, Woo-Young;Kim, Do-Hun;Lee, Kyoung-Il;Jeon, Kye-Jin;Lee, Woo-Young;Chang, Joon-Yeon;Han, Suk-Hee;Jeung, Won-Young;Johnson, Mark
    • Journal of the Korean Magnetics Society
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    • v.17 no.4
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    • pp.166-171
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    • 2007
  • We report the magneto-transport properties of an individual single crystalline Bi nanowire grown by a spontaneous growth method. We have successfully fabricated a four-terminal device based on an individual 400-nm-diameter nanowire using plasma etching technique to remove an oxide layer forming on the outer surface of the nanowire. The transverse MR (2496% at 110 K) and longitudinal MR ratios (38% at 2 K) for the Bi nanowire were found to be the largest known values in Bi nanowires. This result demonstrates that the Bi nanowires grown by the spontaneous growth method are the highest-quality single crystalline in the literatures ever reported. We find that temperature dependence of Fermi energy ($E_F$) and band overlap (${\triangle}_0$) leads to the imbalance between electron concentration ($n_e$) and hole concentration ($n_h$) in the Bi nanowire, which is good agreement with the calculated $n_e\;and\;n_h$ from the respective density of states, N(E), for electrons and holes. We also find that the imbalance of $n_e\;and\;n_h$ plays a crucial role in determining magnetoresistance (MR) at T<75 K for $R_T$ and at T<205 K for $R_L$, while mean-free path is responsible for MR at T>75 K for $R_T$ and T>205 K for $R_L$.

Preparation of KCl through Removal of Heavy Metals from Chlorine By-Pass Dust (염소 바이패스 더스트를 이용한 염화칼륨 제조 및 중금속 제거)

  • Yun, Youngmin;Yeom, Nari;Lee, Kabsoo;Eom, Seonhui;Lee, Yonghyun;Chu, Yongsik
    • Resources Recycling
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    • v.26 no.2
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    • pp.11-17
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    • 2017
  • Many problems are occurred by using industrial by-product and municipal solid waste in the cement manufacturing process. The main components of chlorine by-pass dust generated by the use of the wastes are $K^+$, $Cl^-$, and a slight amount of heavy metals is also contained. In terms of waste recycling, it is necessary to eliminate the heavy metals. Therefore, in this study, the experiments for the removal of heavy metals from KCl which was produced by chlorine by-pass dust were conducted. In order to find optimum conditions for the removal of heavy metals, we have controlled the amount of water and precipitator. The type and concentration of heavy metals in KCl were analyzed. The concentration of heavy metals decreased as amount of precipitator increased. The heavy metals such as Pb, Cd, and As were not detected in dust A and B, when the mixing ratios between dust A(B) and water were controlled to be 1:2 (1:2, 1:3.5) with the addition of 3% precipitator (NaOCl).

Treatment of Liquid Waste Containing Highly Concentrated Ethylenediaminetetraaceticacid by Using Underwater Electrical Discharge (수중 전기방전을 이용한 에틸렌디아민테트라아세트산 폐액의 처리)

  • Jo, Jin-Oh;Mok, Young-Sun;Kang, Duk-Won
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.5
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    • pp.564-570
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    • 2007
  • This study investigated the treatment of liquid waste containing highly concentrated iron(III)-ethylenediaminetetraaceticacid (Fe(III)-EDTA) of 70,000 mg/L by an underwater electrical discharge process using low voltage and high current. When AC voltage is applied to the discharging electrode with the other electrode grounded, the temperature of the liquid waste around the discharging electrode rapidly increases, and at the same time, hydrogen and oxygen gases are formed at the electrode as a result of electrochemical reactions. Ultimately, gases formed by vaporization of water and electrochemical reactions cover the electrode. Since the liquid waste is electrically conductive, it elongates the ground electrode up to the border of the gas layer, where electrical discharge occurs. Without hydrogen peroxide, electrical discharge was able to remove about 50% of Fe(III)-EDTA. As the concentration of hydrogen peroxide added increased, the removal efficiency of Fe(III)-EDTA increased. When the molar ratio of hydrogen peroxide to the initial Fe(III)-EDTA was higher than 24.7, more than 80 g of Fe(III)-EDTA was removed with an energy of 1 kWh. A comparison between tungsten and steel electrodes showed that electrode material did not affect the Fe(III)-EDTA removal. In the present underwater electrical discharge process, the removal of Fe(III)-EDTA was completed within 30 min at molar ratios of hydrogen peroxide to the initial Fe(III)-EDTA higher than 24.7.

Cyclic Loading Test for Beam-to-Column Connections of Concrete Encased CFT Column (콘크리트피복충전 각형강관 기둥-보 접합부의 주기하중 실험)

  • Park, Hong Gun;Lee, Ho Jun;Park, Sung Soon;Kim, Sung Bae
    • Journal of Korean Society of Steel Construction
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    • v.26 no.1
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    • pp.55-68
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    • 2014
  • In this study, the beam-to column connections of concrete-encased-and-filled steel tube columns were tested under cyclic loading. Two specimens using steel beams and two specimens using precast concrete beams were tested. The dimension of the column cross section was $670mm{\pm}670mm$. The beam depths were 488mm and 588mm for the steel beams and 700mm for the precast concrete beams. The longitudinal bar ratios of the precast concrete beams were 1.1% and 1.5%. For the connections to the steel beams, continuity plates were used in the tube columns. For the connections to the PC beams, couplers were used for beam re-bar connections. The test results showed that except for a specimen, deformation capacities of the specimens were greater than 4% rotation angle, which is the requirement for the Special Moment Frame. Particularly, specimens using precast concrete beam showed excellent performances in the strength, deformation, and energy dissipation.

Synthesis and Photoalignment of Soluble Polyimides Containing 4-Styrylpyridine Derivatives as Photoreactive Side Groups (광반응 곁사슬기로서 4-스티릴피리딘유도체를 가지는 용해성 폴리이미드의 합성과 광배향)

  • 김민우;안득균;이동호;박이순;서관호;하기룡;김우식
    • Polymer(Korea)
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    • v.28 no.4
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    • pp.314-320
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    • 2004
  • Soluble aromatic polyimides bearing 4-(4-oxyalkyleneoxystyryl)- pyridines (ethylene and hexylene) as photoreactive side groups were synthesized and characterized. The photoreactive polymers were soluble in various polar organic solvents and their films were easily formed by solution casting. The photoreactivities of the polymers in the film state were approximately 64% at an exposure energy of 1.5 J/$\textrm{cm}^2$. Transmittances of the polymer films were about 85% after annealing at 20$0^{\circ}C$. Therefore, these polymers can be evaluated to be photoreactive polyimides with good transparency and solubility. The dichroic ratios of the polymers with ethylene and hexylene groups as the alkylene spacers were 0.023 and 0.026, respectively. The order parameters of 4'-pentyl-4-bipheny1carbonitrile as a liquid crystal (LC) in the film cells of the former and latter polymers were 0.50 and 0.52, respectively. These results indicate that the polymers show the effect of alkylene spacer on the photoalignments. The LC in the film cells of the polymers was perpendicularly oriented to the electric vector of the linear polarized UV light (LPUVL).