• Title/Summary/Keyword: emission 파장

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Plasma monitoring using optical emission spectroscopy and expert system (광반사분광기와 전문가 시스템을 이용한 플라즈마 감시)

  • Kim, Dae-Hyeon;Kim, Byeong-Hwan
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2009.10a
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    • pp.235-236
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    • 2009
  • 본 연구에서는 Optical emission spectroscopy (OES)에 CUSUM과 전문가 시스템을 이용하여 플라즈마를 감시하는 기법을 개발하였다. CUSUM과 Dempster-Shafer를 이용하여 고장에 민감한 OES파장을 추출하였으며, 추출된 파장은 플라즈마 감시에 이용될 것으로 기대된다.

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Development of Analytical Method of Organophosphates in Sea water by Finger Printing Fluorescence Spectroscopy (형광분석을 이용한 지문방식의 해수중 유기인의 분석 방법)

  • PARK Mi-Ok
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.30 no.3
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    • pp.377-387
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    • 1997
  • Primary fluorescence characteristics of ten standard solutions of organophosphates, sea water, and water from agricultural land were investigated by fluorescence contour. All the standard solutions of organophosphates has shown characteristics countours. Their emission maxima were shown between 296 nm and 437 nm. According to their numbers of emission maxima on the fluorescence contours, the organophosphates can be categorized in two different groups. Ateric and Diazinon are the first group with two emission maxima. DDVP with other seven standard organophosphates belong to the second group. The second group has two subgroups. One is characterized by the similar emission and excitation maxima, which are 310 nm and 280 nm, respectively. Those are DDVP, Hinosan, Kitazin, Locsion, Meta. The other sub-group shows quite different emission and excitation maxima from the first sub-group. They are Monopho, Thaconyl and Gropho and their emisson maxima were in far longer (437 nm) or shorter wavelength (296 nm). From agricutural samples, one of the investigated organophosphates was detetected by its characteristic retention time $(t_r=12min)$. HPIC-fluorescence data gave an additional parameter for differentiation between two organophosphates which has similar excitation and emission maxima.

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Optimization of the Coupling and the Reflector Material in the DOI PET Detector Module using the WLS Fiber (파장변이섬유를 사용하는 반응 위치 측정 양전자방출 단층촬영기기 검출기 모듈의 연결물질과 반사체 물질의 최적화)

  • Lee, Seung-Jae
    • Journal of the Korean Society of Radiology
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    • v.13 no.1
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    • pp.15-20
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    • 2019
  • We developed a novel depth-of-interaction positron emission tomography (PET) detector using wavelength shifting (WLS) fibers and optimized it. The optimization module was designed by using two scintillators and three WLS fibers and attaching a sensor to the end of the WLS fiber. Optimum combinations were obtained through the light collection efficiency and the light collection ratio between sensors depending on coupling materials and reflectors of scintillators, WLS fibers and sensors. The highest light collection efficiency and the light collection ratio between sensors were obtained in the combination of the epoxy (coupling materials)-diffuse reflector (scintillators)-specular reflector (WLS fibers).

Scintillation Properties of Acrylate Based Plastic Scintillator by Photoploymerization Method (아크릴레이트 기반 광중합 플라스틱 섬광체의 섬광 특성)

  • Kim, Sunghwan;Lee, JoonIl
    • Journal of radiological science and technology
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    • v.39 no.4
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    • pp.637-642
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    • 2016
  • In this study, we prepared and characterized a acrylate based UV-curable plastic scintillator. It was used co-polymers TMPTA, DHPA and Ultima $Gold^{TM}$ LLT organic scintillator. The emission spectrum of the plastic scintillator was located in the range of 380~520 nm, peaking at 423 nm. And the scintillator is more than 50% transparent in the range of 400~800 nm. The emission spectrum is well match to the quantum efficiency of photo-multiplier tube and the fast decay time of the scintillation is 12 ns, approximately. This scintillation material provides the possibility of combining 3D printing technology, and then the applications of the plastic scintillator may be expected in human dosimetry etc.

Determination of carbaryl in aqueous solution by fluorescence spectrometry (형광분광법을 이용한 수용액 중의 carbaryl의 정량)

  • Kim, Wook Hyun;Lee, Sang Hak
    • Analytical Science and Technology
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    • v.22 no.4
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    • pp.307-312
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    • 2009
  • A spectrofluorimetric methods has been developed for the determination of carbaryl in an aqueous solution. The effects of excitation wavelength, concentration of surfactant, concentration of ethanol as cosurfactant and emission wavelength on the fluorescence intensity were investigated to find the optimum experimental conditions to determine carbaryl. The emission intensity of the carbayl was increased with addition of sodium dodecyl sulfate (SDS) as a surfactant. The emission intensity of the carbaryl was further increased with addition of ethanol as a co-surfactant. The optimum conditions were 281 nm for excitation wavelength, $1.0{\times}10^{-2}mol/L$ SDS, 20% (v/v) ethanol and 349 nm for emission wavelength. Under the optimum conditions, the emission intensity increased with the carbaryl concentration in the range of $5{\times}10^{-7}$ to $1.0{\times}10^{-4}mol/L$ with a detection limit ($3{\sigma}$) of $1.1{\times}10^{-8}mol/L$. The resulting correlation coefficient of the working curve was 0.9996.

A Study on the Cathodoluminescence and Structure of Thin Film $ZnGa_2O_4:Mn$ Oxide Phosphor (박막형 $ZnGa_2O_4:Mn$ 산화물 형광체의 음극선루미느센스와 구조적 특성에 관한 연구)

  • Kim, Joo-Han;Holloway Paul H.
    • Journal of the Korean Vacuum Society
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    • v.15 no.5
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    • pp.541-546
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    • 2006
  • In this study we have investigated cathodoluminescence (CL) and structural properties of thin film $ZnGa_2O_4:Mn$ oxide phosphor by using field emission scanning electron microscopy (FESEM), atomic force microscopy (AFM), photoluminescence (PL), and cathodoluminescence. PL emission peaked at 506 nm was observed from the $ZnGa_2O_4:Mn$ phosphor target and it was attributed to the $^4T_1-^6A_1$ transition in $Mn^{2+}$ ion. The color coordinates of the emission were x = 0.09 and y = 0.67. The $ZnGa_2O_4:Mn$ films showed the excitation spectrum peaked at 294 nm by $Mn^{2+}$ ion absorption. It was found that the higher intensity of CL emission at 505 nm appears to result from the denser and closely-packed structure in $ZnGa_2O_4:Mn$ phosphor films deposited at lower pressures. The CL intensity did not show any systematic dependence on film surface roughness.

Study on Modeling the Spectral Solar Radiation Absorption Characteristics in Determining the surface Temperature of a Ground Object (지상물체의 표면온도 계산을 위한 파장별 태양복사 흡수특성 모델링 연구)

  • Choi, Jun-Hyuk;Gil, Tae-Jun;Kim, Tae-Kuk
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.35 no.1
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    • pp.33-39
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    • 2007
  • This paper is aimed at the development of a software that predicts the surface temperature profiles of three-dimensional objects on the ground by considering the spectral solar radiation through the atmosphere. The spectral solar radiation through the atmosphere is modeled by using the well-known LOWTRAN7 code which analyzes the detailed spectral transmission characteristics by considering the atmospheric gas layers. In this paper, the transient temperature distribution over a cylinder is calculated by using the semi-implicit method. The spectral radiative surface properties such as the absorptivity and emissivity of the objects are used to model the effects of the solar irradiation and the surface emission. Both the detailed spectral modeling and the simple total modeling for the solar radiation absorption show fairly good agreement with each other by showing less than 3% difference in surface temperature.

Influence of Blue-Emission Peak Wavelength on the Reliability of LED Device (청색 피크 파장이 LED 소자에 미치는 영향)

  • Han, S.H.;Kim, Y.J.;Kim, J.H.;Jung, J.Y.;Kim, H.C.;Cho, G.S.
    • Journal of the Korean Vacuum Society
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    • v.21 no.3
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    • pp.164-170
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    • 2012
  • The dependance of degradation on the blue-peak wavelength is investigated with the blue light-emitting diode (LED) of InGaN/GaN with respect to the optical and the electrical characteristics of the devices. The LED devices emitting the blue-peak wavelength ranging from 437 nm to 452 nm is prepared to be stressed for a long aging time with three different currents of 60 mA, 75 mA and 90 mA, respectively. The degradation of optical intensity is observed with and without phosphor in the devices. The device without phosphor has been degraded significantly as the wavelength of blue-peak is decreased while the optical intensity of LED device with phosphor become less sensitive than that of device without phosphor. The electrical property does not depend on the emission peak wavelength. However, the series-resistance of LED device is slowly increased as the aging time is increased. The deformation of device is observed severely the short wavelength of blue-peak even with the same current since the short wavelength is absorbed substantially at the materials of device during the aging time. Consequently, in order to enhance the lifetime of LED devices, it is important to understand the optical degradation property of the materials against the specific wavelengths emitted from the blue chip.

확장형 히든마코브모델을 이용한 산화막 플라즈마 식각공정의 식각종료점 검출방법

  • Jeon, Seong-Ik;Kim, Seung-Gyun;Hong, Sang-Jin;Han, Seung-Su
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.407-407
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    • 2010
  • 본 논문에서는 확장된 히든마코브모델을 이용하여 플라즈마 식각공정에서 식각종료검출을 위한 방법을 연구하였다. 플라즈마 식각장비는 유도성 결합플라즈마 시스템을 사용하였으며, 종료점 검출을 위해 식각공정이 진행됨에 따른 플라즈마의 상태를 확인할 수 있는 광학 방사 분광기(Optical Emission Spectroscopy: OES)를 사용하였다. 식각이 진행되는 동안 여기되는 입자들은 특정한 재료에 해당하는 파장에서 빛을 방출한다. 플라즈마상태에서 여기되는 원자와 분자들에 의해서 방출되는 빛은 OES를 통해 식각되는 물질을 확인하기 위해서 특별한 파장의 빛을 선택하여 분석한다. 본 논문에서는 확장된 히든마코브모델을 이용해 산화물이 식각될 때 방출하는 고유한 파장의 빛을 분석하여 식각이 종료되는 시점을 찾는 연구를 하였다. 제안된 확장형 히든마코브 모델은 세미-마코브모델과 분절특징 히든마코브모델을 결합한 것으로, 확률적 통계기법을 통해 종료시점을 찾아내는 방법이다. OES를 통해 얻은 데이터는 식각 종료가 일어나기 전의 파장의 상태와 식각이 종료된 후의 파장의 상태로 구분되어지는데, 식각종료시점에서 파장의 상태가 변화하며 이를 감지하여 식각종료점을 검출한다. 분절특징 히든마코브모델을 이용하여 식각종료시점 전후의 파장의 상태를 모델링 하였으며, 일반적인 마코브 모델의 특정상태가 유지될 시간의 확률을 변형된 세미-마코브 모델을 이용하여 OES를 통해 얻은 데이터 내에서 식각 종료가 일어나기 전의 상태가 유지될 수 있는 확률을 모델링 하였다. 실험을 통해 얻어진 6개의 데이터중 4개를 학습을 위해 사용하여 모델링을 하였고 나머지 2개의 데이터를 검증을 위해 사용한 결과, 확장형 히든마코브모델의 식각종료시점검출에 있어 뛰어난 정확성과 우수성을 증명하였다.

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Synthesis and luminescence properties of $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ phosphors ($Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ 형광체의 합성과 발광 특성)

  • Sung, Hye-Jin;Huh, Young-Duk
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.16 no.6
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    • pp.267-272
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    • 2006
  • A series of $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ phosphors have been synthesized by solid-state reaction. The photoluminescence and structural properties of $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ have been examined. The $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ phosphors have a strong absorption at 400 nm, which is the emission wavelength of a violet light emitting diode (LED). The emission peaks of $SrGa_2S_4:Ce,Na$are located at 448 nm and 485 nm. The partial replacement of Sr by Ca in $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ causes a red shift of emission wavelengths. The $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ can be used as blue emitting phosphors pumped by the violet LED for fabricating the multi-band white LED.