Browse > Article

Synthesis and luminescence properties of $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ phosphors  

Sung, Hye-Jin (Department of Chemistry, Dankook University)
Huh, Young-Duk (Department of Chemistry, Dankook University)
Abstract
A series of $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ phosphors have been synthesized by solid-state reaction. The photoluminescence and structural properties of $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ have been examined. The $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ phosphors have a strong absorption at 400 nm, which is the emission wavelength of a violet light emitting diode (LED). The emission peaks of $SrGa_2S_4:Ce,Na$are located at 448 nm and 485 nm. The partial replacement of Sr by Ca in $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ causes a red shift of emission wavelengths. The $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ can be used as blue emitting phosphors pumped by the violet LED for fabricating the multi-band white LED.
Keywords
$Sr_{1-x}Ca_xGa_2S_4:Ce,Na$; Violet LED;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 S. Nakamura, M. Senob, N. Iwasa and S. Nagahama, 'High-power InGaN single-quantum-well-structure blue and violet light-emitting diodes', Appl. Phys. Lett. 67(13) (1995) 1868   DOI   ScienceOn
2 A. Kato, M. Yamazaki, H. Najafov, K. Iwai, A. Bayramov, C. Hidaka, T. Takizawa and S. Iida, 'Radiative and non-radiative processes of Ce related transitions in $CaGa_{2}S_{4} and SrGa_{2}S_{4}$, J. Phys. Chern. Solids 64(9-10) (2003) 1511   DOI   ScienceOn
3 T.E. Peters and J.A. Baglio, 'Luminescence and structural properties of thiogallate phosphors $Ce^{3+} and Eu^{2+}$ activated phosphors', J. Electrochem. Soc. 119(2) (1972) 230   DOI
4 M. Matsumura and W.B. White, 'Photoluminescence of sulfide phosphors with $MB_{2}S_{4}$ composition', J. Electrochern. Soc. 139(8) (1992) 2347   DOI
5 P. Schlotter, R. Schmidt and J. Schneider, 'Lumines. cence conversion of blue light emitting diodes', Appl. Phys. A. 64 (1997) 417   DOI   ScienceOn
6 Y.D. Huh, Y.S. Cho and Y.R. Do, 'The optical properties of $(Y_{1-x}Gd_{x})_{3-2}(AI_{1-y}Ga_{y})_{5}O_{12}$: Cez phosphors for white LED', Bull. Kor. Chem. Soc. 23(10) (2002) 1435   DOI
7 T. Mukai, M. Yamada and S. Nakamura, 'Current and temperature dependence of electroluminescence of InGaN-based UV/Blue/Green light-emitting diodes', Jpn, J. Appl. Phys. 37(11B) (1995) L1332
8 R.C. Weast, CRC Handbook of Chemistry and Physics, 70th Ed.; CRC Press (1995) F187
9 C. Guo, D. Huang and Q. Su, 'Methods to improve the fluorescence intensity of CaS: $Eu^{2+}$ red-emitting phosphor for white LED', Mater. Sci. Eng. B130(1-3) (2006) 189
10 S. Nakamura, 'The role of structural imperfections in InGaN-based blue light-emitting diodes and laser diodes', Science 281 (1998) 956   DOI   ScienceOn
11 F.L. Zhang, Y.C. Stoffers, J. Penczek, P.N. Yocom, D. Zaremba, B.K. Wagner and C.J. Summers, 'Low voltage cathodoluminescence properties of blue emitting $SrGa_{2}S_{4} : Ce^{3+}$ and ZnS : Ag,CI phosphors', Appl. Phys. Lett. 72(18) (1998) 2226   DOI   ScienceOn
12 Y.D. Huh, J.H. Shim, Y Kim and Y.R. Do, 'Optical properties of three-band white light emitting diodes'.', J. Electrochem. Soc. 150(2) (2003) H57   DOI   ScienceOn