• Title/Summary/Keyword: elemental technology

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Elemental Analysis of Bottom Ash from Incinerator by Neutron Activation Analysis (중성자 방사화분석법을 이용한 소각로 바닥재의 원소분석)

  • Moon, Jong-Hwa;Kang, Sang-Hoon;Kim, Sun-Ha;Chung, Young-Sam
    • Analytical Science and Technology
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    • v.16 no.5
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    • pp.418-425
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    • 2003
  • Inorganic elemental content of bottom ash generated from municipal solid waste incinerator was determined by neutron activation analysis. Bottom ash samples were collected monthly from incinerator located in city D, strained out by the 5 mm sieve, dried by oven and pulverized by agate mortar. The samples were irradiated at NAA #1 irradiation hole in HANARO research reactor of Korea Atomic Energy Research Institute and the irradiated samples were measured by HPGe-gamma-ray spectrometer. From the activity of measured nuclides, 33 elements including As, Cr, Cu, Fe, Mn, Sb and Zn were determined applying activity creation formula and nuclear data. The quality control was conducted by simultaneous analysis with NIST standard reference materials.

Changes in sedimentary structure and elemental composition in the Nakdong Estuary, Korea (낙동강 하구역 퇴적구조 및 원소조성 변화에 관한 연구)

  • Kim, Yunji;Kang, Jeongwon;Park, Seonyoung
    • Journal of Wetlands Research
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    • v.23 no.3
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    • pp.213-223
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    • 2021
  • To understand the sedimentary environment of Scirpus planiculmis habitat (Myeongji and Eulsuk tidal flats) in the Nakdong Estuary, this study analyzed the statistical parameters (sorting, skewness, and kurtosis) of grain size data and the major (Al, Fe, Mn, Mg, Ca, Na, K, Ti, and P), minor (Li, Sc, V, Cr, Co, Ni, Cu, Zn, Sr, Zr, Cs, Pb, Th, and U), and rare earth elements (REEs) in sediment cores. For Myeongji, the sediment structure of the upper part of the cores was poorly sorted, more finely skewed, and more leptokurtic due to construction of the West gate. By contrast, the Eulsuk cores all differed due to the contrasting floodgate operation patterns of the West and East gates. The linear discriminate function (LDF) results corresponded to the statistical parameters for grain size. At the Eulsuk tidal flat (sites ES05 and ES11), elemental distributions were representative of Al-, Fe- and Ca-associated profiles, in which the elements are largely controlled by the accumulation of their host minerals (such as Na- and K-aluminosilicate and ferromagnesium silicate) and heavy detrital minerals at the sites. Detrital minerals including the aluminosilicates are major factors in the elemental compositions at ES05, diluting the REE contents. However, clay minerals and Fe-oxyhydroxides, as well as REE-enriched heavy minerals, appeared to be controlling factors of the elemental composition at ES11. Therefore, the mineral fractionation process is important in determining the elemental composition during sedimentation, which reflects the depositional condition of riverine-saline water mixing at both sites.

Preparation of Carrageenan-based Antimicrobial Films Incorporated With Sulfur Nanoparticles

  • Saedi, Shahab;Shokri, Mastaneh;Rhim, Jong-Whan
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.26 no.3
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    • pp.125-131
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    • 2020
  • Carrageenan-based functional films were prepared by adding two different types of sulfur nanoparticles (SNP) synthesized from sodium thiosulfate (SNPSTS) and elemental sulfur (SNPES). The films were characterized using Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction spectroscopy (XRD), and thermal gravimetric analysis (TGA). Also, film properties such as UV-visible light transmittance, water contact angle (WCA), water vapor permeability (WVP), mechanical properties, and antibacterial activity were evaluated. SNPs were uniformly dispersed in the carrageenan matrix to form flexible films. The addition of SNP significantly increased the film properties such as water vapor barrier and surface hydrophobicity but did not affect the mechanical properties. The carrageenan/SNP composite film showed some antibacterial activity against foodborne pathogenic bacteria, L. monocytogenes and E. coli.

3D Visualization for Extremely Dark Scenes Using Merging Reconstruction and Maximum Likelihood Estimation

  • Lee, Jaehoon;Cho, Myungjin;Lee, Min-Chul
    • Journal of information and communication convergence engineering
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    • v.19 no.2
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    • pp.102-107
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    • 2021
  • In this paper, we propose a new three-dimensional (3D) photon-counting integral imaging reconstruction method using a merging reconstruction process and maximum likelihood estimation (MLE). The conventional 3D photon-counting reconstruction method extracts photons from elemental images using a Poisson random process and estimates the scene using statistical methods such as MLE. However, it can reduce the photon levels because of an average overlapping calculation. Thus, it may not visualize 3D objects in severely low light environments. In addition, it may not generate high-quality reconstructed 3D images when the number of elemental images is insufficient. To solve these problems, we propose a new 3D photon-counting merging reconstruction method using MLE. It can visualize 3D objects without photon-level loss through a proposed overlapping calculation during the reconstruction process. We confirmed the image quality of our proposed method by performing optical experiments.

Options Study for the Neutralization of Elemental Sodium During the Pyroprocessing of Used Nuclear Fuel

  • Westphal, Brian;Tolman, David;Tolman, Kevin;Frank, Steven;Herrmann, Steve;Warmann, Stephen;Marsden, Kenneth;Patterson, Michael
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.2
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    • pp.113-118
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    • 2020
  • An options study was performed for the treatment of residual elemental sodium in driver plenums following the chopping operation during the pyroprocessing of used nuclear fuel. Given the pending availability of a multi-function furnace for distillation and consolidation operations in the Fuel Conditioning Facility, the furnace was considered for the processing of driver plenums. Although two options (oxidation and distillation) could be performed in the multi-function furnace, neither option has been developed sufficiently to date to warrant the use of the furnace for treatment operations. Thus, it was decided to defer the treatment of elemental sodium from driver plenums in the multi-function furnace until more developed technologies and/or furnaces become available. In the interim, storage of the plenums and characterization efforts are recommended.

Experimental setup for elemental analysis using prompt gamma rays at research reactor IBR-2

  • Hramco, C.;Turlybekuly, K.;Borzakov, S.B.;Gundorin, N.A.;Lychagin, E.V.;Nehaev, G.V.;Muzychka, A. Yu;Strelkov, A.V.;Teymurov, E.
    • Nuclear Engineering and Technology
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    • v.54 no.8
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    • pp.2999-3005
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    • 2022
  • The new experimental setup has been built at the 11b channel of the IBR-2 research reactor at FLNP, JINR, to study the elemental composition of samples by registration of prompt gamma emission during thermal neutron capture. The setup consists of a curved mirror neutron guide and a radiation-resistant HPGe high-purity germanium detector. The detector is surrounded by lead shielding to suppress the natural background gamma level. The sample is placed in a vacuum channel and surrounded by a LiF shield to suppress the gamma background generated by scattered neutrons. This work presents characteristics of the experimental setup. An example of hydrogen concentration determining in a diamond powder made by detonation synthesis is given and on its basis, the sensitivity of the setup is calculated being ~4 ㎍.

Activity of $V_2O_5-WO_3/TiO_2$-based SCR Catalyst for the Oxidation of Gas-phase Elemental Mercury ($V_2O_5-WO_3/TiO_2$ 계 SCR 촉매의 가스상 원소수은 산화 활성)

  • Hong, Hyun-Jo;Ham, Sung-Won
    • Clean Technology
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    • v.17 no.4
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    • pp.370-378
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    • 2011
  • Catalytic activity of $V_2O_5-WO_3/TiO_2$-based SCR catalyst was examined for the oxidation of gas-phase elemental mercury to oxidized mercury. Mercury species was not detected on the commercial SCR catalyst after the oxidation reaction of elemental mercury, regadless of the presence of HCl acting as oxidant and the reaction conditions. This suggests that elemental mercury oxidation by HCl could occur via a Eley-Rideal mechanism with gas phase or weakly-bound mercury on the surface of $V_2O_5-WO_3/TiO_2$ SCR catalyst. The activity for mercury oxidation was significantly increased with the increase of $V_2O_5$ loading, which indicates that $V_2O_5$ is the active site. However, turnover frequency for mercury oxidation was decreased with the increase of $V_2O_5$ loading, indicating the activity for mercury oxidation was strongly dependent on the surface structure of vanadia species. The activity for oxidation of elemental mercury under SCR condition was much less than that under oxidation condition at the same HCl concentration and reaction temperature.

Transformation Characteristics of Chlorinated Aliphatic Hydrocarbon (CAH) Mixtures by Natural Ores (자연광석을 이용한 염소계 지방족 탄화수소 혼합물 변환 특성)

  • Son, Bong-han;Kim, Nam-hee;Hong, Kwang-pyo;Yun, Jun-ki;Lee, Chae-young;Kim, Young;Kwon, Soo-youl
    • Journal of Korean Society on Water Environment
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    • v.23 no.5
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    • pp.712-722
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    • 2007
  • This study screened three natural ores (iron, mangenase, and zinc), two types of slags, and two elemental metals (elemental iron and zinc) to evaluate transformation characteristics of CAH mixtures [e.g. Carbontetrachloride (CT), 1,1,1-Trichloroethane (1,1,1-TCA), and Perchloroethene (PCE)]. To select an effective metal medium to treat the CAH mixtures, we measured transformation capacities (CAH mass ultimately transformed/mass of metal added) and the degree of dechlorination. We also considered economical efficiency of the metal media by comparing the value, CAH mass ultimately transformed divided by the price of metal medium added. A simplified mathematical model adapting CAH transformation capacity, first-order transformation kinetics, and available mass of metal transforming CAH was developed and used for estimating CAH transformation rate coefficient and longevity of the metal medium. CAH transformation capacity for elemental iron and elemental zinc were 4258~7129 and $4215{\sim}6330{\mu}g\;CAH\;transformed/g$ metal added, respectively, which are a factor of 80~200 higher than slags and natural ores. They also showed a factor of 1.1 to 2.2 greater degree of dechlorination than the others. Among natural ores and slags, Zinc ore showed the highest transformation capacity, $47{\sim}53{\mu}g\;CAH\;transformed/g$ metal added. Although zinc ore have smaller transformation capacity than elemental metals, economical efficiency of zinc ore is a factor of 10~20 greater than elemental metals tested. Consequently, zinc ore would be more economical medium than the others tested in this study. We estimated the pseudo first-order transformation rate of zinc ore was in the order of CT > 1,1,1-TCA > PCE.

Borehole Elemental Concentration Logs: Theory, Current Trends and Next Level (암석구성성분검층: 원리, 연구동향 및 향후 과제)

  • Shin, Jehyun;Hwang, Seho
    • Geophysics and Geophysical Exploration
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    • v.22 no.3
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    • pp.149-159
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    • 2019
  • Borehole elemental concentration logging, measuring neutron-induced gamma rays by inelastic scattering and neutron capture interactions between neutron and formation, delivers concentrations of the most common elements found in the minerals and fluids of subsurface formation. X-ray diffraction and X-ray fluorescence analysis from core samples are traditionally used to understand formation composition and mineralogy, but it represents only part of formations. Additionally, it is difficult to obtain elemental analysis over the whole intervals because of poor core recovery zones such as fractures or sand layers mainly responsible for groundwater flow. The development of borehole technique for in situ elemental analysis plays a key role in assessing subsurface environment. Although this technology has advanced consistently starting from conventional and unconventional resources evaluation, it has been considered as exclusive techniques of some major service company. As regards domestic research and development, it has still remained an unexplored field because of some barriers such as the deficiency of detailed information on tools and calibration facility for chemistry and mineralogy database. This article reviews the basic theory of spectroscopy measurements, system configuration, calibration facility, and current status. In addition, this article introduces the domestic researches and self-development status on borehole elemental concentration tools.

Elemental Composition of PM2.5 Particulate with a 3-Stage DRUM Sampler during Spring and Summer Seasons in Urban Area of Gwangju, Korea (3-Stage DRUM 샘플러를 이용한 광주 도심지역의 봄철과 여름철 PM2.5 원소적 조성 비교)

  • Ryu S.Y.;Kim Y.J.
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.6
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    • pp.699-708
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    • 2005
  • To characterize the elemental composition of fine particles in urban area, $PM_{2.5}$ was collected by a 3-stage DRUM impactor at Gwangju during spring and summer. Time and size resolved concentrations for 19 trace elements were obtained by synchrotron X-Ray fluorescence analysis. Trace elements in summer were distributed in smaller size range compared to those in spring. Almost trace element concentrations in fine particles were highly increased during the Asian dust. In spring, soil elements such as Si, K, Ca, Ti and Fe had low enrichment factors indicating the dominant influence of soil dust. However, all elements had high enrichment factors in summer implying that these elements could be emitted from the anthropogenic sources. Factor analysis was conducted with the elemental composition data in order to identify anthropogenic sources of aerosols in urban area during spring and summer. Fine particles in spring have several sources such as soil dust originating from China continental region, coal and oil combustion, biomass burning, sea salt, ferrous and nonferrous metal sources. On the other hand, fine particles in summer were influenced by road dust, gasoline vehicle as well as coal and oil combustion, sea salt, ferrous and nonferrous metal sources.