Journal of Korean Society for Atmospheric Environment (한국대기환경학회지)

Korean Society for Atmospheric Environment (한국대기환경학회)
권호 표지

Elemental Composition of PM2.5 Particulate with a 3-Stage DRUM Sampler during Spring and Summer Seasons in Urban Area of Gwangju, Korea

3-Stage DRUM 샘플러를 이용한 광주 도심지역의 봄철과 여름철 PM2.5 원소적 조성 비교

  • Ryu S.Y. (Department of Environmental science and engineering, Gwangju Institute of science and Technology, Advanced Environmental Monitiring Research Chnter) ;
  • Kim Y.J. (Department of Environmental science and engineering, Gwangju Institute of science and Technology, Advanced Environmental Monitiring Research Chnter)
  • 류성윤 (광주과학기술원 환경공학과, 환경모니터링신기술연구센터) ;
  • 김영준 (광주과학기술원 환경공학과, 환경모니터링신기술연구센터)
  • Published : 2005.12.01
Download PDF
⟨ Previous Next ⟩

Abstract

To characterize the elemental composition of fine particles in urban area, $PM_{2.5}$ was collected by a 3-stage DRUM impactor at Gwangju during spring and summer. Time and size resolved concentrations for 19 trace elements were obtained by synchrotron X-Ray fluorescence analysis. Trace elements in summer were distributed in smaller size range compared to those in spring. Almost trace element concentrations in fine particles were highly increased during the Asian dust. In spring, soil elements such as Si, K, Ca, Ti and Fe had low enrichment factors indicating the dominant influence of soil dust. However, all elements had high enrichment factors in summer implying that these elements could be emitted from the anthropogenic sources. Factor analysis was conducted with the elemental composition data in order to identify anthropogenic sources of aerosols in urban area during spring and summer. Fine particles in spring have several sources such as soil dust originating from China continental region, coal and oil combustion, biomass burning, sea salt, ferrous and nonferrous metal sources. On the other hand, fine particles in summer were influenced by road dust, gasoline vehicle as well as coal and oil combustion, sea salt, ferrous and nonferrous metal sources.

Keywords

References

  1. 김경준, 김영준 (2003) 에어로졸의 준실시간 관측에 의한 여름철 도시지역 시정 감쇄 현상의 광학적인 특성 분석, 한국대기환경학회지, 19(6), 647-661
  2. 김기현, 강창희, 이진홍, 최금찬, 윤용훈 (2004) 봄철 황사의 발생과 대기 중 중금속 성분의 농도 변화-납 성분을 이용한 사례 연구, 한국대기환경학회지, 20(6), 833-838
  3. 신은상, 최민규, 선우영, 정용삼 (2002) 서울지역 PM10 중 미량원소의 특성 평가, 한국대기환경학회지, 18(5), 363-372
  4. 신선아, 한진석, 홍유덕, 안준영, 문광주, 이석조, 김신도(2005) 2000-2002년 우리나라에서 관측된 황사의 화학조성 및 특성, 한국대기환경학회지, 21(1), 119-129
  5. 최규훈, 김기현, 강창희, 이진홍(2003) 황사와 비황사기간의 중금속 농도분포 특성: 2001년 황사기간에 대한 비교 연구, 한국대기환경학회지, 19(1), 45-56
  6. 한진석, 김영성, 문광주, 안준영, 김정은, 류성윤, 김영준, 공부주, 이석조 (2004a) 2001년 11월 오염시기와 2002년 봄 황사시기 제주도 고산에서의 미량원소 농도 변화, 한국대기환경학회지, 20(2), 143-151
  7. 한진석, 문광주, 공부주, 류성윤, 김영준 (2004b) 인자분석을 통한 대기 입자상 물질의 입경별 발생원 추정- Drum impactor를 이용한 2002년 5월 제주도 고산지역 측정을 중심으로, 한국대기환경학회지, 20(5), 685-695
  8. Alfaro, S.C., L. Gomes, J.L. Rajot, S. Lafon, A. Gaudichet, B. Chatenet, M. Maille, G. Cautenet, F. Lasserre, H. Cachier, and X.Y. Zhang (2003) Chemical and optical characterization of aerosols measured in spring 2002 at the ACE-Asia supersite, Zhen-beitai, China, J. Geophys. Res., 108, D23 8641, doi 10.1029/2002JD003214
  9. Allen, A.G., E. Nemitz, J.P. Shi, R.M. Harrison, and J.C. Greenwood (2001) Size distributions of trace metals in atmospheric aerosols in the United Kingdom, Atmospheric Environment, 35, 4581 -4591 https://doi.org/10.1016/S1352-2310(01)00190-X
  10. Bench, G., P.G. Grant, D. Ueda, S.S. Cliff, K.D. Perry, and T.A. Cahill (2002) The use of STIM and PESA to respectively measure profiles of aerosol mass and hydrogen content across Mylar rotating drum impactor samples, Aerosol Sci. Technol., 36, 642-651 https://doi.org/10.1080/02786820252883874
  11. Han, J.S., KJ. Moon, S.Y. Ryu, Y.J. Kim, and K.D. Perry (2005) Source estimation of anthropogenic aerosols collected by a DRUM sampler during spring of 2002 at Gosan, Korea, Atmospheric Environment, 39,3113-3125 https://doi.org/10.1016/j.atmosenv.2005.01.047
  12. Huebert, B.J., T. Bates, P.B. Russell, G. Shi, Y.J. Kim, K. Kawamura, G. Carmichael, and T. Nakajima (2003) An overview of ACE-Asia: Strategies for quantifying the relationships between Asian aerosols and their climatic impacts, J. Geophys. Res., 108, D23 8633, doi:10.1029/2003JD003550
  13. Kim, K.W., Z. He, and Y.J. Kim (2004) Physicochemical characteristics and radiative properties of Asian dust particles observed at Kwangju, Korea, during the 2001 ACE-Asia intensive observation period, J. Geophys. Res., 109, DS19S02, doi:10.1029/ 2003JD003693
  14. Malm, W.C., J.F. Sisler, D. Huffman, R.A. Eldred, and T.A. Cahill (1994) Spatial and seasonal trends in particle concentration and optical extinction in the United States, J. Geophys. Res., 99, 1347-1370 https://doi.org/10.1029/93JD02916
  15. NARSTO (2003) Particulate Matter Science for Policy Makers. A NARSTO Assessment, EPRI 1007735, http://www.cgenv.com/Narsto/ (accessed in May 2003)
  16. Perry, K.D., T.A. Cahill, R.A. Eldred, D.D. Dutcher, and T.E. Gill (1997) Long-range transport of North African dust to the eastern United States, J. Geophys. Res., 102, 11225-11238 https://doi.org/10.1029/97JD00260
  17. Perry, K.D., S.S. Cliff, and M.P. Jimenez-Cruz (2004) Evidence for hygroscopic mineral dust particles from the Intercontinental Transport and Chemical Transformation Experiment, J. Geophys. Res., 109, D23S28 doi: 10.1029/2004JD004979
  18. Reid, J.S., H.H. Jonsson, H.B. Maring, A. Smirnov, D.L. Savoie, S.S. Cliff, E.A. Reid, J.M. Livingston, M.M. Meier, O. Dubovik, and S.C. Tsay (2003) Comparison of size and morphological measurements of coarse mode dust particles from Africa, J. Geophys. Res., 108, D19 8593, doi:10.1029/ 2002JD002485
  19. Seinfeld, J.H. and S.N. Pandis(1998) Atmospheric Chemistry and Physics: From Air Pollution to Climate Change, Wiley-lnterscience, New York, NY
  20. Taylor, S.R. and S.M. McLennan (1995)The geochemical evolution of the continental crust, Reviews of Geophysics, 33, 241 -265 https://doi.org/10.1029/95RG00262