• Title/Summary/Keyword: electrostatic field

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Study on the Scan Field of Modified Octupole and Quadrupole Deflector in a Microcolumn (마이크로칼럼에서 변형된 4중극 디플렉터와 8중극 디플렉터의 스캔 영역 비교)

  • Kim, Young Chul;Kim, Ho-Seob;Ahn, Seong Joon;Oh, Tae-Sik;Kim, Dae-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.11
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    • pp.1-7
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    • 2018
  • In a microcolumn, a miniaturized electrostatic deflector is often adopted to scan an electron beam. Usually, a double octupole deflector is used because it can avoid excessive spherical aberrations by controlling the electron beam path close to the optical axis of the objective lens and has a wide scan field. Studies on microcolumns have been performed to improve the low throughput of an electron column through multiple column applications. On the other hand, as the number of microcolumns increases, the number of wires connected to the components of the microcolumn increases. This will result in practical problems during the process of connecting the wires to electronic controllers outside of the vacuum chamber. To reduce this problem, modified quadrupole and octupole deflectors were examined through simulation analysis by selecting an ultraminiaturized microcolumn with the Einzel lens eliminated. The modified deflectors were designed changing the size of each electrode of the conventional Si octupole deflector. The variations of the scan field and electric field strength were studied by changing the size of active electrodes to which the deflection voltage was to be applied. The scan field increased linearly with increasing deflection voltage. The scan field of the quadrupole deflector and the electric field strength at the center were calculated to be approximately 1.3 ~ 2.0 times larger than those of the octupole deflector depending on the electrode size.

Comparative Molecular Field Analyses on the Fungicidal Activities of N-phenylthionocarbamate Derivatives based on Different Alignment Approaches (상이한 정렬에 따른 N-phenylthionocarbamate 유도체들의 살균활성에 관한 비교 분자장 분석)

  • Sung, Nack-Do;Soung, Min-Gyu;You, Jae-Won;Jang, Seok-Chan
    • The Korean Journal of Pesticide Science
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    • v.10 no.3
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    • pp.157-164
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    • 2006
  • Three dimensional quantitative structure-activity relationships (3D-QSARs) for the fungicidal activities against Rhizoctonia solani (RS) and Phytophthora capsici (PC) by N-phenyl substituents(X) of N-phenylthionocarbamate derivatives were studied quantitatively using comparative molecular field analysis (CoMFA) methodology based on different alignment approaches. Statistical quality of CoMFA models with field fit alignment were slightly higher than that of atom based fit alignment. The optimized CoMFA models (RS: RF2 & PC: PF2) were derived from field fit alignment and combination of CoMFA fields. And the statistical results of the two models showed the best predictability of the fungicidal activities based on the cross-validated value $q^2$ ($r^2_{cv.}$ =RS: 0.557 & PC: 0.676) and non-cross-validated value ($r^2_{ncv.}$ =RS: 0.954 & PC: 0.968), respectively. The selective fungicidal activities between two fungi were dependence upon the electrostatic field of substrate molecule. Therefore, the fungicidal activities from CoMFA contour maps showed that the fungicidal activity will be able to increased according to the modification of X-substituents on the substrate molecules.

3D-QSAR Analysis on the Fungicidal Activity of N-phenyl-O-phenylthionocarbamate Analogues against Gray Mold (Botrytis cinerea) (잿빛곰팡이병균(Botrytis cinerea)에 대한 N-Phenyl-O-phenyl-thionocarbamate 유도체들의 살균활성에 관한 3D-QSAR 분석)

  • Sung, Nack-Do;Park, Kee-Han;Jang, Seok-Chan;Soung, Min-Kyu
    • The Korean Journal of Pesticide Science
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    • v.11 no.2
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    • pp.59-66
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    • 2007
  • Three dimensional quantitative structure-activity relationships (3D-QSARs) on the fungicidal activity of N-phenyl-O-phenylthionocarbamate analogues against resistant and sensitive gray mold (Botrytis cinerea) (RBC & SBC) were studied quantitatively using CoMFA and CoMSIA methods. The correlation coefficient and predict- ability of optimized CoMFA model with the atom based fit alignment were better ($r^2$ & $q^2=CoMFA{\gg}CoMSIA$) than that of CoMSIA model. And statistical values of the models on the fungicidal activity against SBC were showed higher ($r^2=SBC{\gg}RBC$) than that of RBC. In CoMFA models, steric field on the activity was more influenced than electrostatic field. And in case of CoMSIA models, the influence of CoMSIA field on the activity against RBC and SBC was differ from each other but the influence of H-bond donor field was same to the two fungi. It is revealed that the selectivity factor with CoMFA model on the fungicidal activity between the two fungi was caused on the difference of steric field. Therefore, it is predicted that the large steric field with meta- and para-substituents on the N-phenyl ring will be improved to the fungicidal activity with SBC.

Recent Developments in Agricultural Sprays : Review

  • No, S. Y.
    • Agricultural and Biosystems Engineering
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    • v.3 no.1
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    • pp.44-54
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    • 2002
  • A brief review of current status in the field of agricultural spray and future research challenges are presented. Researches on the pesticides sprays, pollen sprays, postharvest sprays, and biological control agent sprays among the various applications of agricultural spray were selected and reviewed. In the agrochemical sprays, the techniques to increase the deposition such as electrospray and reduce the drift such as introductions of drift retardants and of mechanical means are reviewed. The introduction of mechanical means includes low drift, air-assisted, air inclusion, shield or shroud assisted and pulse flow nozzles. For flat fan nozzles, the data of breakup length and thickness of liquid sheet are essential to understand the atomization processes and develop the transport model to target In the air-assisted spray technology to reduce drift, further works on the effect of application height on drift and air assistance on droplet size should be followed. In addition, methods for quantifying the included air in the air inclusion techniques are required. The atomization characteristics of biopesticides spray are not being elucidated and the formulations of biopesticides should be taken into account the spray characteristics of existing nozzle and sprayer. A few researches on the droplet size of fallout can be found in the literature. A combined technology with electrostatic method into one of method for the reduction of drift may be an effective strategy for increasing deposition and reducing drift. Only an integrated approach involving all stakeholders such as engineers, chemists, and biologists, etc. can result in improved application of agricultural spray.

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Characterization of Au-MWNT nanocomposite in thin films (다중벽 탄소나노튜브와 금나노입자를 사용한 나노박막의 특성연구)

  • Kim, Jung-Soo;Bae, Jong-Seong;Ko, Chang-Hyun;Oh, Won-Tea
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.49-49
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    • 2009
  • Nanocomposites of gold nanoparticles and multi-walled carbon nanotubes (MWNTs) were prepared by electrostatic interaction. Gold nanopartic1es were stabilized by polyvinylpyrrolidone (PVP), sodium dodecyl sulfate (SDS) and poly(sodium-4-styrenesulfonate) (PSS) in aqueous medium, and MWNTs were modified by poly(diallyldimethylammonium)chloride (PDDA) in water. The as-perpared Au-MWNT nanocomposites were structurally and electrically characterized by transmission electron microscopy (TEM), field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), UV/Vis spectroscopy, X-ray photoelectron spectroscopy (XPS) and cyclo voltammetry (CV). UV/Vis spectra of Au-MWNT nanocomposites showed the characteristic surface plasmon bands in the range of ~515nm, depending on the stabilizers. There is only slight change on the band shape with variation of stabilizing agents for gold nanoparticles. Through FE-SEM and TEM images, the distribution of gold, nanoparticles on the sidewalls of MWNTs was deliberately investigated on Au-MWNT nanocomposites treated with different stabilizers. XPS and CV showed redistribution of electron densities and changes in the binding energy states of nanopartic1es in nanocomposite respectively.

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A Study on the Mass Collection Efficiency in Collector Step of Electrostatic Precipitator by Physical Gas Characterization (전기집진장치에서 가스의 물리적인 특성에 따른 포집구역내의 입자포집율 연구)

  • Ha, Sang-An;Im, Gyeong-Taek;Sin, Nam-Cheol
    • Journal of Environmental Science International
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    • v.7 no.1
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    • pp.36-40
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    • 1998
  • This study was carried out to investigate the collection Efficiency of mass in collector step at the different of physical gas characterization. This work has focused on the dependence of the collection efficiency of mass in the collector zone of a two-stage set up field with gas temperature T and the dew point tmeperature. To identify the dependence of the mass collection efficiency on the Bounded plate of the collector zone MP.k by the spectre electric resistance of dust $p_e$. and the relative humidify ${\varphi}$, 20 at- tempts have been made with three different gas temperature ($50{\circ}C, 80{\circ}C, 110{\circ}C$) at different dew point. At the specific electric resistance of dust $p_e$=$10^6{\Omega}m$ which relative humidity corresponds to $\phi$ > 15%, a easy rise of the sounded plate secluded dust mass share was measured atwain. As the result of the higher cohesion imprisonment power due to the adsorbtion of particle, the rinse of the relative humidity developed on the particle surface. Therefore, the collection efficiency of mass was not predominant the high temperature T in the collector zone, neither was the pecific ellectric resistance of dust dependent.

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Development of Multi-Type Soft X-ray Ionizer using Radiation Dose Overlapped Effect (선량 중첩을 이용한 멀티형 연 X-선 정전기 제거장치의 개발)

  • Lee, Su Hwan;Lee, Dong Hoon
    • Journal of the Korean Society of Safety
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    • v.33 no.2
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    • pp.28-31
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    • 2018
  • In display and semi-conductor manufacturing process, there are numerous unstable factors such as particle concentration, minimal vibration, changes in magnetic field, or electrostatic that becomes an issue to be managed and controlled. In the recent, X-ray ionization is widely used that is neutralized by separating air or gas molecules in the area where the static must be resolved. The mono-type of X-ray ionizer was not capable to be used in $8^{th}$ generation panels manufacturing plant due to its insufficient ionizing coverage since the panel itself is approximately in $2m{\times}3m$. To resolve the current problem, the development of new type called, "Multi-type X-ray ionizer" has resulted in covering enough ionizing space in $8^{th}$ generation panels industry. Comparing mono and multi types with MCNPX code simulation, the multi one indicates more X-ray flux, efficiency, and ionization performance in comparison with either a mono-type or multi-type in array format. In addition, the ionizing efficiency of overlapping area with multi-type showed 30% higher effectiveness rate as to the ordinary mono-type.

Electrical and Thermo-mechanical Properties of DGEBA Cycloaliphatic Diamine Nano PA and SiO2 Composites

  • Trnka, Pavel;Mentlik, Vaclav;Harvanek, Lukas;Hornak, Jaroslav;Matejka, Libor
    • Journal of Electrical Engineering and Technology
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    • v.13 no.6
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    • pp.2425-2433
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    • 2018
  • This study investigates a new organic based material and its dielectric and mechanical properties. It is a comprehensive nanocomposite comprising a combination of various types of nanofillers with hydrophobic silica nanoparticles (AEROSIL R 974) as a matrix modifier and a polyamide nano nonwoven textile, Ultramid-Polyamide 6, pulped in the electrostatic field as a dielectric barrier. The polymer matrix is an epoxy network based on diglycidyl ether of bisphenol A (DGEBA) and cycloaliphatic diamine (Laromine C260). The designed nanocomposite material is an alternative to the conventional three-component composites containing fiberglass and mica with properties that exceed current electroinsulating systems (volume resistivity on the order of $10^{16}{\Omega}{\cdot}m$, dissipation factor tan ${\delta}=4.7{\cdot}10^{-3}$, dielectric strength 39 kV/mm).

3D-QSAR Analysis on the Antitrypanosomal Activity of Phenoxy, Phenylthio or Benzyloxy Group Substituted Quinolone Analogues (Phenoxy, Phenylthio 및 Benzyloxy-기가 치환된 Quinolone 유도체들의 항트리파노소마 활성에 대한 3D-QSAR 분석)

  • Myung, Pyung-Keun;Kang, Na-Na;Kim, Sang-Jin;Sung, Nack-Do
    • YAKHAK HOEJI
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    • v.54 no.4
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    • pp.288-294
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    • 2010
  • Three dimensional quantitative-structure relationships (3D-QSARs) models between structures of phenoxy, phenylthio or benzyloxy substituted quinolone analogues and their antitrypanosomal activity against Chagas disease (Trypanosoma cruzi) were derived and discussed quantitatively using comparative molecular field analysis (CoMFA) and comparative molecular similarity indices analysis (CoMSIA) methods. The optimized CoMFA 1 model ($q^2$=0.528 and $r^2$=0.964) showed the best statistical results. According to the optimized CoMFA 1 model, the antitrypanosomal activities were dependent on the steric (60.0%) and electrostatic (36.2%) factors of quinolone derivatives. From the contour maps, it is predicted that the activity will be increased when sterically favored groups were located in $R_4$ and $R_5$ position and sterically disfavored groups were located in $R_2$ position. Also, the positively charged groups on $R_2$ would be able to increase the antitrypanosomal activities.

Trends of microbial electrochemical technologies for nitrogen removal in wastewater treatment (하폐수처리에서 질소 제거를 위한 미생물 전기화학 기술의 동향)

  • Chai, Hyungwon;Choi, Yonghoon;Kim, Myeongwoon;Kim, Youngjin;Jung, Sokhee P.
    • Journal of Korean Society of Water and Wastewater
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    • v.34 no.5
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    • pp.345-356
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    • 2020
  • The removal of organic carbon and nutrients (i.e. N and P) from wastewater is essential for the protection of the water environment. Especially, nitrogen compounds cause eutrophication in the water environment, resulting in bad water quality. Conventional nitrogen removal systems require high aeration costs and additional organic carbon. Microbial electrochemical system (MES) is a sustainable environmental system that treats wastewater and produces energy or valuable chemicals by using microbial electrochemical reaction. Innovative and cost-effective nitrogen removal is feasible by using MESs and increasing attention has been given to the MES development. In this review, recent trends of MESs for nitrogen removal and their mechanism were conclusively reviewed and future research outlooks were also introduced.