• Membrane and Water Treatment
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• 제9권5호
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• pp.317-325
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• 2018

Polyvinyl chloride (PVC) ultrafiltration (UF) membrane was modified by silica sol in the coagulation bath during non-solvent induced phase separation (NIPS) process. The effects of silica sol concentrations on the morphology, surface property, mechanical strength and separation property of PVC UF membranes were systematically investigated. PVC membranes were characterized by Fourier transform infrared spectroscopy (FTIR), energy dispersive spectroscopy (EDS), scanning electron microscopy (SEM), contact angle goniometry and tensile strength measurement. The results showed that silica had been successfully assembled on the surface of PVC UF membrane. With the increase of silica sol concentration in the coagulation bath, the morphologies of PVC UF membranes changed from cavity structure to finger-like pore structure and asymmetric cross-section structure. The hydrophilicity and permeability of PVC UF membranes were further evaluated. When silica sol concentration was 20 wt.%, the modified PVC membrane exhibited the highest hydrophilicity with a static contact angle of $36.5^{\circ}$ and permeability of $91.8(L{\cdot}m^{-2}{\cdot}h^{-1})$. The structure of self-assemble silica had significant impact on the surface property, morphology, mechanical strength and resultant separation performance of the PVC membranes.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 하계학술대회 논문집
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• pp.153-153
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• 2009

We investigated the dependence of the memory margin of the Cap-less memory cell on the strain of top silicon channel layer and also compared kink effect of strained Cap-less memory cell with the conventional Cap-less memory cell. For comparison of the characteristic of the memory margin of Cap-less memory cell on the strain channel layer, Cap-less transistors were fabricated on fully depleted strained silicon-on-insulator of 0.73-% tensile strain and conventional silicon-on-insulator substrate. The thickness of channel layer was fabricated as 40 nm to obtain optimal memory margin. We obtained the enhancement of 2.12 times in the memory margin of Cap-less memory cell on strained-silicon-on-insulator substrate, compared with a conventional SOI substrate. In particular, much higher D1 current of Cap-less memory cell was observed, resulted from a higher drain conductance of 2.65 times at the kink region, induced by the 1.7 times higher electron mobility in the strain channel than the conventional Cap-less memory cell at the effective field of 0.3MV/cm. Enhancement of memory margin supports the strained Cap-less memory cell can be promising substrate structures to improve the characteristics of Cap-less memory cell.

• 한국지하수토양환경학회지:지하수토양환경
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• 제25권1호
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• pp.25-36
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• 2020

In a redox transition zone, geochemical reactions are facilitated by active bacteria that mediate reactions involving electrons, and arsenic (As) and iron (Fe) cycles are the major electron transfer reactions occurring at such a site. In this study, the effect of repetitive redox changes on soil bacterial community in As-contaminated soil was investigated. The results revealed that bacterial community changed actively in response to redox changes, and bacterial diversity gradually decreased as the cycle repeated. Proportion of strict aerobes and anaerobes decreased, while microaerophilic species such as Azospirillum oryzae group became the predominant species, accounting for 72.7% of the total counts after four weeks of incubation. Bacterial species capable of reducing Fe or As (e.g., Clostridium, Desulfitobacterium) belonging to diverse phylogenetic groups were detected. Indices representing richness (i.e., Chao 1) and phylogenetic diversity decreased from 1,868 and 1,926 to 848 and 1,121, respectively. Principle component analysis suggests that repetitive redox fluctuation, rather than oxic or anoxic status itself, is an important factor in determining the change of soil bacterial community, which in turn affects the cycling of As and Fe in redox transition zones.

• 폴리머
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• 제27권3호
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• pp.183-188
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• 2003

유전체 분광계를 사용하여 불소함유 에폭시 수지, 벤조트리플루오라이드의 다이글리시딜 에테르(FER)/다이아미노다이페닐메탄 (DDM)과 비스페놀 A의 다이글리시딜 에테르 (DGEBA)DDM 시스템의 유전상수를 측정하였으며, DMA와 TGA에 의한 열분석을 통하여 유리 전이 온도 및 열분해 개시온도, 최대 무게 감량시 온도, 그리고 분해 활성화 에너지 등 열안정성 인자를 고찰하였다. 경화된 시편의 기계적 물성은 파괴 인성, 굴곡강도 및 충격강도 실험을 통하여 알아보았으며, 주사전자 현미경을 사용하여 시편의 파단 특성을 조사하였다. 실험 결과, DGEBA/DDM 시스템에 비해 FER/DDM 시스템은 낮은 유전 상수를 나타내었으며, 경화된 시편의 기계적 물성은 높은 값을 나타내었다. 이는 trifluoromethyl (CF$_3$) 기의 도입으로 인하여 전기적 특성과 기계적 물성이 증가한 것으로 사료된다.

• 한국항공우주학회지
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• 제45권11호
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• pp.932-938
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• 2017

플라자마의 거동을 오일러리안 격자와 라그랑지안 입자를 혼합하여 해석하는 Particle-in-cell 기법을 적용하여 간략화된 홀추력기를 해석하였다. 본 연구는 중성입자, 이온입자 뿐만 아니라 전자도 라그랑지안 기법으로 개별추적 계산하기 때문에 message passing interface 기법을 이용해 대용량 계산이 가능한 병렬클러스터링을 적용하였다. 계산에 앞서 일정한 벡터의 자기장에서 전자군의 나선형 거동을 해석하였고, 절대해와 일치함을 확인하여 코드를 검증하였다. 실린더 내부에 반경방향으로 일정한 자기장과 축방향으로 일정한 전기장을 고정시켜 플라즈마의 거동을 PIC 모델을 이용하여 해석하였다. 반응 실린더 내부에 전자가 로렌츠 힘에 의해 이중나선을 그리며 구속되는 현상이 잘 포착되었고, 고속 회전하는 전자와 주입된 중성입자가 충돌하여 이온화 되었고, 대전된 입자가 축방향의 전기장에 의해 급 가속하는 현상 또한 잘 모사되어 플라즈마의 플룸 거동을 모사하였다.

• Journal of the korean society of oceanography
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• 제36권4호
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• pp.101-108
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• 2001

Polybrominated diphenylether (PBDEs) congeners, 2,4,4'-TrBDE, 2,2',4,4'-TeBDE, 2,2',4,4',5-PeBDE, 2,2',4,4',5,5'-HXBDE, and 2,2',4,4',5,6-HxBDE, were measured in sediments from 52 stations in the southeastern coastal areas of Korea. Sediment samples were analyzed using gas chromatography coupled to mass spectrometer detector (GC/MSD) with positive electron impact (PEI) mode. New analytical methodology for PBDEs by the isotope dilution method was established using a multi-layer silica gel column chromatography. Total PBDEs levels in sediments for Pohang coast ranged from 1,1 to 33.8 ng/g dry weight (mean 5.3 ng/g dry), from 1.6 to 36.4 ng/g dry weight (mean 5.7 ng/g dry) for Ulsan coast, from 0.8 to 20.3 ng/g dry weight (mean 4.9 ng/g dry) for Busan coast, and from 0.8 to 10.3 ng/g dry weight (mean 4.4 ng/g dry) for Jinhae Bay. PBDEs contamination in surface sediments from Korean southeastern coasts was relatively moderate in comparison to that of other marine environment in the world. The predominant PBDE congeners were 2,2',4,4'-TeBDE and 2,2',4,4',5-PeBDE.

• 열처리공학회지
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• 제23권1호
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• pp.23-28
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• 2010

The cylindrical magnetron sputtering has not been widely used, although this system is useful for only certain types of applications such as fiber coatings. This paper presents electrode configurations which improved the complicacy of the target assembly by using the positive voltage power supply. It is a modified type which has a target constructed with a large cylindrical part, a conical part and a small cylindrical part. When positive voltage was applied to an anode, a stable glow discharge was established and a high deposition rate was obtained. The substrate bias current was monitored to estimate the effect of ion bombardment. As a result, it was found that the substrate current was large. With cylindrical and conical cathode magnetron sputter deposition on the surface of the substrate to prevent re-sputtering, ion impact because it can increase the effectiveness with excellent ductility and adhesion of Ti film deposition can be obtained. We board at the front end of the ground resistance of $5\;k{\Omega}$ attached to the substrate potential can be controlled easily, and Ti film deposition with excellent adhesion can be obtained. Microstructure and morphology of Ti films deposited on pure Cu wires were investigated by scanning electron microscopy in relation to preparation conditions. High level ion bombardment was found to be effective in obtaining a good adhesion for Cu wire coatings.

• Environmental Engineering Research
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• 제21권4호
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• pp.341-349
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• 2016

To improve the utilization rate of construction waste as mine backfilling materials, this paper investigated the feasibility of using recycled powder as mine paste backfilling cementitious material, and studied the pozzolanic activity of recycled construction waste powder. In this study, alkali-calcium-sulfur served as the activation principle and an orthogonal test plan was performed to analyze the impact of the early strength agent, quick lime, and gypsum on the pozzolanic activity of the recycled powder. Our results indicated that in descending order, early strength agent > quick lime > gypsum affected the strength of the backfilling paste with recycled powder as a cementitious material during early phases. The strength during late phases was affected by, in descending order, quick lime > gypsum > early strength agent. Using setting time and early compressive strength as an analysis index as well as an extreme difference analysis, it was found that the optimal ratio of recycled powder cementitious material for mine paste backfilling was recycled powder:quick lime:gypsum:early strength agent at 78%:10%:8%:4%. X-ray diffraction analysis and scanning electron microscope were used to show that the hydration products of recycled powder cementitious material at the initial stages were mainly CH and ettringite. As hydration time increased, more and more recycled powder was activated. It mainly became calcium silicate hydrate, calcium aluminate hydrate, etc. In summary, recycled powder exhibited potential pozzolanic activities. When activated, it could replace cementitious materials to be used in mine backfill.

• Current Optics and Photonics
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• 제4권1호
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• pp.9-15
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• 2020

Fresnel zone plates have been widely used in many applications, such as x-ray telescopes, microfluorescence, and microimaging. To obtain an x-ray Fresnel zone plate, many fabrication methods, such as electron-beam etching, ion-beam etching and chemical etching, have been developed. Fresnel zone plates fabricated by these methods will inevitably lead to some nonideal factors, which have an impact on the focusing characteristics of the zone plate. In this paper, the influences of these nonideal factors on the focusing characteristics of the zone plate are studied systematically, by numerical simulations based on scalar diffraction theory. The influence of the thickness of a Fresnel zone plate on the absolute focusing efficiency is calculated for a given incident x-ray's wavelength. The diffraction efficiency and size of the focal spot are calculated for different incline angles of the groove. The simulations of zone plates without struts, with regular struts, and with random struts are carried out, to study the effects of struts on the focusing characteristics of a zone plate. When a Fresnel zone plate is used to focus an ultrashort x-ray pulse, the effect of zone-plate structure on the final pulse duration is also discussed.

• 한국식품영양과학회지
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• 제18권2호
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• pp.205-210
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• 1989

Capillary column GLC 및 GCMS를 병용하는 분석방법을 이용하여 식물유 트리글리세리드 분자종과 산화안정성과의 관계를 밝히기 위해서, 규산 컬럼으로 분획한 대두유 트리글리세리드를 모델 시료로 하여 $60^{\circ}C$, 암소에서 저장하면서 산화에 따른 트리글리세리드 각 분자종의 산화안정성을 조사하였다. 대두유 트리글리세리드의 주요 분자종은 LLL(19.6%), OLL(17.4%), PLL(14.2%), OLO(10.2%) 및 PLO(9.4%)이었으며, 트리글리세리드 분자종의 산화안정성은 전반적으로 구성불포차지방산의 이중결합수가 적을 수록 증가하는 경향을 보였다. 그런데 트리글리세리드를 구성하는 불포화지방산들의 이중결합수가 같을 경우는 불포화도가 낮은 지방산이 결합되어 있는 분자종의 산화안정성이 높았고, 또 결합되어 있는 불포화지방산의 이중결합수 및 불포화도가 똑같은 경우에는 공존하고 있는 포화지방산의 acyl의 사슬길이가 짧은 분자종의 산화안정성이 높은 것으로 밝혀져, 식물유 트리글리세리드 분자종의 산화안정성에는 구성불포화지방산의 이중결합수와 불포화도 및 공존하고 있는 포화지방산의 acyl기의 사슬길이가 중요한 영향을 미치는 인자임을 알 수 있었다.