• Title/Summary/Keyword: electrolysis

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Characteristics of Electrolytic Treatment for Chromium and Cyanide containing Wastewater (크롬과 시안이 공존하는 폐수의 전해처리 특성)

  • 정일현;윤용수
    • Journal of environmental and Sanitary engineering
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    • v.13 no.3
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    • pp.85-92
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    • 1998
  • In this study, the electrolytic treatment by one-stage electrolysis was investigated for electroplating wastewater containing $Cr^{6+}$ and $CN^{-}$. From the results, we concluded as follows : Optimum initial pH of wastewater was pH : 3. Amount of optimum addition of electroltyte(NaCl) was 0.1 wt%. Optimum potential for electrolysis was 5 volt. Concentration and removal efficiency for $Cr^{6+}$ and $CN^{-}$ were under 1 mg/L and above 99% at optimum conditions. And the feasibility of electrolytic treatment for electroplating wastewater containing $Cr^{6+}$ and $CN^{-}$ was certified.

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The Synthesis Method of Tin Dioxide Nanoparticles by Plasma-Assisted Electrolysis Process and Gas Sensing Property

  • Kim, Tae Hyung;Song, Yoseb;Lee, Chan-Gi;Choa, Yong-Ho
    • Journal of Powder Materials
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    • v.24 no.5
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    • pp.351-356
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    • 2017
  • Tin dioxide nanoparticles are prepared using a newly developed synthesis method of plasma-assisted electrolysis. A high voltage is applied to the tin metal plate to apply a high pressure and temperature to the synthesized oxide layer on the metal surface, producing nanoparticles in a low concentration of sulfuric acid. The particle size, morphology, and size distribution is controlled by the concentration of electrolytes and frequency of the power supply. The as-prepared powder of tin dioxide nanoparticles is used to fabricate a gas sensor to investigate the potential application. The particle-based gas sensor exhibits a short response and recovery time. There is sensitivity to the reduction gas for the gas flowing at rates of 50, 250, and 500 ppm of $H_2S$ gas.

Electrochemical Dechlorination of 1,2,4-Trichlorobenzene Using a Reticulated Vitreous Carbon Electrode

  • Paeng, Ki-Jung;Lim, Chae-Yun;Lee, Bo-Young;Myung, No-Seung;Rhee Paeng, In-Sook
    • Bulletin of the Korean Chemical Society
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    • v.24 no.9
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    • pp.1329-1332
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    • 2003
  • Stepwise dechlorination of 1,2,4-trichlorobenzene was observed at a glassy carbon electrode in dimethylformamide containing 0.1 M tetraethylammonium perchlorate. Especially, dechlorination to dichlorobenzene and further to monochlorobenzene or benzene was successfully demonstrated with a porous reticulated vitreous carbon electrode. Electrochemical dechlorination of polychlorobenzenes employing a flow cell with a reticulated vitreous carbon working electrode is also described. Preliminary experiments with a flow cell showed that dechlorination of trichlorobenzene to dichlorobenzene was partially completed while dechlorination to benzene or monochlorobenzene was not successful, suggesting that a flow rate and electrolysis time should be further optimized for the complete electrolysis.

Properties of Carbon for Application of New Light Source Technology

  • Lee Sang-Heon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.5
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    • pp.477-479
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    • 2006
  • Carbon films was grown on Si substrates using the method of electrolysis for methanol liquid. Deposition parameters for the growth of the carbon films were current density for the electrolysis, methanol liquid temperature and electrode spacing between anode and cathode. We examined electrical resistance and the surface morphology of carbon films formed under various conditions specified by deposition parameters. It was clarified that the high electrical resistance carbon films with smooth surface morphology are grown when a distance between the electrodes was relatively wider. We found that the electrical resistance in the films was independent of both current density and methanol liquid temperature for electrolysis. The temperature dependence of the electrical resistance in the low resistance carbon films was different from one obtained in graphite.

In Vitro Test of a Micro Syringe Fabricated for the Intravascular Injection (초소형 주사 시스템의 모의 혈관 내에서의 작동 시험)

  • Kim, Geun-Young;Sim, Woo-Young;Lee, Sang-Woo;Yang, Sang-Sik;Chang, Jun-Keun;Lee, Seung-Ki
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.50 no.6
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    • pp.307-313
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    • 2001
  • A micro syringe which can be attached to the end of a micro intravascular endoscope for drug injection is fabricated and its characteristic is tested. The syringe consists of a drug chamber and an actuator chamber which are separated by a silicone rubber membrane. The drug chamber is filled with liquid drug by the membrance actuation caused by the vaporization and condensation of the working liquid in the actuator chamber. The liquid drug is ejected by the electrolysis of the working liquid. The membrane deflection by each actuation method has been measured. The liquid ejection image has been captured during the electrolysis of the electrolyte. Also, the successful operation of the micro syringe under the normal blood pressure was verified.

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Eletrochemical Characteristics of Ozone Generator using Boron-doped Diamond Electrode (붕소가 도핑된 다이아몬드전극을 이용한 오존발생기의 전기화학적 특성)

  • ;;Yasuaki Einaga;Akira Fujishima
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.585-588
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    • 2001
  • Thin, Boron-doped conducting diamond films are expected to be excellent electrodes for industrial electrolysis. Boron-doped conducting diamond films were used as anode for generating ozone gas by electrolysis of acidic solution. In this work, we have studied ozone generating system using Boron-doped Diamond electrode. Electrochemical cell and ozone generating system were designed for decreasing the temperature of the system, which was elevated during the reaction. by circulation of electrolyte in the system. In order to determine the ozone generation properties of diamond electrode, experimental conditions, electrolyte concentration, temperature, flow rate and reaction time were varied diversely. As a result, we could confirm that ozone gas was generated successfully and the performance of diamond electrode was stable while PbO$_2$ electrode was disintegrated. Actually we are found that ozone amount increased by lowering the temperature of electrolyte.

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Fabrication Technology of DLC for New Light Source (광원 적용을 위한 DLC합성)

  • Lee, Sang-Heon;Park, Dae-Hee
    • Proceedings of the KIEE Conference
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    • 2006.07c
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    • pp.1663-1664
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    • 2006
  • Carbon films was grown on Si substrates using the method of electrolysis for methanol liquid. Deposition parameters for the growth of the carbon films were current density for the electrolysis, methanol liquid temperature and electrode spacing between anode and cathode. We examined electrical resistance and the surface morphology of carbon films formed under various conditions specified by deposition parameters. It was clarified that the high electrical resistance carbon films with smooth surface morphology are grown when a distance between the electrodes was relatively wider. We found that the electrical resistance in the films was independent of both current density and methanol liquid temperature for electrolysis. The temperature dependence of the electrical resistance in the low resistance carbon films was different from one obtained in graphite.

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NaOCl produced by electrolysis of seawater using BDD electrode (BDD전극을 이용한 해수에서의 NaOCl 생성)

  • Hong, Kyeong-Mi;Park, Soo-Gil;Okajima, Takeyoshi;Ohsaka, Takeo;Fujishima, Akira
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.373-374
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    • 2005
  • NaOCl (Sodium hydrochlorite) have similar smell of chloride and solution of straw color. And boiling point is $110^{\circ}C$, specific gravity is 1.0(50g/l)/1.1(100g/l), Value of pH is 12. NaOCl playa role as bleach, a oxidizer, a germicide, a decolorant, a deodorant, treatment of water supply and drainage, food addition agent because strong oxidation, bleaching, sterilization effect is had. When NaOCl is produced in electrolysis of seawater, this system is composed of injection system by directly electrolysis of salt water on the spot and sodium hydrochlorite generate a safe low concentration(0.4~0.8 %).

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Fabrication of Carbon Film for New Light Source (광원용 탄소박막의 합성)

  • Lee, Sang-Heon;Choi, Young-Sung;Park, Dae-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.553-554
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    • 2006
  • Carbon films was grown on Si substrates using the method of electrolysis for methanol liquid. Deposition parameters for the growth of the carbon films were current density for the electrolysis. methanol liquid temperature and electrode spacing between anode and cathode. We examined electrical resistance and the surface morphology of carbon films formed under various conditions specified by deposition parameters. It was clarified that the high electrical resistance carbon films with smooth surface morphology are grown when a distance between the electrodes was relatively wider. We found that the electrical resistance in the films was independent of both current density and methanol liquid temperature for electrolysis. The temperature dependence of the electrical resistance in the low resistance carbon films was different from one obtained in graphite.

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CHARACTERISTICS OF PLATED GOLD LAYER ON ANSI 304 STAINLESS STEEL ACCORDING TO THE VARIATION OF PRETREATMENTS AND ELECTROLYSIS CONDITIONS

  • Lee, Dong-hun;Lee, Jae-Bong
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.224-234
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    • 1999
  • An attempt was made to characterize the relationship between pretreatment processes, electrolysis conditions and behaviors of the plated gold layer. In order to investigate the effect of pretreatment processes on plating, rest potential measurements of various pretreated stainless steels and a.c.-impedance spectroscopy tests were carried out in the strike plating solution. Characteristics of plated gold layers and adhesions between plated gold layers and stainless steel substrates were examined by scratching tests and micro-Vickers hardness tests. The result shows that the strike plating enhanced the adhesion of interface, the cathodic electro-activation pretreatment process improving both corrosion resistance and adhesion strength. The preferred orientations of plated gold layers were examined by the X-ray diffraction technique. As the current density increases, [111] preferred orientation of plated gold layers was found to become well developed.

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