• 제목/요약/키워드: electrode impedance

검색결과 686건 처리시간 0.029초

A Review of Ac-impedance Models for the Analysis of the Oxygen Reduction Reaction on the Porous Cathode Electrode for Solid Oxide Fuel Cell

  • Kim, Ju-Sik;Pyun, Su-Il
    • 전기화학회지
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    • 제8권2호
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    • pp.106-114
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    • 2005
  • This article covers the theoretical ac-impedance models for the analysis of oxygen reduction on the porous cathode electrode f3r solid oxide fuel cell (SOFC). Firstly, ac-impedance models were explained on the basis of the mechanism of oxygen reduction, which were classified into the rate-determining steps; (i) adsorption of oxygen atom on the electrode surface, (ii) diffusion of adsorbed oxygen atom along the electrode surface towards the three-phase (electrode/electrolyte/gas) boundaries, (iii) surface diffusion of adsorbed oxygen atom m ixed with the adsorption reaction of oxygen atom on the electrode surface and (iv) diffusion of oxygen vacancy through the electrode coupled with the charge transfer reaction at the electrode/gas interface. In each section for ac-impedance model, the representative impedance plots and the interpretation of important parameters attributed to the oxygen reduction reaction were explained. Finally, we discussed in detail the applications of the proposed theoretical ac-impedance models to the real electrode of SOFC system.

임피던스 방법을 이용한 기공율 측정에 대한 연구 (Void Fraction Measurements Using the Impedance Method)

  • 김무환;양훈철;송철화;정문기
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2000년도 춘계학술대회논문집B
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    • pp.721-727
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    • 2000
  • Impedance method was carried out to design the electrode that can measure the void fraction of the bubbly flow in pool reservoir. To find out the optimum electrode shape, Styrofoam-tests were performed in a specially designed acrylic reservoir. Three kinds of electrodes were designed to compare the characteristics of water-air flow. The resistance was increased as the void fraction increased and the capacitance was decreased as the void fraction increased. The resistance is a main parameter to express the nature of the water-air flow in impedance method. Almost all the values of impedance were involved in resistance. The degree of deviation from the mean-resistance values showed reasonable results. Electrode type-I expressed excellent results among the three electrode shapes. The impedance values in void fraction 0-10% were similar to those of Maxwell's equation. But the impedance values in void fraction 10-20% were not similar to those of Maxwell' equation because of the edge effect near electrode.

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비침습적 복압 측정을 위한 생체 임피던스 전극의 최적 위치 선정 (Optimum electrode selection for measuring the abdominal pressure using bio-impedance method)

  • 안양수;김거식;송철규
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2007년도 심포지엄 논문집 정보 및 제어부문
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    • pp.46-48
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    • 2007
  • In this study, we determined the optimum electrode pair for measuring the abdominal pressure using bio-impedance method. Because impedance changes differ from a weight, a height, contractile force, volume of muscle and blood other or whatever of individuals, it was quantified using values of impedance change, correlation coefficient and SNR. Our results showed the optimum electrode pair (1, 9) which could detect impedance changes due to an increase of the intensity of the abdominal pressure. The correlation coefficient and quadratic function between the RMS values of EMG and the impedance changes were 0.87 and $y=0.0014x^2$+0.0620x+0.6958, respectively. It demonstrated that the abdominal pressure could be measured non-invasively and simply using bio-impedance method. We propose that this optimum electrode configuration would be useful for future studies involving the convenient measurement of abdominal pressure by ambulatory urodynamics monitoring study.

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탄소혼합물 접지전극의 접지임피던스의 특성 (Characteristics of Grounding Impedances of Carbon Compound Grounding Electrodes)

  • 이강수;이복희
    • 조명전기설비학회논문지
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    • 제25권5호
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    • pp.54-60
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    • 2011
  • This paper presents characteristics of frequency-dependent grounding impedance and transient grounding impedance for the carbon compound grounding electrode used in the installation of computerized electronic equipment and lightning protection system. The frequency-dependent grounding impedances were measured by applying sinusoidal currents in the frequency range from 100 [Hz] to 10[MHz], and the transient grounding impedances were examined by subjecting the impulse current with the front-time between 1~80[${\mu}s$]. As a result, the ground resistance of the carbon compound grounding electrode is less than that of another type grounding electrodes. The transient grounding impedance is relatively low and the conventional grounding impedance is rather lower than the ground resistance. The frequency-dependent grounding impedance of the carbon compound grounding electrode is capacitive and the grounding impedance is decreased with increasing the frequency of injected currents. Therefore in the case that the carbon compound grounding electrode is jointly used with large-scaled grounding electrodes, it is possible to reduce the high frequency grounding impedance of the integrated grounding electrode system.

전기화학적 임피던스 Fitting 개선을 위한 전극/전해질 계면의 전기회로 모델 연구 (A Study on the Electrical Circuit Model of the Electrode/Electrolyte Interface for Improving Electrochemical Impedance Fitting)

  • 장종현;박정호
    • 전기학회논문지
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    • 제56권6호
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    • pp.1087-1091
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    • 2007
  • Exact impedance modeling of the electrode/electrolyte interface is important in bio-signal sensing electrode development. Therefore, the investigation of the equivalent circuit models for the interface has been pursued for a long time by several researchers. Previous circuit models fit the experimental results in limited conditions such as frequency range, type of electrode, or electrolyte. This paper describes a new electrical circuit model and its capability of fitting the experimental results. The proposed model consists of three resistors and two constant phase elements. Electrochemical impedance spectroscopy was used to characterize the interface for Au, Pt, and stainless steel electrode in 0.9% NaCl solution. Both the proposed model and the previous model were applied to fit the measured impedance results for comparison. The proposed model fits the experimental data more accurately than other models especially at the low frequency range, and it enables us to predict the impedance at very low frequency range, including DC, using the proposed model.

생체임피던스에 의한 상지운동 감지를 위한 최적 전극 위치의 평가 및 검증 (Evaluation and Verification of Optimal Electrode Configurations for Detection of Arm Movement Using Bio-Impedance)

  • 안선희;김수찬;남기창;김덕원
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2002년도 합동 추계학술대회 논문집 정보 및 제어부문
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    • pp.399-402
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    • 2002
  • In this study, we constructed a four-channel impedance measurement system including a two-channel goniometer to analyze human arm movement. Impedances and joint angles were simultaneously measured for wrist and elbow movements. As the impedance changes resulting from wrist and elbow movements depended heavily on electrode placement, we determined the optimal electrode configurations for those movements by searching for high correlation coefficients, large impedance changes, and minimum interferences in ten subjects (age: 29+6). Our optimal electrode configurations showed very strong relationships between the wrist joint angle and forearm impedance (correlation coefficient = 0.95+0.04), and between the elbow joint angle and upper arm impedance (correlation coefficient = -0.98+0.02). Although the measured impedances changes of the wrist (1.1+1.5 ohm) and elbow (-5.0+2.9 ohm) varied among individuals, the reproducibilities of wrist and elbow impedance changes of five subjects were 5.8+1.8 % and 4.6+1.4 % for the optimal electrode pairs, respectively. We propose that this optimal electrode configuration would be useful for future studies involving the measurement of accurate arm movements by impedance method.

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임피던스 변환 회로를 이용한 건식능동뇌파전극 개발 (Development of an Active Dry EEG Electrode Using an Impedance-Converting Circuit)

  • 고덕원;이관택;김성민;이찬희;정영진;임창환;정기영
    • Annals of Clinical Neurophysiology
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    • 제13권2호
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    • pp.80-86
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    • 2011
  • Background: A dry-type electrode is an alternative to the conventional wet-type electrode, because it can be applied without any skin preparation, such as a conductive electrolyte. However, because a dry-type electrode without electrolyte has high electrode-to-skin impedance, an impedance-converting amplifier is typically used to minimize the distortion of the bioelectric signal. In this study, we developed an active dry electroencephalography (EEG) electrode using an impedance converter, and compared its performance with a conventional Ag/AgCl EEG electrode. Methods: We developed an active dry electrode with an impedance converter using a chopper-stabilized operational amplifier. Two electrodes, a conventional Ag/AgCl electrode and our active electrode, were used to acquire EEG signals simultaneously, and the performance was tested in terms of (1) the electrode impedance, (2) raw data quality, and (3) the robustness of any artifacts. Results: The contact impedance of the developed electrode was lower than that of the Ag/AgCl electrode ($0.3{\pm}0.1$ vs. $2.7{\pm}0.7\;k{\Omega}$, respectively). The EEG signal and power spectrum were similar for both electrodes. Additionally, our electrode had a lower 60-Hz component than the Ag/AgCl electrode (16.64 vs. 24.33 dB, respectively). The change in potential of the developed electrode with a physical stimulus was lower than for the Ag/AgCl electrode ($58.7{\pm}30.6$ vs. $81.0{\pm}19.1\;{\mu}V$, respectively), and the difference was close to statistical significance (P=0.07). Conclusions: Our electrode can be used to replace Ag/AgCl electrodes, when EEG recording is emergently required, such as in emergency rooms or in intensive care units.

구형파를 이용한 전극계면 분석용 고속 임피던스 분석기의 설계변수 확정을 위한 컴퓨터 시뮬레이션 (Computer simulation to determine system parameters of the square-wave adapted fast impedance analyzer for the electrode - electrolyte interface analysis)

  • 김기련;김광년;심윤보;전계록;정동근
    • 한국시뮬레이션학회논문지
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    • 제14권2호
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    • pp.45-55
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    • 2005
  • There are electric double layer capacitance, polarization resistance and solution resistance in the interface between electrode and solution. Electrode process could be evaluated by the electrical impedance analysis. The necessities of the electrochemical cell analysis with high speed impedance analyzer are followings: minimization of the effects of electric stimulation on electrochemical cell and the concentration of reactive materials, and optimization of impedance signal resolution. This paper represents the design criteria for the selection and stimulation to develop fast impedance analyzer prototype for a electrochemical cell. It was suggested that the design of 470k sample/s sampling rate, 13 bit ABC resolution, and 140ms recording time is required for high speed impedance analysis system in frequency range between dc and 10kHz.

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생체 임피던스 방법을 이용하여 복압을 측정하기 위한 최적 전극위치 선정 (Optimum Electrode Selection for Measuring Abdominal Pressure using Bio-Impedance Method)

  • 김거식;이상옥;서정환;김경섭;송철규
    • 전기학회논문지
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    • 제56권7호
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    • pp.1339-1342
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    • 2007
  • In this study, we determined the optimum electrode pair for measuring the abdominal pressure using bio-impedance method and compared with conventional methods. Because impedance changes differ from a weight, a height, contractile force, volume of muscle and blood other or whatever of individuals, it was quantified using values of impedance change, correlation coefficient and SNR. Our results showed the optimum electrode pair (1, 9) which could detect impedance changes due to an increase of the intensity of the abdominal pressure. The correlation coefficient and quadratic function between the RMS values of EMG and the impedance changes were 0.87 and $y=0.0014x^2+0.0620x+0.6958$, respectively. It demonstrated that the abdominal pressure could be measured noninvasively and simply using bio-impedance method. We propose that this optimum electrode configuration would be useful for future studies involving the convenient measurement of abdominal pressure by ambulatory urodynamics monitoring study.

경락 임피던스 측정 시스템 개발에 관한 연구 (Study on the Development of Meridian Impedance Measurement System)

  • 이우철;인창식;민경기
    • 전기학회논문지
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    • 제58권2호
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    • pp.422-429
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    • 2009
  • Meridian which used as the basic theory of acupuncture treatment, is an important functional connection system of acupuncture point in oriental medicine. Yangdorak and EAV have lack of precision because of using 2-electrode method, occurring high non-uniformed current density and electrode contact status on electrode placement spot. Therefore we implemented a meridian impedance measurement system for measuring meridian impedance using 4-electrode method. In order to confirm the precision of developed system, we made an constant current characteristic experiment using standard resistor. As a results of clinical study with 18 subjects, the meridian impedance showed that reproductivity and repeatability of HT7 acupuncture point are $0.515[k{\Omega}]{\pm}0.000$(mean${\pm}$standard deviation) and $0.515[k{\Omega}]{\pm}0.002$, respectively. And reproductivity and repeatability of PC7 are $0.521[k{\Omega}]{\pm}0.000$ and $0.521[{\Omega}]{\pm}0.001$ respectively. The proposed system was stable and reliable. Therefore this study proved AC impedance method to valid in measuring meridian impedance, and also verified precision and repeatability of the proposed meridian impedance measurement system. The proposed system will serve as more effective method of measuring meridian phenomena as a bioelectric signal in clinical practice.