• Corrosion Science and Technology
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• 제5권1호
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• pp.33-38
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• 2006

Current coating practice requires the thickness of anti-corrosion organic coatings to be over $250{\mu}m$ for immersion parts of ships and offshore structures and the corrosion resistance of these coatings has been evaluated by destructive and qualitative analysis. Recently, Electrochemical Impedance Spectroscopy(EIS) method has been employed, as an alternative, to evaluate corrosion resistance of organic coatings. This method is characterized as being nondestructive, reproducible, and quantitative in evaluating aging of organic coatings. In this study, EIS method was adopted to quantitatively and effectively select the coating systems having optimized protective performance. Evaluations of several epoxy and epoxy/polyurethane coating systems typically used for ships and offshore structures were carried out in wet($50^{\circ}C$, $90^{\circ}C$) and dry(room temp.) environments to accelerate the degradation of the organic coatings. These results were compared with the conventional scribed(scratched) test results. The plausible prediction model for determining the remaining life-time of coating systems was also proposed based on variations of impedance data, FT-IR and $T_g$ measurements results.

• 한국표면공학회지
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• 제57권2호
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• pp.57-70
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• 2024

Nickel-cobalt-manganese (NCM) lithium-ion batteries(LIBs) are increasingly prominent in the energy storage system due to their high energy density and cost-effectiveness. However, they face significant challenges, such as rapid capacity fading and structural instability during high-voltage operation cycles. Addressing these issues, numerous researchers have studied the enhancement of electrochemical performance through the coating of NCM cathode materials with substances like metal oxides, lithium composites, and polymers. Coating these cathode materials serves several critical functions: it acts as a protection barrier against electrolyte decomposition, mitigates the dissolution of transition metals, enhances the structural integrity of the electrode, and can even improve the ionic conductivity of the cathode. Ultimately, these improvements lead to better cycle stability, increased efficiency, and enhanced overall battery life, which are crucial for the advancement of NCM-based lithium-ion batteries in high-demand applications. So, this paper will review various cathode coating materials and examine the roles each plays in improving battery performance.

• Journal of Electrochemical Science and Technology
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• 제7권2호
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• pp.132-138
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• 2016

In this study, we report the fabrication of functional complex fibers, which have been studied widely globally for numerous applications. Here, we fabricated conductive complex fibers with antibacterial properties by coating metal ions on the surface of plastic (polypropylene) fibers using the electroless and electrochemical deposition. First, we polished the polypropylene melt-blown fiber surface and obtained an absorbing Pd seed layer on its surface. Subsequently, we substituted the Pd with Cu. Bis-3-sulfopropyl-disulfide disodium salt (SPS), polyethylene glycol (PEG), and ethylene thiourea (ETU) were used as the brightener, carrier, and leveler, respectively for the electroplating. We focused on most achieving the stable plating condition to remove dendrites, which are normally during electroplating metals so that smooth layer is formed on the fiber surface. The higher the amount of SPS, the higher was the extent of irregular plate-like growth. Many irregularities in the form of round spheres were observed with increase in the amount of PEG and ETU. Hence, when the additives were used separately, a uniform coating could not be obtained. A stable coating was obtained when the three additives were combined and a uniform 5-9 μm thick copper layer with a stable morphology could be obtained around the fiber. We believe that our results can be applied widely to obtain conductive fibers with antibacterial properties and are useful in aiding research on conductive lightweight composite fibers for application in information technology and robotics.

• Journal of Electrochemical Science and Technology
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• 제11권2호
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• pp.155-164
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• 2020

Here we report our preliminary results about nickel phosphide (Ni-P) electroless coating on the surface of cellulose paper (CP) and its feasibility as the anode for lithium (Li) batteries. In particular, CP can act as a flexible skeleton to maintain the mechanical structure, and the Ni-P film can play the roles of both the anode substrate and the active material in Li batteries. Ni-P films with different P contents were plated uniformly and compactly on the microfiber strands of CP. When they were tested as the anode for Li battery, their theoretical capacity per physical area was comparable to or higher than hypothetical pure graphite and P film electrodes having the same thickness. After the large irreversible capacity loss in the first charge/discharge process, the samples showed relatively reversible charge/discharge characteristics. All samples showed no separation of the plating layer and no detectable micro-cracks after cycling. When the charge cut-off voltage was adjusted, their capacity retention could be improved significantly. The electrochemical result was just about the same before and after mechanical bending with respect to the overall shape of voltage curve and capacity.

• Korean Chemical Engineering Research
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• 제55권4호
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• pp.483-489
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• 2017

The loss of the sulfur cathode material through dissolution of the polysulfide into electrolyte causes a significant capacity reduction of the lithium-sulfur cell during the charge-discharge reaction, thereby debilitating the electrochemical performance of the cell. We addressed this problem by using a chemical and physical approach called reduction of polysulfide dissolution through direct coating functional inorganic (graphene oxide) or organic layer (polyethylene oxide) on electrode, since the deposition of external functional layer can chemically interact with polysulfide and physically prevent the leakage of lithium polysulfide out of the electrode. Through this approach, we obtained a composite electrode for a lithium-sulfur battery (sulfur: 60%) coated with uniform and thin external functional layers where the thin external layer was coated on the electrode by solution coating and drying by a subsequent heat treatment at low temperature (${\sim}80^{\circ}C$). The external functional layer, such as inorganic or organic layer, not only alleviates the dissolution of the polysulfide electrolyte during the charging/discharging through physical layer formation, but also makes a chemical interaction between the polysulfide and the functional layer. As-formed lithium-sulfur battery exhibits stable cycling electrochemical performance during charging and discharging at a reversible capacity of 700~1187 mAh/g at 0.1 C (1 C = 1675 mA/g) for 30 cycles or more.

• Corrosion Science and Technology
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• 제15권6호
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• pp.314-319
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• 2016

Reduced activation ferritic-martensitic steels (RAFM) are envisaged in future fusion technology as structural material which will be in direct contact with a flowing liquid lead-lithium melt, serving as breeder material. Aluminium-based coatings had proven their ability to protect the structural material from corrosion attack in flowing Pb-15.7Li and to reduce tritium permeation into the coolant, significantly. Coming from scales produced by hot dipping aluminization (HDA), the development of electrochemical-based processes to produce well-defined aluminium-based coatings on RAFM steels gained increased attention in research during the last years. Two different electrochemical processes are described in this paper: The first one, referred to as ECA, is based on the electrodeposition of aluminium from volatile, metal-organic electrolytes. The other process called ECX is based on ionic liquids. All three processes exhibit specific characteristics, for example in the field of processability, control of coating thicknesses (low activation criteria) and heat treatment behavior. The aim of this article is to compare these different coating processes critically, whereby the focus is on the comparison of ECA and ECX processes. New results for ECX will be presented and occurring development needs for the future will be discussed.

• Bulletin of the Korean Chemical Society
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• 제34권8호
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• pp.2343-2347
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• 2013

In this work, manganese dioxide ($Mn_3O_4$)/carbon black (CB) composites (Mn-CBs) were prepared by an in situ coating method as electrical fillers and the effect of the Mn-CBs on the electrical performance of activated carbon (AC)-based electrodes was investigated. Structural features of Mn-CBs produced via in situ coating using a $KMnO_4$ solution were confirmed by XRD and TEM images. The electrical performances, including cv curves, charge-discharge behaviors, and specific capacitance of the ACs/Mn-CBs, were determined by cyclic voltammograms. It was found that the composites of $Mn_3O_4$ and CBs were successfully formed by in situ coating method. ACs/Mn-CBs showed higher electrical performance than that of AC electrodes fabricated with conventional CBs due to the pesudocapacitance reaction of manganese oxides in the aqueous electrolyte. Consequently, it is anticipated that the incorporation of $Mn_3O_4$ into CBs could facilitate the utilization of CBs as electrical filler, leading to enhanced electrochemical performance of AC electrodes for supercapacitors.

• Corrosion Science and Technology
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• 제22권2호
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• pp.108-114
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• 2023

In this study, anti-corrosion effect was investigated through various electrochemical experiments after applying Al thermal spraying technology to AA5083-H321. Open circuit potential and anodic polarization curves were analyzed through electrochemical experiments in natural seawater. The shape of the surface was observed using a scanning electron microscope (SEM) and a 3D microscope before and after the experiment. Component and crystal structure were analyzed through EDS and XRD. As a result, the surface roughness of AA5083-H321 and the Al thermal sprayed coating layer increased due to surface damage caused by anodic dissolution reaction during the anodic polarization experiment. The corrosion rate of AA5083-H321 was relatively low because the Al thermal spray coating layer contained structural defects such as pores and crevices. Nevertheless, the open circuit potential of the Al thermal spray coating layer in natural seawater was measured about 0.2 V lower than that of AA5083-H321. Thus, a sacrificial anode protection effect can be expected.

• 한국결정성장학회지
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• 제10권1호
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• pp.55-61
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• 2000

리튬이온전지의 음극재료로서 hard carbon에 PVC를 이용한 탄소를 코팅함으로써 비가역용량 감소와 가역용량 증가 등 전기화학적 특성이 향상되었다. 이러한 특성 향상은 PVC코팅에 의한 표면개질로 대기와의 반응을 억제함에 기인한 것으로 생각되며, 또한 Ni 첨가에 의해 PVC 탄소의 흑연화 정도를 조절할 수 있었으며, 이들과 관련된 전기화학적 특성을 비교 고찰하였다.

• Journal of Electrochemical Science and Technology
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• 제10권2호
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• pp.196-205
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• 2019

Ni-rich layered oxides $Li(Ni_xCo_yMn_z)O_2$ (x + y + z = 1) have been extensively studied in recent times owing to their high capacity and low cost and can possibly replace $LiCoO_2$ in the near future. However, these layered oxides suffer from problems related to the capacity fading, thermal stability, and safety at high voltages. In this study, we use surface coating as a strategy to improve the thermal stability at higher voltages. The uniform and conformal $Al_2O_3$ coating on prefabricated electrodes using atomic layer deposition significantly prevented surface degradation over prolonged cycling. Initial capacity of 190, 199, 188 and $166mAh\;g^{-1}$ is obtained for pristine, 2, 5 and 10 cycles of ALD coated samples at 0.2C and maintains 145, 158, 151 and $130mAh\;g^{-1}$ for high current rate of 2C in room temperature. The two-cycle $Al_2O_3$ modified cathode retained 75% of its capacity after 500 cycles at 5C with 0.05% capacity decay per cycle, compared with 46.5% retention for a pristine electrode, at an elevated temperature. Despite the insulating nature of the $Al_2O_3$ coating, a thin layer is sufficient to improve the capacity retention at a high temperature. The $Al_2O_3$ coating can prevent the detrimental surface reactions at a high temperature. Thus, the morphology of the active material is well-maintained even after extensive cycling, whereas the bare electrode undergoes severe degradation.