• 한국전기전자재료학회논문지
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• 제35권4호
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• pp.342-347
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• 2022

In-situ analyzation and detection of real-time chemical reactions can be a significant part in interpreting the underlying mechanism in very reactive chemical reactions. To do this, first we have designed a microfluidic device (MFD) pattern for observation of synthesis of hierarchical nanostructures based on graphene oxide (GO), conjugating the well-known coupling reaction by which the solution of 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide (EDC)-mediated coupling is enhanced in the presence of n-hydroxysuccinimide (NHS) to make amide bonding, hereafter called as the EDC coupling. Then, we have manufactured microfluidic devices with multiple tens of micrometer-sized channels that can circulate those nanomaterials to be chemically reacted in the channels. These microfluidic devices were made by negative photo lithography and soft lithography. We showed the possibility of using Raman spectroscopy to reveal the basic mechanism of the energy storage applications.

• 한국재료학회지
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• 제32권11호
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• pp.474-480
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• 2022

Lithium-ion batteries (LIBs) are powerful energy storage devices with several advantages, including high energy density, large voltage window, high cycling stability, and eco-friendliness. However, demand for ultrafast charge/discharge performance is increasing, and many improvements are needed in the electrode which contains the carbon-based active material. Among LIB electrode components, the conductive additive plays an important role, connecting the active materials and enhancing charge transfer within the electrode. This impacts electrical and ionic conductivity, electrical resistance, and the density of the electrode. Therefore, to increase ultrafast cycling performance by enhancing the electrical conductivity and density of the electrode, we complexed Ketjen black and graphene and applied conductive agents. This electrode, with the composite conductive additives, exhibited high electrical conductivity (12.11 S/cm), excellent high-rate performance (28.6 mAh/g at current density of 3,000 mA/g), and great long-term cycling stability at high current density (88.7 % after 500 cycles at current density of 3,000 mA/g). This excellent high-rate performance with cycling stability is attributed to the increased electrical conductivity, due to the increased amount of graphene, which has high intrinsic electrical conductivity, and the high density of the electrode.

• Journal of Industrial and Engineering Chemistry
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• 제67권
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• pp.12-27
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• 2018

Supercapacitors (SCs) has gained an impressive concentration by the researchers due to its advantages such as high energy and power densities, long cyclic life, rapid charge-discharge rates, low maintenance and desirable safety. Hence it has been widely utilized in energy storage and conversion devices. Among the different components of SC, electrodes play a vital role in the performances of SCs. In this review, we present the recent advances in 2-D nanostructured metal nitrides, carbides, and phosphides based materials for SC electrodes. Finally, the electrochemical stability and designing approach for the future advancement of the electrode materials are also highlighted.

• 반도체디스플레이기술학회지
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• 제4권2호
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• pp.15-19
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• 2005

The organic light-emitting devices(OLEDs) based on fluorescence have low efficiency due to the requirement of spin-symmetry conservation. By using the phosphorescent material, the internal quantum efficiency can reach 100$\%$, compared to 25$\%$ in case of the fluorescent material [1]. Thus recently phosphorescent OLEDs have been extensively studied and showed higher internal quantum efficiency than conventional OLEDs. In this study, we have applied a new Ir complex as a red dopant and fabricated a red phosphorescent OLED on a flexible PC(Polycarbonate) substrate. Also, we have investigated the electrical and optical properties of the devices with a structure of A1/LiF/Alq3/(RD05 doped)BAlq/NPB/2-TNAIA/ITO/PC substrate. Our device showed the lightening efficiency of > 30 cd/A at an initial brightness of 1000 cd/$m^{2}$. The CIE(Commission Internationale de L'Eclairage) coordinates for the device were (0.62,0.37) at a current density of 1 mA/$cm^{2}$. In addition, although the sheet resistance of ITO films on PC substrate is higher than that on glass substrate, the flexible OLED showed much better lightening efficiency without much increase in operating voltage.

• 한국재료학회지
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• 제30권9호
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• pp.480-488
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• 2020

The electrocaloric effect can be observed in pyroelectric materials based on conversion between electrical and thermal energy, and can be utilized for the future environment-friendly refrigeration technology. Especially, a strong electrocaloric effect is expected in materials in which field-induced phase transition can be achieved. Emerging fluorite-structure ferroelectrics such as doped hafnia and zirconia, first discovered in 2011, are considered the most promising materials for next-generation semiconductor devices. Besides application of fluorite-structure ferroelectrics for semiconductor devices based on their scalability and CMOS-compatibility, field-induced phase transition has been suggested as another interesting phenomenon for various energy-related applications such as solid-state cooling with electrocaloric effect as well as energy conversion/storage and IR/piezoelectric sensors. Especially, their giant electrocaloric effect is considered promising for solid-state-cooling. However, the electrocaloric effect of fluorite-structure oxides based on field-induced phase transition has not been reviewed to date. In this review, therefore, the electrocaloric effect accompanied by field-induced phase transition in fluorite-structure ferroelectrics is comprehensively reviewed from fundamentals to potential applications.

• 전기학회논문지
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• 제63권1호
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• pp.184-190
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• 2014

Fuel cell power system, unlike conventional energy sources, converts chemical energy into electrical energy through electrochemical reaction of hydrogen and oxygen. In recent years, railway field as well as mobile fuel cell power system is being studying actively with development of hydrogen storage technologies. This paper presents the feasibility study on small-scale prototype electric railway vehicle application using fuel cell generation system. it is confirmed that proposed fuelcell-battery hybrid system shows good response characteristic about speed and torque based on design of parameter on system. Also as results of response for proposed system modeling, it show that powering mode and braking mode of system is controlled by switching devices of converters.

• ETRI Journal
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• 제34권4호
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• pp.553-563
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• 2012

Serial peripheral interface (SPI) has been identified as a bottleneck in many wireless sensing systems today. SPI is used almost universally as the physical connection between the microcontroller unit (MCU) and radios, storage devices, and many types of sensors. Virtually all wireless sensor nodes today perform up to twice as many bus transactions as necessary to transfer a given piece of data, as an MCU must serve as the bus master in all transactions. To eliminate this bottleneck, we propose the master-handoff protocol. After the MCU initiates reading from the source slave device and writing to the sink slave device, the MCU as a master becomes a slave, and either the source or the sink slave becomes the temporary master. Experiment results show that this master-handoff technique not only cuts the data transfer time in half, but, more importantly, also enables a superlinear energy reduction.

• 전력전자학회논문지
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• 제23권3호
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• pp.161-167
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• 2018

In battery-operated systems, an isolated converter is used to interface the utility grid with the system to increase stability when charging and discharging batteries. Systems such as vehicle-to-grids (V2Gs), on-board chargers, and energy storage systems (ESSs) have recently become popular, and the roles of isolated converters have become important considerations in fabricating such devices. A fixed-frequency LLC converter, which is a type of isolated converter, presents the advantages of high efficiency and high power density by performing zero-voltage switching (ZVS) over wide frequency ranges. However, the magnetizing inductance of the LLC converter should be designed to enable ZVS in all switching devices. Therefore, in this study, the operating characteristics of the LLC circuit are analyzed, and an optimal design method for ZVS operation is established. Moreover, an 8 kW LLC high-efficiency and high-power-density resonant converter is designed and tested for ESS application. The LLC converter achieves 98% efficiency at rated power.

• Journal of Magnetics
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• 제19권3호
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• pp.266-272
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• 2014

In this paper, we suggest reliability as a metric to evaluate the robustness of a design for the optimal design of electromagnetic devices, with respect to constraints under the uncertainties in design variables. For fast numerical efficiency, we applied the sensitivity-assisted Monte Carlo simulation (S-MCS) method to perform reliability calculation. Furthermore, we incorporated the S-MCS with single-objective and multi-objective particle swarm optimization algorithms to achieve reliability-based optimal designs, undertaking probabilistic constraint and multi-objective optimization approaches, respectively. We validated the performance of the developed optimization algorithms through application to the optimal design of a superconducting magnetic energy storage system.

• 조명전기설비학회논문지
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• 제23권11호
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• pp.61-68
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• 2009

A Microgrid is a private small-scale power system composed of distributed energy resources (DERs), storage devices and loads. And it is expected that the Microgrid will come into wide use in the near future. For this, the establishment of the Microgrid operation methodology is a very important problem. Especially, the Microgrid is greatly different from existing private small-scale power systems because of the multiple participants. Therefore, the Microgrid operation considered various requirements according to multiple participants is more complicated than the operation of existing private small-scale power systems. In this paper, Microgrid operation methodology based on a market environment is suggested. Through case studies, the effectiveness of the suggested methodology is verified.