• Korea-Australia Rheology Journal
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• v.15 no.4
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• pp.179-185
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• 2003

Associating polymers act as flocculants in colloidal suspensions, because the hydrophobic groups (hydrophobes) can adsorb onto particle surfaces and create intermolecular cross-linking. The steady-shear viscosity and dynamic viscoelasticity were measured for suspensions flocculated by multichain bridging of associating polymers. The effects of surfactant on the suspension rheology are studied in relation to the bridging conformation. The surfactant molecule behaves as a displacer and the polymer chains are forced to desorb from the particle surfaces. The overall effect of surfactant is the reduction of suspension viscosity. However, the additions of a small amount of surfactant to suspensions, in which the degree of bridging is low, cause a viscosity increase, although the number of chains forming one bridge is decreased by the forced desorption of associating polymer. Since the polymer chains desorbed from one bridge can form another bridge between bare particles, the bridging density over the system is increased. Therefore, the surfactant adsorption leads to a viscosity increase. The surfactant influences the viscosity in two opposing ways depending on the degree of bridging.

• International Journal of Aeronautical and Space Sciences
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• v.15 no.2
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• pp.113-122
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• 2014

The objective of the paper is to clarify a methodology based on the use of the existing component mode synthesis methods for the case of two damped substructures which are coupled through a linking viscoelastic flexible substructure and for which the structural modes with free geometrical interface are used for each main substructure. The proposed methodology corresponds to a convenient alternative to the direct use either of the Craig-Bampton method applied to the three substructures (using the fixed geometric interface modes) or of the flexibility residual approaches initiated by MacNeal (using the free geometric interface modes). In opposite to a geometrical interface which is a topological interface on which there is a direct linkage between the degrees of freedom of substructures, we consider a physical flexible interface which exists in certain present technologies and for which the general framework linear viscoelasticity is used and yields a frequency-dependent damping and stiffness matrices of the physical flexible interface.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.25 no.4
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• pp.619-628
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• 2001

A viscoelastic constitutive equation of rubber is proposed under small oscillatory load superimposed on large static deformation. The proposed model is derived through linearization of Simos nonlinear viscoelastic constitutive model and reference configuration transformation. Statically pre-deformed state is used as reference configuration. The model is extended to a generalized viscoelastic constitutive equation including widely-used Mormans model. Static deformation correction factor is introduced to consider the influence of pre-strain on the relaxation function. The model is tested for dynamic behavior of rubbers with different carbon black fractions. It is shown that the constitutive equation with static deformation correction factor agrees well with test results.

• Proceedings of the KSME Conference
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• 2000.04a
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• pp.280-285
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• 2000

A viscoelastic constitutive equation of rubber that is under small oscillatory load superimposed on large static deformation is proposed. The proposed model is derived through linearization of Simo's viscoelastic constitutive model and reference configuration transformation. The proposed constitutive equation is extended to a generalized viscoelastic constitutive equation that includes widely used Mormin's model as a special case using objective stress increment. Static deformation correction factor is introduced to consider the influence of Pre-strain on the relaxation function. The proposed constitutive model is tested fer dynamic behavior of rubber specimens with different carbon black contents. It is concluded from the test that the viscoelastic constitutive equation for filled rubber must include the influence of the static deformation on the time effects. The suggested constitutive equation with static deformation correction factor shows good agreement with test values.

• Smart Structures and Systems
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• v.19 no.5
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• pp.539-551
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• 2017

A mathematical model of electro-thermoelasticity has been constructed in the context of a new consideration of heat conduction with memory-dependent derivative. The governing coupled equations with time-delay and kernel function, which can be chosen freely according to the necessity of applications, are applied to several concrete problems. The exact solutions for all fields are obtained in the Laplace transform domain for each problem. According to the numerical results and its graphs, conclusion about the proposed model has been constructed. The predictions of the theory are discussed and compared with dynamic classical coupled theory. The result provides a motivation to investigate conducting thermoelectric viscoelastic materials as a new class of applicable materials.

• Macromolecular Research
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• v.15 no.2
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• pp.109-113
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• 2007

The surface molecular motion of monodisperse polystyrene (PS) films was examined using scanning vis-coelasticity microscopy (SVM) in conjunction with lateral force microscopy (LFM). The dynamic storage modulus, E', and loss tangent, $tan\delta$, at a PS film surface with number-average molecular weights, $M_n$, smaller than 30 k were found to be smaller and larger than those for the bulk sample, even at room temperature, meaning that the PS surface is in a glass-rubber transition or fully rubbery sate at this temperature when the $M_n$ is small. In order to quantitatively elucidate the dynamics of the molecular motion at the PS surface, SVM and LFM measurements were performed at various temperatures. The glass transition temperature, $T_g$, at the surface was found to be markedly lower than the bulk $T_g$, and this discrepancy between the surface and bulk became larger with decreasing $M_n$. Such an intensive activation of the thermal molecular motion at the PS surfaces can be explained in terms of an excess free volume in the vicinity of the film surface induced by the preferential segregation of the chain end groups.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2003.05a
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• pp.495-500
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• 2003

The vibration of a flexible cantilever tube with nonlinear constraints when it is subjected to flow internally with fluids is examined by experiment and theoretical analysis. These kind of studies have often been performed that finds the existence of chaotic motion. In this paper, the important parameters of the system leading to such a chaotic motion such as Young's modulus and coefficient of viscoelasticity in tube material are discussed. The parameters are investigated by means of a system identification so that comparisons are made between numerical analysis using the parameters of a handbook and the experimental results. The chaotic region led by several period-doubling bifurcations beyond the Hopf bifurcation is also re-established with phase portraits and bifurcation diagram so that one can define optimal parameters for system design.

• Computers and Concrete
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• v.27 no.4
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• pp.369-383
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• 2021

This article deals with the frequency analysis of viscoelastic sandwich disk with graphene nano-platelets (GPLs) reinforced viscoelastic concrete (GPLRVC) face sheets and honeycomb core. The honeycomb core is made of aluminum due to its low weight and high stiffness. The rule of the mixture and modified Halpin-Tsai model are engaged to provide the effective material constant of the concrete. By employing Hamilton's principle, the governing equations of the structure are derived and solved with the aid of the Generalize Differential Quadrature Method (GDQM). In this paper, viscoelastic properties are modeled according to Kelvin-Voigt viscoelasticity. The deflection as the function of time can be solved by the fourth-order Runge-Kutta numerical method. Afterward, a parametric study is carried out to investigate the effects of the outer to inner radius ratio, hexagonal core angle, thickness to length ratio of the concrete, the weight fraction of GPLs into concrete, and the thickness of honeycomb core to inner radius ratio on the frequency of the viscoelastic sandwich disk with honeycomb core and FG-GPLRVC face sheet.

• Restorative Dentistry and Endodontics
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• v.29 no.6
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• pp.489-497
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• 2004

Objective: The purpose of this study was to investigate the viscoelastic properties related to handling characteristics of composite resins, Methods: A custom designed vertical oscillation rheometer (VOR) was used for rheological measurements of composites. The VOR consists of three parts: (1) a measuring unit, (2) a deformation induction unit and (3) a force detecting unit, Two medium viscous composites, Z100 and Z250 and two packable composites, P60 and SureFil were tested. The viscoelastic material function, including complex modulus $E^{*}$ and phase angle ${\delta}$, were measured. A dynamic oscillatory test was used to evaluate the storage modulus (E'), loss modulus (E") and loss tangent ($tan{\delta}$) of the composites as a function of frequency ($\omega$) from 0.1 to 20 Hz at $23^{\circ}C$. Results: The E' and E" increased with increasing frequency and showed differences in magnitude between brands. The $E^{*}s$ of composites at ${\omega}{\;}={\;}2{\;}Hz$, normalized to that of Z100, were 2.16 (Z250), 4,80 (P60) and 25.21 (SureFil). The magnitudes and patterns of the change of $tan{\delta}$ of composites with increasing frequency were significantly different between brands. The relationships between the complex modulus $E^{*}$, the phase angle ${\delta}$ and the frequency \omega were represented by frequency domain phasor form, $E^{*}{\;}(\omega){\;}={\;}E^{*}e^{i{\delta}}{\;}={\;}E^{*}{\angle}{\delta}$. Conclusions: The viscoelasticity of composites that influences handling characteristics is significant different between brands, The VOR is a relatively simple device for dynamic, mechanical analysis of high viscous dental composites. The locus of frequency domain phasor plots in a complex plane is a valuable method of representing the viscoelastic properties of composites.

• Transactions of the Korean Society of Automotive Engineers
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• v.18 no.2
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• pp.83-90
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• 2010

The windshield wiper consists of 4 parts: a blade, an arm, a linkage and a motor. The wiper blade makes contact with the windshield and is designed to be operated normally at an angle of 30~50 degrees to the front glass. If the contact pressure between the wiper blade and windshield surface is too high, noise and wear of the rubber will result. On the other hand, if the contact pressure is too low, the performance will do badly, since foreign substances such as dust and stains will not be removed well. The pressure and friction of the wiper blade has a great influence on its effectiveness in cleaning the front window. This is due to the contact of the rubber with the window. This paper presents the dynamic analysis method to estimate the performance of the flat type blade of the wiper system. The blade has a nonlinear characteristic since the rubber is an incompressible hyper-elastic and visco-elastic material. Thus, Structural dynamic analysis using a complex contact model for the blade is performed to find the characteristics of the blade. The flexible multi-body dynamic model is verified by the comparison between test and analysis result. Also, the optimization using the central composite design table is performed.