• Journal of Korean Society on Water Environment
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• v.32 no.3
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• pp.243-252
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• 2016

In cases of water pollution accidents, accurate prediction for arrival time and concentration of contaminants in a river is essential to take proper measures and minimize their impact on downstream water intake facilities. It is critical to fully understand the behavior characteristics of contaminants on river surface, especially in case of oil spill accidents. Therefore, in this study, the effects of main parameters of advection and diffusion of contaminants were analyzed and validated by comparing the results of Lagrangian particle tracking (LPT) simulation of Environmental Fluid Dynamic Code (EFDC) model with those of Global Position System (GPS)-equipped drifter experiment. Prevention scenario modeling was accomplished by taking cases of movable weir operation into account. The simulated water level and flow velocity fluctuations agreed well with observations. There was no significant difference in the speed of surface particle movement between 5 and 10 layer modeling. Therefore, 5 layer modeling could be chosen to reduce computational time. It was found that full three dimensional modeling simulated wind effects on surface particle movements more sensitively than depth-averaged two dimensional modeling. The diffusion range of particles was linearly proportional to horizontal diffusivity by sensitivity analysis. Horizontal diffusivity estimated from the results of GPS-equipped drifter experiment was 0.096 m²/sec, which was considered to be valid for applying the LPT module in this area. Finally, the scenario analysis results showed that particle movements could be stagnant when discharge from the upstream weir was reduced, implying the possibility of securing time for mitigation actions such as oil boom installation and wiping oil contaminants. The outcomes of this study can help improve the prediction accuracy of particle tracking simulation to establish the most suitable mitigation plan considering the combination of movable weir operation.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.30 no.5
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• pp.389-396
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• 2017

Peridynamics has been widely used in the dynamic fracture analysis of brittle materials. Recently, various crack patterns(compact region, floret, Hertz-type crack, etc.) of multilayered glass structures in experiments(Bless et al. 2010) were implemented with a bond-based peridynamic simulation(Bobaru et al.. 2012). The actual glass layers are bound with thin elastic interlayer material while the interlayer is missing from the peridynamic model used in the previous numerical study. In this study, the peridynamic interlayer modeling for the multilayered structures is proposed. It requires enormous computational time and memory to explicitly model very thin interlayer materials. Instead of explicit modeling, fictitious peridynamic particles are introduced for modeling interlayer materials. The computational efficiency and accuracy of the proposed peridynamic interlayer model are verified through numerical tests. Furthermore, preventing penetration scheme based on short-range interaction force is employed for the multilayered structure under compression and verified through parametric tests.

• Elastomers and Composites
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• v.48 no.3
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• pp.201-208
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• 2013

In this study, effect of different amounts of sulfur and vulcanization accelerators in the acrylonitrile styrene-butadiene rubber (AN-SBR)/silica compounds on the properties of tire tread compound were studied. As a result, cure rate and degree of cross-linking of the compounds were increased due to enhanced cross-linking reactivity by the increased amounts of sulfur and vulcanization accelerators. Also, abrasion resistance and the mechanical properties such as hardness and modulus of the compounds were improved by enhanced degree of cross-linking of the compounds. For the dynamic properties, tan ${\delta}$ value at $0^{\circ}C$ was increased due to the increase of glass transition temperature ($T_g$) by enhanced degree of cross-linking of the compound, and tan ${\delta}$ value at $60^{\circ}C$ was decreased. Initial cure time ($t_1$) showed the linear relationship with tan ${\delta}$ value at $60^{\circ}C$. This result is attributed that reduced initial cure time ($t_1$) of compounds by applying increased amount of curatives can form cross-linking in early stage of vulcanization that may suppress development of filler network. This result is verified by observation on the surface of annealed compounds using AFM (atomic force microscopy). Consequently, decreased initial cure time is considered a very important parameter to reduce tan ${\delta}$ at $60^{\circ}C$ through reduced re-agglomeration of silica particles.

• Journal of the Korean Geographical Society
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• v.39 no.2
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• pp.269-282
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• 2004

Luminescence dating of a coastal dune from the Shindu dunefield on the T'aean Peninsula shows that deposition of the dune structure began about 500-600 years ago. The lower section of the dune has remained stable since then but the upper part yields an age of about 30 years, suggesting reactivation or additional deposition since the 1970's. The two samples that were collected from the lower part of the dune at depths of 3.5 m and 2.0 m below the surface differ by an age interval of about 50-70 years. This indicates a net depositional rate of around 2.5 cm a year which is relatively slow for a coastal dune. Whilst only one dune structure has been dated for the time being and even though the dunefield was probably established much earlier in the Holocene, the OSL ages obtained demonstrate that some dunes in the area could be younger than 1000 years. Such chronologies point to a dynamic environment where the dune structures are not permanently fixed. Sedimentological properties of the dune sands are consistent with those of particles initially deposited under subaqueous conditions and then later transported by wind.

• Journal of Korea Water Resources Association
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• v.51 no.10
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• pp.917-927
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• 2018

Seven heavy metal concentrations (As, Cd, Cr, Cu, Ni, Pb, Zn) were continuously analyzed for twenty rainfall events in 2017~2018 in an urban basin. The overall and dynamic correlations between runoff characteristics and heavy metal concentrations were examined. The peak metal concentration generally appeared in the initial runoff but found to be delayed when the rainfall intensity was low. The rainfall duration had no relationship with either heavy metal concentrations or their total mass. Dynamics of heavy metal mass (load), with the exception of Cu and Zn, showed strong correlation with the 30 minute rainfall intensity (0.60~0.88) and runoff volume (0.74~0.89). While event mean concentration (EMC) showed positive correlation (0.54~0.73) with antecedent dry days (ADD), no significant relationship was found between runoff volume and pollutant concentration. This implies that the pollutants built up on the surface during dry days are washed off even with low rainfall energy. The dynamics of heavy metal and TSS concentrations showed good correlation (0.68~0.87). This result shows that the metals are transported along with solid particles as adsorbate in surface runoff. Regular street sweeping will reduce significant amount of heavy metal loads in urban surface runoff.

• Geophysics and Geophysical Exploration
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• v.8 no.1
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• pp.1-6
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• 2005

Analogue physical modelling using granular materials (i.e., sandbox experiments) has been applied with great success to a number of geological problems at various scales. Such physical experiments can also be simulated numerically with the Discrete Element Method (DEM). In this study, we apply the DEM simulation to the collision between the Indian subcontinent and the Eurasian Plate, one of the most significant current tectonic processes in the Earth. DEM simulation has been applied to various kinds of dynamic modelling, not only in structural geology but also in soil mechanics, rock mechanics, and the like. As the target of the investigation is assumed to be an assembly of many tiny particles, DEM simulation makes it possible to treat an object with large and discontinuous deformations. However, in DEM simulations, we often encounter difficulties when we examine the validity of the input parameters, since little is known about the relationship between the input parameters for each particle and the properties of the whole assembly. Therefore, in our previous studies (Yamada et al.,2002a,2002b,2002c), we were obliged to tune the input parameters by trial and error. To overcome these difficulties, we introduce a numerical biaxial test with the DEM simulation. Using the results of this numerical test, we examine the validity of the input parameters used in the collision model. The resulting collision model is quite similar to the real deformation observed in eastern Asia, and compares well with GPS data and in-situ stress data in eastern Asia.

• Applied Chemistry for Engineering
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• v.32 no.5
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• pp.509-515
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• 2021

In this study, poly lactic-co-glycolic acid (PLGA) nanoparticles (PNP) were prepared through double (w/o/w) emlusion and emulsifying solvent-evaporation technique using PLGA, which has biocompatibility and biodegradability. To maximize stability and bioavailability of the particles, chitosan-coated PLGA nanoparticles (CPNP) were prepared by charge interaction between PNP and chitosan. We demonstrated that CPNP can be utilized as a drug carrier of oral administration. The chemical structure of CPNP was analyzed by ¹H-NMR and FT-IR, and all characteristic peaks appeared, confirming that it was successfully prepared. In addition, particle size and zeta potential of CPNP were analyzed using dynamic light scattering (DLS) while morphological images were obtained using transmission electron microscope (TEM). Thermal decomposition behavior of CPNP was observed through thermogravimetric analysis (TGA). In addition, the cytotoxicity of CPNP was confirmed by MTT assay at HEK293 and L929 cell lines, and it was proved that there is no toxicity confirmed by the cell viability of above 70% at all concentrations. These results suggest that the CPNP developed in this study may be used as an oral drug delivery carrier.

• Korean Chemical Engineering Research
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• v.57 no.3
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• pp.358-367
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• 2019

Adsorption equilibrium and intraparticle diffusion characteristics of benzene, toluene, and xylene vapors on activated carbon and zeolite 13X were investigated. Static adsorption experiments were carried out under the pressure range of 0.01~0.07 bar while changing the adsorption temperature to 293.15 K, 303.15 K, and 313.15 K, respectively. Adsorption equilibrium was analyzed by Langmuir, Freundlich and Toth models. The adsorption energy was 5.26~31.0 kJ/mol representing physical adsorption characteristics. The maximum adsorption capacity on activated carbon was the largest for benzene, and the smallest for xylene. Toluene was in between. In the case of zeolite 13X, the maximum adsorption capacity was the largest for xylene, and the smallest for benzene as opposed to activated carbon. The effective diffusion coefficients of gas adsorbate were measured to be about $10^{-5}{\sim}10^{-4}cm^2/s$, and increased with temperature. As the pressure increased, the effective diffusion coefficients were decreased. The dependence of effective diffusion coefficients on temperature and pressure was greater in zeolite 13X particles than in activated carbon. Therefore, it is necessary to express the diffusion coefficients as a function of pressure in order to predict the precise dynamic behavior of the adsorption process using zeolite 13X where the pressure fluctuation occurs abruptly.

• Journal of the Korean Geotechnical Society
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• v.38 no.4
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• pp.59-70
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• 2022

There is a growing interest in evaluating earthquake damage and determining disaster prevention measures due to the magnitude 5.8 earthquake in Pohang, Korea. Since the liquefaction phenomena occurred extensively in the residential area as a result of the earthquake, there was a demand for research on liquefaction phenomenon evaluation and liquefaction disaster prediction. Liquefaction is defined as a phenomenon where the strength of the ground is completely lost due to a sudden increase in excess pore water pressure caused due to large dynamic stress, such as an earthquake, acting on loose sand particles in a short period of time. The liquefaction potential index, which can identify the occurrence of liquefaction and predict the risk of liquefaction in a targeted area, can be used to create a liquefaction hazard map. However, since liquefaction assessment using existing field testing is predicated on a single borehole liquefaction assessment, there has been a representative issue for the whole targeted area. Spatial interpolation and geographic information systems can help to solve this issue to some extent. Therefore, in order to solve the representative problem of geotechnical information, this research uses the kriging method, one of the geostatistical spatial interpolation techniques, and constructs a geotechnical information database for liquefaction and spatial interpolation. Additionally, the liquefaction hazard map was created for each return period using the constructed geotechnical information database. Cross validation was used to confirm the accuracy of this liquefaction hazard map.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.26 no.1
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• pp.49-64
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• 2014

Seabed beneath and near the coastal structures may undergo large excess pore water pressure composed of oscillatory and residual components in the case of long durations of high wave loading. This excess pore water pressure may reduce effective stress and, consequently, the seabed may liquefy. If the liquefaction occurs in the seabed, the structure may sink, overturn, and eventually fail. Especially, the seabed liquefaction behavior beneath a gravity-based structure under wave loading should be evaluated and considered for design purpose. In this study, to evaluate the liquefaction potential on the seabed, numerical analysis was conducted using 2-dimensional numerical wave tank. The 2-dimensional numerical wave tank was expanded to account for irregular wave fields, and to calculate the dynamic wave pressure and water particle velocity acting on the seabed and the surface boundary of the structure. The simulation results of the wave pressure and the shear stress induced by water particle velocity were used as inputs to a FLIP(Finite element analysis LIquefaction Program). Then, the FLIP evaluated the time and spatial variations in excess pore water pressure, effective stress and liquefaction potential in the seabed. Additionally, the deformation of the seabed and the displacement of the structure as a function of time were quantitatively evaluated. From the analysis, when the shear stress was considered, the liquefaction at the seabed in front of the structure was identified. Since the liquefied seabed particles have no resistance force, scour can possibly occur on the seabed. Therefore, the strength decrease of the seabed at the front of the structure due to high wave loading for the longer period of time such as a storm can increase the structural motion and consequently influence the stability of the structure.