• Title/Summary/Keyword: drying characteristic

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Multi-physics Model of Moisture Related Shrinkage on Lightweight and Normal Concrete (경량콘크리트 및 일반콘크리트의 수분관련 수축에 대한 다중물리모델)

  • Lee, Chang-Soo
    • Journal of the Korea Concrete Institute
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    • v.22 no.2
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    • pp.159-169
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    • 2010
  • A multiphysics model analysis including moisture transport, heat transfer and solid mechanics and experiments on the normal and light weight concrete were carried out in order to study the effect of preabsorbed water in the light weight aggregates on the drying and shrinkage characteristics of concrete. Consequently, with fixed water-cement ratio, loss of water content of normal and light weight concrete were compared and the results showed that the lightweight concrete lost less moist than the normal concrete in early age and long term which was by moist supply effect. Accordingly, shrinkage strain size and distribution of lightweight concrete were decreased, and shrinkage reducing effect was efficient in early age with water cement ratio 0.3 and in both early age, and long term with water cement ratio 0.5. The comparison of analysis results and exaperimental results indicate that characteristic values of moisture transport and the relation humidity and shrinkage strain from this study are resonable for application for other differential shrinkage analysis in lightweight concrete.

Synthesis and Electrochemical Characterization of Reduced Graphene Oxide-Manganese Oxide Nanocomposites

  • Lee, Yu-Ri;Song, Min-Sun;Lee, Kyung-Min;Kim, In-Young;Hwang, Seong-Ju
    • Journal of Electrochemical Science and Technology
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    • v.2 no.1
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    • pp.1-7
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    • 2011
  • Nanocomposites of reduced graphene oxide and manganese (II,III) oxide can be synthesized by the freeze-drying process of the mixed colloidal suspension of graphene oxide and manganese oxide, and the subsequent heat-treatment. The calcined reduced graphene oxide-manganese (II,III) oxide nanocomposites are X-ray amorphous, suggesting the formation of homogeneous and disordered mixture without any phase separation. The reduction of graphene oxide to reduced graphene oxide upon the heat-treatment is evidenced by Fourier-transformed infrared spectroscopy. Field emission-scanning electronic microscopy and energy dispersive spectrometry clearly demonstrate the formation of porous structure by the house-of-cards type stacking of reduced graphene oxide nanosheets and the homogeneous distribution of manganese ions in the nanocomposites. According to Mn K-edge X-ray absorption spectroscopy, manganese ions in the calcined nanocomposites are stabilized in octahedral symmetry with mixed Mn oxidation state of Mn(II)/Mn(III). The present reduced graphene oxide-manganese oxide nanocomposites show characteristic pseudocapacitance behavior superior to the pristine manganese oxide, suggesting their applicability as electrode material for supercapacitors.

The Relationship Between Effective Stress and Shear Strength of Weathered Granite Soils Based on Matric Suctions (모관흡수력에 따른 화강풍화토의 유효응력과 전단강도의 관계)

  • Lee, Younghuy;Oh, Seboong;Kim, Kwanghyun;Seong, Yulho
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.4
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    • pp.45-51
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    • 2012
  • The shear strength of weathered granite soils under unsaturated condition was evaluated by $K_0$ consolidated triaxial tests. Various matric suctions in the unsaturated triaxial tests were applied using suction-controlled triaxial test apparatus for weathered granite soils obtained in Daegu. Soil water characteristic curve (SWCC) laboratory tests for drying and wetting procedure were performed and van Genuchten curves were fitted by experimental results. The contribution of matric suction in unsaturated soils is directly correlated to effective stress and evaluated from SWCCs. The effective stresses were estimated from these SWCCs and the relationship between effective stress and unsaturated shear strength was determined. In the effective stress description, the unsaturated shear strength with respect to various suctions indicates unique relationship and almost the same as that of the saturated envelope.

Combustion Characteristics and Design of Fiber Mat Catalytic Burners (매트 형태 연소촉매를 사용하는 촉매버너의 구조와 연소특성)

  • Song, Kwang-Sup;Jung, Nam-Jo;Kim, Hee-Yeon
    • Journal of Energy Engineering
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    • v.17 no.2
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    • pp.100-106
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    • 2008
  • Flameless fiber mat catalytic burners have been known as an effective heat source in industrial drying processes since heat obtained from combustion can be transferred to absorptive body by far-infrared radiation. In order to extend the application of fiber mat catalytic burner, novel fiber mat catalytic burners were manufactured and combustion characteristics of them were investigated. For diffusive catalytic burners, the efficiency of combustion was significantly affected by the installation direction and the temperature of catalytic bed perimeter influenced on the diffusion rate of oxygen which determined the combustion efficiency of catalytic burner. It was seen in premixed catalytic combustion that air content in premixed fuel gas was optimized at slightly higher than theoretical amount of air. Combustion heat released higher than 70% by radiant heat in premixed catalytic combustion likewise diffusive catalytic combustion.

Preparation and Characterization of Pamidronate-loaded PLGA Wafer for the Treatment of Bone Resorption (골 재흡수 치료를 위한 파미드로네이트를 함유한 이식형 생분해성 PLGA 웨이퍼의 제조와 특성결정)

  • 유제영;김상욱;강길선;성하수;정제교
    • Polymer(Korea)
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    • v.26 no.5
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    • pp.680-690
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    • 2002
  • Implantable biodegradable wafers were prepared with pamidronate -loaded poly (L-lactide-co-glycolide) (PLGA, 75 : 25 mole ratio by lactide to glycolide, molecular weight : 20000 and 90000 g/mole) by direct compression method for the sustained release of pamidronate to investigate the possibility for the treatment of bone resorption. Pamidronate-loaded PLGA powders were prepared by means of physical mixing and spray drying with the control of formulation factors and characterized by scanning electron microscope and X-ray diffractometer. The pamidronate-loaded PLGA powders fabricated into wafers by direct compression under the constant pressure and time at room temperature. These wafers were also observed for their structural characteristic, release pattern, and degradation pattern. The release rate of pamidronate increased with increasing their initial loading ratio as well as increasing wafer thickness. The molecular weight of PLGA affects the release pattern : the higher molecular weight of PLGA, the faster release rate. It can be explained that the higher viscosity of high molecular PLGA solution at same concentration tends to aggregate PLGA and pamidronate resulting in unstable pharmaceutical dosage form. This system had advantages in terms of simplicity in design and obviousness of drug release rate and nay be useful as an implantable dosage form for the treatment of aural cholesteatoma.

Studies on the Characteristic of Removal Type Pressure-Sensitive Acrylic Adhesives (4원 공중합체 박리형 아크릴 점착제의 특성에 관한 연구)

  • Seo, Young-Ok;Seul, Soo-Duk
    • Journal of Adhesion and Interface
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    • v.1 no.1
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    • pp.15-22
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    • 2000
  • To prepare acrylic type pressure-sensitive adhesive, quarter polymers were synthesized from butylacrylate (BA), 2-ethylhexylacrylate (2-EHA), methyl methacrylate (MMA), 2-hydroxyethylmethacrylate (2-HEMA). The quarter polymer was identified by FT-IR. Molecular weight was measured by Gel Pearmeation Chromatograhy. Also, viscosity, solid content and peel strength were investigated. The peel strength was $160g_f/25mm$ when the volume ratio of feed monomer to solvent was 1.3:1 and the ratio was relevant to commercial usage. The pot life of adhesive was 30 s at the 50 m/min of heat treatment rate, and it indicated that the minimum drying time was 30 s. Not only weathering resistance keep up peel strength $160{\sim}180g_f/25mm$ after 1000 h, but also no residual remains.

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Digital Image Analysis (DIA) for Estimating the Degree of Saturation of The Soil-Water Characteristic Curves (SWCC) (SWCC의 포화도를 구하기 위한 DIA 적용)

  • Min, Tuk-Ki;Huy, Phan Thieu
    • Journal of the Korean Geotechnical Society
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    • v.24 no.3
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    • pp.53-63
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    • 2008
  • The aim of this study was to validate the suitability of an digital image analysis (DIA) method to measure the degree of saturation in the unsaturated conditions. This study was carried out on the Joo-Mun-Jin standard sand. A one-dimensional sand column test was used in the constant water level condition to get the correlation equation between the color number ($C_n$) and the measured degree of saturation (5). In addition, the hanging wale. column technique to determine the soil-water charactenstic curve (SWCC) was performed in a Buchner funnel. The average degree of saturation ($S_{ave}$) in the SWCC could be obtained by substituting average color number at each suction head value with the $C_n\;-\;S$ correlation equation. Comparisons were made between the measured results by the hanging water column test and those obtained from DIA method. Results showed that the DIA method tested here provided fairly good saturation distribution values in the drying and wetting processes.

Chemical Modification of Silk by Ethylene Cyanohydrin (에틸렌 시아노히드린에 의한 실크의 화학적 개질)

  • Lee, Geun-Souk;Bae, Do-Gyu
    • Current Research on Agriculture and Life Sciences
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    • v.26
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    • pp.23-30
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    • 2008
  • In this paper, when the silk fabric was modified by ethylene cyanohydrine, the reaction mechanism between both was studied at various treatment conditions such as curing temperatures and times, ethylene cyanohydrin concentrations and $ZnCl_2$ concentrations. Through the FT-IR and DSC analyses of the treated silk fabrics, we found the results as follows : It was observed in FT-IR analysis of the treated silk fabrics that the -OH characteristic peak($3,450cm^{-1}$)position and shape were all changed when drying and curing treatment conditions were at $80^{\circ}C$ for 3 minute and $110^{\circ}C$ for 2.5 minute, and the concentration of the $ZnCl_2$ was 0.1%. It indicated that the -OH group of the silk participated in the reaction between the silk fabric and ethylene cyanohydrin. From the DSC analysis, it was found that the pyrolysis temperatures of the treated silk fabrics by ethylene cyanohydrin which was processed in the same condition, were all increased from $311^{\circ}C$ to ab. $320^{\circ}C$. From the FT-IR analyses of the silk fabrics treated by ethylene cyanohydrin at the various concentrations of $ZnCl_2$, it was found that the -OH characteristic peaks($3,450cm^{-1}$) were similar to the nontreated one except that of the fabric treated at the $ZnCl_2$ conconcentration of 0.8% when drying and curing treatment conditions were at $80^{\circ}C$ for 3minute and $110^{\circ}C$ for 2.5 minute, and the concentration of the ethylene cyanohydrin was 5%. In the case of the $ZnCl_2$ concentration of 0.8% solution, a lot of change were observed in peak. From the DSC analysis of the treated silk fabrics which was processed in the same condition, it was showed that the pyrolysis temperatures of treated silk fabric were all increased from $311^{\circ}C$ to ab. $320^{\circ}C$, which was no relation with the concentration of $ZnCl_2$.

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Analysis of Food Components of Gastrodiae Rhizoma and Changes in Several Characteristics at the Various Drying Conditions (천마의 식품학적 성분 분석 및 건조방법에 따른 특성 변화)

  • Lee, Boo-Yong;Choi, Hyeon-Son;Hwang, Jin-Bong
    • Korean Journal of Food Science and Technology
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    • v.34 no.1
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    • pp.37-42
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    • 2002
  • This study was performed to provide basic that will predict the usefulness of Gastrodiae Rhizoma as food materials. The physicochemical properties of raw, freeze-dried, and hot air-dried Gastrodiae Rhizoma were investigated and analyzed. The moisture content of raw Gaxtrodiae Rhizoma was 81.20%. The moisture, crude protein, crude fat, crude ash and carbohydrates of freeze-dried Gastrodiae Rhizoma were 7.61%, 6.21%, 1.50%, 2.55%, and 89.74%, respectively. The total dietary fiber (TDF) of freeze-dried Gastrodiae Rhizoma was 11.68%. The K (1265.03 mg%) was the highest mineral found in Gastrodiae Rhizoma. Aspartic acid (1272.10 mg%) and glutamic acid (1249.50 mg%) in Gastrodiae Rhizoma were major amino acids. Linoleic acid (53.79%), palmitic acid (20.17%), oleic acid (11.93%), and linolenic acid (4.78%) were principal fatty acids in crude fat of Gaxtrodiae Rhizoma. Most of the free sugars of freeze-dried Gastrodiae Rhizoma was maltose (11.04%). In color, the freeze-dried showed the highest lightness (94.52) and the $60^{\circ}C$ hot air-dried showed the highest redness(0.76) and yellowness (16.41). The color differences among freeze-dried, $40^{\circ}C$ hot air-dried, and $60^{\circ}C$ hot air-dried Gastrodiae Rhizoma were distinguished markedly. Vitamin C contents in raw, freeze-dried, and $60^{\circ}C$ hot air-dried Gastrodiae Rhizoma were 0.015%, 0.010%, and 0.002%, respectively. The organoleptic characteristics of raw, freeze-dried, and hot air-dried Gastrodiae Rhizoma were evaluated and compared on the basis, 5 points of raw Gastrodiae Rhizoma by 9 points scale. The undesirable characteristics, such as fishy odor, sewage odor, bitter taste, bad and salty taste, decreased, while desirable characteristic such as sweet taste was maintained or increased considerably as drying temperature got higher.

The Comparative Understanding between Red Ginseng and White Ginsengs, Processed Ginsengs (Panax ginseng C. A. Meyer) (홍삼과 백삼의 비교 고찰)

  • Nam, Ki-Yeul
    • Journal of Ginseng Research
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    • v.29 no.1
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    • pp.1-18
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    • 2005
  • Ginseng Radix, the root of Panax ginseng C. A. Meyer has been used in Eastern Asia for 2000 years as a tonic and restorative, promoting health and longevity. Two varieties are commercially available: white ginseng(Ginseng Radix Alba) is produced by air-drying the root, while red ginseng(Ginseng Radix Rubra) is produced by steaming the root followed by drying. These two varieties of different processing have somewhat differences by heat processing between them. During the heat processing for preparing red ginseng, it has been found to exhibit inactivation of catabolic enzymes, thereby preventing deterioration of ginseng quality and the increased antioxidant-like substances which inhibit lipid peroxide formation, and also good gastro-intestinal absorption by gelatinization of starch. Moreover, studies of changes in ginsenosides composition due to different processing of ginseng roots have been undertaken. The results obtained showed that red ginseng differ from white ginseng due to the lack of acidic malonyl-ginsenosides. The heating procedure in red ginseng was proved to degrade the thermally unstable malonyl-ginsenoside into corresponding netural ginsenosides. Also the steaming process of red ginseng causes degradation or transformation of neutral ginsenosides. Ginsenosides $Rh_2,\;Rh_4,\;Rs_3,\;Rs_4\;and\;Rg_5$, found only in red ginseng, have been known to be hydrolyzed products derived from original saponin by heat processing, responsible for inhibitory effects on the growth of cancer cells through the induction of apoptosis. 20(S)-ginsenoside $Rg_3$ was also formed in red ginseng and was shown to exhibit vasorelaxation properties, antimetastatic activities, and anti-platelet aggregation activity. Recently, steamed red ginseng at high temperature was shown to provide enhance the yield of ginsenosides $Rg_3\;and\;Rg_5$ characteristic of red ginseng Additionally, one of non-saponin constituents, panaxytriol, was found to be structually transformed from polyacetylenic alcohol(panaxydol) showing cytotoxicity during the preparation of red ginseng and also maltol, antioxidant maillard product, from maltose and arginyl-fructosyl-glucose, amino acid derivative, from arginine and maltose. In regard to the in vitro and in vivo comparative biological activities, red ginseng was reported to show more potent activities on the antioxidant effect, anticarcinogenic effect and ameliorative effect on blood circulation than those of white ginseng. In oriental medicine, the ability of red ginseng to supplement the vacancy(허) was known to be relatively stronger than that of white ginseng, but very few are known on its comparative clinical studies. Further investigation on the preclinical and clinical experiments are needed to show the differences of indications and efficacies between red and white ginsengs on the basis of oriental medicines.