• 한국환경과학회지
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• 제16권5호
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• pp.641-647
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• 2007

The phase transfer catalysis(PTC) reagent, ethyl tri-octyl ammonium bromide(ETABr), strongly catalyzes the reaction of p-nitrophenyi diphenyl phosphinate(p-NPDPIN) with benzimidazole(BI) and its anion($BI^{\theta}$). In ETABr solutions, the dephosphorylation reactions exhibit higher first order kinetics with respect to the nucleophile, BI, and ETABr, suggesting that reactions are occuring in small aggregates of the three species including the sub-strate(p-NPDPIN), whereas the reaction of p-NPDPIN with $OH^{\theta}$ is not catalyzed by ETABr. This behavior for the drastic rate-enhancement of the dephosphorylation is referred as 'aggregation complex model' for reaction of hydrophobic organic phosphinates with benzimidazole(BI) in hydrophobic quarternary ammonium salt(ETABr) solutions.

• Computers and Concrete
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• 제17권1호
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• pp.29-51
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• 2016

Tension-stiffening is the contribution of concrete between the cracks to carry tensile stresses after cracking in Reinforced Concrete (RC) members. In this paper, a tension-stiffening model has been proposed for computationally efficient nonlinear analysis of RC flexural members subjected to service load. The proposed model has been embedded in a typical cracked span length beam element. The element is visualized to consist of at the most five zones (cracked or uncracked). Closed form expressions for flexibility and stiffness coefficients and end displacements have been obtained for the cracked span length beam element. Further, for use in everyday design, a hybrid analytical-numerical procedure has been developed for nonlinear analysis of RC flexural members using the proposed tension-stiffening model. The procedure yields deflections as well as redistributed bending moments. The proposed model (and developed procedure) has been validated by the comparison with experimental results reported elsewhere and also by comparison with the Finite Element Method (FEM) results. The procedure would lead to drastic reduction in computational time in case of large RC structures.

• 한국산업융합학회 논문집
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• 제20권2호
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• pp.195-204
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• 2017

Predicting the failure life of automated manufacturing systems can reduce overall downtime, maintenance costs, and total plant operation costs. Therefore, there is a growing interest in fatigue failure mechanisms as the safety or service life assessment of manufacturing systems becomes an important issue. In particular, fretting fatigue is caused by repeated tangential stresses that are generated by friction during small amplitude oscillatory movements or sliding between two surfaces pressed together in intimate contact. Previous studies in fretting fatigue have observed size effects related to contact width such that a critical contact width exists where there is drastic change in the fretting fatigue life. However, most of them are the two-dimensional finite element analyses based on the plane strain assumption. The purpose of this study is to investigate the contact size effects on the three-dimensional finite element model of a finite width of a flat specimen and a cylindrical pad exposed to fretting fatigue. The contact size effects were analyzed by means of the stress and strain averages at the element integration points of three-dimensional finite element model. This study shows that the fretting fatigue life of manufacturing systems can be predicted by three-dimensional finite element analysis based on SWT critical plane model.

• 응용통계연구
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• 제24권5호
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• pp.735-743
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• 2011

본 논문에서는 개입모형(intervention model)을 이용하여 한국의 입출국자 시계열 자료를 분석한다. 개입분석을 위하여 1997년 12월의 IMF 구제금융사건, 2003년의 3월의 SARS 발생, 그리고 2008년의 9월의 리먼브라더스 사태를 개입변수로 고려하였다. 그 결과, 한국의 총 입국자 수에는 SARS 개입변수만이 2003년 4월부터 영향을 미치기 시작하여 2003년 5월부터 급격하게 감소하는 영향을 미친 것으로 나타났다. 반면, 한국의 총 출국자 수에는 모든 3가지 개입의 효과가 유의하게 나타났으며 특히 IMF 개입변수는 1997년 12월부터 영구적인 영향을 미친 것으로 보이며 SARS 및 리먼브라더스 개입변수는 점차로 감소하는 영향을 미친 것으로 나타났다.

• Nuclear Engineering and Technology
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• 제32권3호
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• pp.214-226
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• 2000

In an effort to assess the performance of KAERI's coupled 3D kinetics - system T/H code, MARS/MASTER, Exercise III of the OECD main steam line break benchmark is solved. The analysis model of the reference plant, TMI-1 - a 2772 MWth B&W plant, consists of three major components: a core neutronics model involving 241$\times$28 neutronic nodes, a vessel 3D T/H model consisting of 374 hydrodynamic volumes, and a 1D system T/H model containing 157 hydrodynamic volumes. The results show that there is a significant amount of flow mixing occurring in the upper and lower plenum regions and the core power distribution evolves to a highly localized shape due to the presence of a stuck rod, as well as the asymmetric flow distribution. It is judged that MARS/MASTER properly captures these drastic 3-dimensional effects. Comparisons with other results submitted to OECD confirm the accuracy of the MARS/MASTER solution.

• 대한지질공학회:학술대회논문집
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• 대한지질공학회 2002년도 정기총회 및 학술발표회
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• pp.235-248
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• 2002

지하수개발 기술의 발전과 생활여건 개선으로 지하수의 사용이 증가되면서 지하수에 대한 관리상 어려움과 여러 문제점들이 발생하고 있다. 지하수관리체계의 부실, 관리 인원의 부족, 무분별한 개발 등으로 지하수 오염 및 수량부족 현상이 가중되고 있고, 또한 지하수관 정의 관리가 어려워 지역적인 과잉개발이나 폐공이 방치되는 현상이 나타나고 있다. 본 논문은 GIS를 이용한 지하수관리의 시스템구축 모델을 제시하고, 지하수관리시스템에 필요한 분석기능 및 지하수관리 방법을 구현하여 효율적인 지하수관리가 이루어질 수 있도록 하는데 목적이 있다. 지하수개발의 위치정보를 기록하고 개발자료와 현장조사자료 등의 여러 자료를 D/B화 하였다. 또한 위성영상을 이용한 선구조 분석 자료와 수리시험 자료, 수질조사 자료 등을 활용하여 지역별 특성 값을 주제도로 작성하였고, 이러한 자료들을 활용하여 지하수 모델링 기초자료를 자동 생성할 수 있도록 하였다. 신규 지하수개발 위치에 대하여 주변의 지하수개발현황 및 오염원 현황, 선구조의 발달, 오염취약성도(DRASTIC), 수질조사 등의 자료를 손쉽게 파악할 수 있는 장점이 있다. 지하수관리시스템은 이러한 기능들을 이용하여 지하수개발 적지선정이 가능하다.

• 한국환경과학회지
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• 제20권1호
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• pp.119-126
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• 2011

In this study, reaction model and reactions rate accelerated by o-iodosobenzoate ion(IB$^{\ominus}$) on hydrolysis reaction of p-nitrophenyl valate(NPV) using ethyl tri-octyl ammonium mesylate(ETAMs) for quaternary ammonium salts, the phase transfer catalysis(PTC) reagent, were investigated. The effect of IB$^{\ominus}$ on hydrolysis reaction rate constant of NPV was weak without ETAMs solutions. Otherwise, in ETAMs solutions, the hydrolysis reactions exhibit higher first order kinetics with respect to the nucleophile, IB$^{\ominus}$, and ETAMs, suggesting that reactions are occurring in small aggregates of the three species including the substrate(NPV), whereas the reaction of NPV with OH$^{\ominus}$ is not catalyzed by ETAMs. Different concentrations of NPV were tested to measure the change of rate constants to investigate the effect of NPV as substrate and the results showed that the effect was weak. This means the reaction would be the first order kinetics with respect to the nucleophile. This behavior for the drastic rate-enhancement of the hydrolysis is referred as 'Aggregation complex model' for reaction of hydrophobic organic ester with o-iodosobenzoate ion(IB$^{\ominus}$) in hydrophobic quarternary ammonium salt(ETAMs) solutions.

• 한국지반공학회지:지반
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• 제12권2호
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• pp.43-58
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• 1996

지하구조물에 대한 설계 및 시공기술의 많은 발전에도 불구하고 아직도 상당부분 그간의 경험에 의존하며, 또한 많은 불확정성 요소들을 내포하고 있다. 그 중 가장 대표되는 것이 지반계수로서, 이를 설계단계에서 정확히 산정하는 데는 많은 어려움이 따른다. 본 논문의 주된 목적은 지하공간의 설계와 시공을 유기적으로 연결할 수 있는 지반공학적 접근의 일환으로 최적의 지반계수를 산정하는 데 있다. 이를 위하여 초기예측치와 계측치로부터 예측된 간을 합리적으로 조합할 수 있는 Extended Bayesian Method(EBM)을 적용하였으며, 이를 유한요소해석으로부터 구할 수 있도록 하였다. 또한 부산 지하철 현장과 캐나다의 Darlington취수터널에 대한 예제해석을 수행하여 제안된 방법의 효용성을 검증하였다.

• 한국잠사학회:학술대회논문집
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• 한국잠사학회 2003년도 International Symposium of Silkworm/Insect Biotechnology and Annual Meeting of Korea Society of Sericultural Science
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• pp.134-135
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• 2003

The insect cuticle undergoes drastic morphological alterations during postembryonic development and is an extracellular structure composed mainly of chitin and proteins that are synthesized and secreted by epidermal cells. Cuticle proteins, the major components of insect integument, are recently being focused as a model fur studying the mechanisms of gene regulation during molting and metamorphosis. (omitted)

• 한국진공학회지
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• 제8권2호
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• pp.157-164
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• 1999

The post ion implantation has been applied to modify early-grown BN layer and improve the adhesion of the BN films. The effect of ion implantation doses on microstructure and interlayer was investigated by FTIR and HRTEM. And the hardness and delamination life time of N+-implanted BN films were measured. With increasing the ion dose up to $5.0\times10^{15}\textrm{atoms/cm}^2$,the change of IR spectrum is observed. At $5.0\times10^{16}\textrm{atoms/cm}^2$, a drastic transition of cubic phase into hexagonal phase is detected. The change of microstructure of early-grown layers by ion implantation is confirmed using HRTEM. Both microhardness and delamination life time of BN films increase with ion dose. The modification model of early-grown BN layers is briefly discussed based on the displacement per atom and excess boron in the BN film induced by ion irradiation.