• Title/Summary/Keyword: dispersion method

Search Result 1,631, Processing Time 0.04 seconds

Preparation and Characteristics of Cellulose Acetate Based Nanocomposites Reinforced with Cellulose Nanocrystals (CNCs) (셀룰로오스 나노크리스탈 강화 셀룰로오스 아세테이트 나노복합소재 제조 및 특성)

  • Gwon, Jae-Gyoung;Lee, Dan-Bee;Cho, Hye-Jung;Lee, Sun-Young
    • Journal of the Korean Wood Science and Technology
    • /
    • v.46 no.5
    • /
    • pp.565-576
    • /
    • 2018
  • Cellulose acetate (CA) has been widely utilized for composite materials due to its high transparency and thermal resistance. In this study, CNCs (cellulose nanocrystals) were reinforced in CA nanocomposites for fortifying mechanical properties of the composites. In addition, CA nanocomposites reinforced with CNCs were manufactured by extrusion/injection processes applied with CNC-predispersion method for achieving a high dispersion level of CNCs in the CA matrix. According to the analysis of mechanical properties, the CA nanocomposite with 3 wt% CNCs has the highest tensile and flexural strengths due to the reinforcing effect of CNC nanoparticles. Thermogravimetric analysis (TGA) showed that the addition of acid hydrolyzed CNCs slightly lowered the initial pyrolysis temperature of CA nanocomposite.

Study of PSII-treated PMMA, PHEMA, and PHPMA ; Investigation of Their Surface Stabilities

  • Hyuneui Lim;Lee, Yeonhee;Seunghee Han;Jeonghee Cho;Moojin suh;Kem, Kang-Jin
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 1999.07a
    • /
    • pp.204-204
    • /
    • 1999
  • The plasma source ion implantation(PSII) technique which is a method using high negative voltage pulse in plasma system has the potential to change the surface properties of polymer. PSII technique increase the surface free energy by introducing polar functional groups on the surface so that it improves reactivity, hydrophilicity, adhension, biocompatability, etc. However, the mobility of polymer chains enables the modified surface layers to adapt their composition to interfacial force. This hydrophobic recovery interrupts the stability of modified surfaces to keep for the long time. In this study, poly(methyl methacrylate)(PMMA), poly(2-hydroxyethyl methacrylate)(PHEMA), and polu(2-hydroxypropyl methacylate)(PHPMA) for contact lens application, were modified to improve the wettability with PSII technique and were investigated the surface stabilities. Polymer film was prepared with solution casting(3 wt.% solution) and was annealed at 11$0^{\circ}C$ under vacuum oven to remove solvent completely and to eliminate physical ageing. The thickness of the film measured by scanning electron microscopy (SEM) and surface profilometer was about 10${\mu}{\textrm}{m}$. Polymers were treated with different kinds of gases, pulse frequency, pulse with, pulse voltage, and treatment time. Even though PMMA, PHEMA, and PHPMA have similar repeat unit structure, the optimal treatment conditions and the tendency to hydrophobic recovery were different. PHPMA, more hydrophilic polymer than PMMA and PHEMA showd better wettability and stability after mild treatment. Surface tensions were obtained by water and diiodomethane contact angle measurements to monitor the relation between hydrophobic recovery and polymer structure. Different ion species in plasma change the polar component and dispersion component of polymer surface. For better wettability surface, the increase of polar component was a dominant factor. We also characterized modified polymer surfaces using x-ray photoelectron spectroscopy(XPS), secondary ion mass spectrometry(SIMS), Fourier Transform infrared spectroscopy(FT-IR), and SEM.

  • PDF

Promoting Arbitration System in The Era of Digital Economy (디지털 경제시대의 중재제도 활성화 방안)

  • Kang Lee-Soo
    • Journal of Arbitration Studies
    • /
    • v.15 no.3
    • /
    • pp.3-25
    • /
    • 2005
  • The companies' management strategies of the electronic commerce market are different from those of the traditional market. The main difference between the electronic commerce market and the traditional market is an IT network system which is a companies' management strategies in the electronic commerce market. This study focuses on the examination and analysis of the companies' management strategies which are constituted through influence on the effectiveness of the IT network system in the electronic commerce market and Promoting Arbitration System in The Era of Digital Economy this study is to introduce several alternative policies of the Government and companies to such formated IT network system of the electronic commerce market in the future. It's also suggested that the Korean Commercial Arbitration Board (KCAB) fully cover consideration and arbitration, while KCAB for Electronic Commerce activates its proper role of consulting and ad hoc arbitration by using electronic information. E-commerce sets up the probability that its merchants and customers will not exist in the same legal jurisdictions. The confusing application of laws and wide geographical dispersion of these parties will necessitate a faster and cheaper dispute resolution methodology. Therefore, online ADR may be effective for e-commerce dispute resolution. The examples of online ADR operation are the cyber mediation of Electronic Transaction Dispute Resolution Committee, the cyber mediation of Korean Commercial Arbitration Board, the cyber mediation of Click N Settle, the online ADR of BBB online, and the cyber arbitration of virtual Magistrate. The paper points out the last one as the most desired practice. This study results are how to minimize the disputes and the method of dispute settlement. Therefore, a role of arbitration proposed and emphasized. To protect the dispute in advance, it's suggested to revise rules timely following on technical changes, and emphasized that the dispute has to lead to arbitration settlement not for consuming unnecessary time and finance for enterprises and consumers.

  • PDF

The Study on the Improvement of the Strength and the Thermal Shock Resistance of $Al_2O_3-ZrO_2$ Composites ($Al_2O_3-ZrO_2$ 복합체의 강도 및 열충격 저항의 향상에 관한 연구)

  • Hwang, K.H.;Bae, W.T.;Choi, M.D.;Oh, K.D.;Kim, K.U.;Kim, H.
    • Journal of the Korean Ceramic Society
    • /
    • v.25 no.3
    • /
    • pp.225-230
    • /
    • 1988
  • The strength and thermal shock resistance of $Al_2O_3-ZrO_2$ composites have been studied. The tetragonal $ZrO_2$ powder containing 1 mol.% $Y_2O_3$ and monoclinic $ZrO_2$ powder were prepared by coprecipitation method and subsequently mixed with $Al_2O_3$ powder and granulated by sieving. Duplex composites were prepared by dry mixing matrix agglomerate with 15 to 30 vol.% of dispersion agglomerate, followed by pressing and sintering at 1$600^{\circ}C$ for1 hr. These $Al_2O_3-ZrO_2$ 2 composites having heterogeneous structure showed improved thermal shock behaviors because of the microcracking and pores in dispersed granules, and compressive stresses around dispersed granules resulting from $ZrO_2$ transformation.

  • PDF

A study on the improvement of receiver antenna as elevation angle on optical satellite communication downlink for B-ISDN (B-ISDN용 광휘성통신 다운링크의 앙각에 따른 수신안테나 개선에 관한 연구)

  • 이상규;한종석;정진호;김영권
    • Journal of the Korean Institute of Telematics and Electronics A
    • /
    • v.32A no.3
    • /
    • pp.1-9
    • /
    • 1995
  • In the B-ISDN using satellite between geo-satellites and earth stations, the laser having high security and broad band width has to be used as a carrier for transmitting massive information of visual, vocal, and high rate data. In this paper, by computer simulation we analyzed the number of optical detector array of optical satellite communication downlink in case of using channel coding and no channel coding for BISDN between geo-satelites and earth stations under clear weather condition. It was supposed that 1 watt semiconductor laser was used and as modulation method, the binary FSK was used. The data rate of 10Gbps was used for B-ISDN. Also, hardly affected by atmospheric absorption 1.55$\mu$m wave-length was used to reduce influence of dispersion and chirp generated at a high speed transmission. We analyzed the received power, SNR and BER. The number of optical detector array was determined to satisfy for the BER less than 10$^{-7}$. Also, we ananlyzed the possibility of reducting the number of optical detector array in case of using channel coding. the number of optical detector array is one in the region where the elevation nangle is between 38$^{\circ}$ and 90$^{\circ}$ and two where the elevation angle is between 33$^{\circ}$ and 37$^{\circ}$ and three where the elevation angle is between 30$^{\circ}$ and 32$^{\circ}$ and increases per one as the elevation angle decreases per 1.deg.. So in the region where the elevation angle is 25$^{\circ}$, the number of optical detector arrays is eight. In case of using channel coding, the number of optical detector arrays decreases to five in the region where the elevation angle is 25$^{\circ}$. Therefore, we remaark the advantage of the channelcoding to decrease the size of received antenna and the number ob optical detector arrays.

  • PDF

Implementation of Compressive Receiver with Chirp LO Based on DDS for RFID Signal Detection (DDS 기반의 Chirp LO가 적용된 RFID 신호 탐지용 컴프레시브 수신기의 구현)

  • Jo, Won-Sang;Park, Dong-Chul
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
    • /
    • v.20 no.11
    • /
    • pp.1186-1193
    • /
    • 2009
  • In this paper, we propose DDS(Direct Digital Synthesizer) as a new implementation method of chirp LO(Local Oscillator) for compressive receiver applied for RFID signal detection in UHF band. We designed a receiver whose input frequency range is 908.5~914 MHz, DDL(Dispersive Delay Line) bandwidth is 6 MHz, and dispersion delay time is $13\;{\mu}s$. Chirp LO based on DDS is designed to meet $26\;{\mu}s$ sweep time and 12 MHz bandwidth for complete compressive mechanism. The measured 3 dB pulse width of the compressed signal of the fabricated receiver is 260 ns and the frequency resolution for simultaneous input signals is below 200 kHz. These performances indicate that the proposed chirp LO based on DDS and the compressive receiver is suitable for RFID signal detection in UHF band.

An efficient shear deformation theory for wave propagation in functionally graded material beams with porosities

  • Benadouda, Mourad;Atmane, Hassen Ait;Tounsi, Abdelouahed;Bernard, Fabrice;Mahmoud, S.R.
    • Earthquakes and Structures
    • /
    • v.13 no.3
    • /
    • pp.255-265
    • /
    • 2017
  • In this paper, an efficient shear deformation theory is developed for wave propagation analysis in a functionally graded beam. More particularly, porosities that may occur in Functionally Graded Materials (FGMs) during their manufacture are considered. The proposed shear deformation theory is efficient method because it permits us to show the effect of both bending and shear components and this is carried out by dividing the transverse displacement into the bending and shear parts. Material properties are assumed graded in the thickness direction according to a simple power law distribution in terms of the volume fractions of the constituents; but the rule of mixture is modified to describe and approximate material properties of the functionally graded beams with porosity phases. The governing equations of the wave propagation in the functionally graded beam are derived by employing the Hamilton's principle. The analytical dispersion relation of the functionally graded beam is obtained by solving an eigenvalue problem. The effects of the volume fraction distributions, the depth of beam, the number of wave and the porosity on wave propagation in functionally graded beam are discussed in details. It can be concluded that the present theory is not only accurate but also simple in predicting the wave propagation characteristics in the functionally graded beam.

Preparation and Physical Properties of Acrylonitrile-Butadiene Rubber Nanocomposites Filled with Zinc Dimethacrylate (디메틸아크릴산 아연을 이용한 아크릴로나이트릴-부타디엔 고무 나노복합체의 제조 및 물성)

  • 진원섭;이해성;나창운
    • Polymer(Korea)
    • /
    • v.28 no.2
    • /
    • pp.185-193
    • /
    • 2004
  • Elastomeric nanocomposites were prepared by employing zinc dimethacrylate into an acrylonitrile-butadiene rubber, and their network structures, mechanical properties, and fracture morphologies were investigated according to the adding methods and contents of zinc dimethacrylate. The total crosslink density increased with increasing the zinc dimethacrylate level, due to increased ionic bonds. Both the tensile strength and tear strength increased with increasing zinc dimethacrylate loadings, and then decreased after reaching a maximum value. It was found that the tear strength and crack resistance were greatly affected by the mixing method of zinc dimethacrylate. The in-situ nanocomposites, where zinc dimethacrylate particles were formed by the reaction of zinc oxide and methacrylic acid, showed much improved tear strength and crack resistance compared to those of the nanocomposites based on the direct mixing of zinc dimetacrylate powders. This was because of the finer zinc dimethacrylate particles and improved dispersion of the in-situ nanocomposites.

Preparation and Application of Wnitening Ingredient Entrapped in Solid Lipid Nanoparticle [SLN] (미백성분이 포함된 나노입자의 제조와 응용)

  • 한성철;김연주;이기영;김동운
    • KSBB Journal
    • /
    • v.19 no.3
    • /
    • pp.178-186
    • /
    • 2004
  • The aim of this study was to investigate the skin-whitening effect of okyong-san and to develop new drug delivery carrier The extracts of okyong-san were found to have the whitening effect and Eudragit$\^$ⓡ/ L 100-55 (EUD) coated solid lipid nanoparticle (E-SLN) was prepared by solvent evaporation method and melt dispersion technique. As a result, E-SLN have a 144-170 nm of particle size, spherical shape, and 33-41% encapsulation efficiency, After release test in vitro, release profile of E-SLN depended on pH and temperature. Lastly, closed patch test and skin-whitening test was peformed clinically. In conclusion, test sample had non-stimulation and high % whiteness. The results suggest that okyong-san and E-SLN is useful as cosmeceuticals for whitening cosmetics.

Development and Application of Process Model for Description of Load Change of Boiler Plant in High Load (고부하에서의 보일러 플랜트 부하변동 묘사를 위한 프로세스 모델 개발 및 적용)

  • Park, Jeong;Lee, Ki-Hyun;Yang, Li-Ming;In, Jong-Soo;Park, Seok-Ho;Kweon, Sang-Hyeok;Oh, Dong-Han
    • Journal of Energy Engineering
    • /
    • v.6 no.1
    • /
    • pp.41-51
    • /
    • 1997
  • A dynamic mathematical model of a thermal power plant with a single drum-type boiler is described with the base on modular concept. The present process model, which is including full scope of the components and high load changes, is based on physical approach through lumped parameters. The module, which means a component of the power plant and must essentially depict the characteristics of the component well, might be interconnected using pressure nodal method in a arrangement determined by users. With the results of the load changes of 75 MW to 95 MW and 95MW to 75 MW with the rate of 3 MW/min, the applicability of the process model is examined connecting to DCS(Dispersion Control System), which has a real running logic of 100 MW real power plant.

  • PDF