• 제목/요약/키워드: direct energy gap

검색결과 117건 처리시간 0.024초

InSb 결정 성장과 Zn 확산에 관한 연구 (A study on the InSb crystal growth and the Zn diffusion)

  • 김백년;송복식;문동찬;김선태
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1992년도 하계학술대회 논문집 B
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    • pp.816-819
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    • 1992
  • Binary compound semiconductor InSb crystal which has direct-transition energy gap (0.17 ev) grown by vertical Bridgman method, then the electric-magnetic and optical properties of InSb crystal were surveyed. The growth rate of the crystals was 1mm/hr and the lattice constant $a_\circ$ of the grown crystal was 6.4863$\AA$. The electrical properties were examined by the Hall effect measurement with the van der Pauw method in the temperature range of 70$\sim$300K, magnetic field range of 500$\sim$10000 gauss. The undoped InSb crystal was n-type, the concentration and the electron mobility were 2$\sim$6 ${\times}$ $10^{16}$$\textrm{cm}^{-3}$ and carrier mobility was 6$\sim$2${\times}$$10^{4}$$cm^{2}$/v.sec at 300K, respectively. The carrier mobility was decreased with $T^{-1/2}$ due to the lattice scattering above 100K, and decreased by impurity scattering below100K. The magnetoresistance was increased 190% at 9000 gauss as compared with non-appliced magnetic field and the magnetoresistance was increased with increasing the magnetic field. Also, the Hall voltage was increased with increasing the magnetic field and decreasing the thickness of sample. The optical energy band gap of InSb at room temperature determined using the IR spectrometer was 0.167eV. The diffusion depth of Zn into InSb proportionally increased with the square root of diffusion time and the activation energy for Zn diffusion was 0.67eV. The temperature dependence of diffusion coefficient was $D=4.25{\times}10^{-3}$exp (-0.67/$K_BT$).

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Layer-by-layer Control of MoS2 Thickness by ALET

  • 김기현;김기석;염근영
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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    • pp.234.1-234.1
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    • 2015
  • Molybdenum disulfide (MoS2)는 van der Waals 결합을 통한 층상구조의 물질로써 뛰어난 물리화학적, 기계적 특성으로 Field Effect Transistors (FETs), Photoluminescence, Photo Detectors, Light Emitters 등의 많은 분야에서 연구가 보고 되어지고 있는 차세대 2D-materials이다. 이처럼 MoS2 가 다양한 범위에 응용될 수 있는 이유는 layer 수가 증가함에 따라 1.8 eV의 direct band gap 에서 1.2 eV 의 indirect band-gap으로 특성이 변화할 뿐만 아니라 다양한 고유의 전기적 특성을 지니고 있기 때문이다. 그러나 MoS2 는 원자층 단위의 layer control 이 어렵다는 이유로 다양한 전자소자 응용에 많은 제약이 보고 되어졌다. 본 연구에서는 MoS2 의 layer를 control 하기 위해 ICP system 에서 mesh grid 를 삽입하여 Cl2 radical을 효과적으로 adsorption 시킨 뒤, Ion beam system 에서 Ar+ Ion beam 을 통해 한 층씩 제거하는 방식의 atomic layer etching (ALE) 공정을 진행하였다. ALE 공정시 ion bombardment 에 의한 damage 를 최소화하기 위해 Quadruple Mass Spectrometer (QMS) 를 통한 에너지 분석으로 beam energy 를 20 eV에서 최적화 할 수 있었고, Raman Spectroscopy, X-ray Photoelectron Spectroscopy (XPS), Atomic Force Microscopy(AFM) 분석을 통해 ALE 공정에 따른 MoS2 layer control 가능 여부를 증명할 수 있었다.

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Annealing Effect on the Structural and Optical Properties of In2S3 Thin Films

  • 황동현;안정훈;손영국
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.589-589
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    • 2012
  • Indium sulfide thin films have been grown onto glass substrates using radio frequency magnetron sputtering at room temperature. The as-deposited film were annealed in nitrogen atmosphere at different temperatures of 100, 200, 300, 400 and $500^{\circ}C$ with an 1 h annealing time. The effect of annealing temperature on composition, structure, morphology and optical properties of the as-grown In2S3 films has been studied. The XRD results indicate that the as-deposited films are composed by a mixture of both cubic ${\alpha}$ and ${\beta}$ crystalline phases, with some fraction of tetragonal phase. The thermal annealing on the films produces the conversion of the cubic crystalline phases to the tetragonal ${\beta}$ one and a crystalline reorientation of the latter phase. The surface morphological analysis reveals that the films grown at $300^{\circ}C$ have an average grain size of ~ 58 nm. These films show a S/In ratio of 0.99. The optical band gap is found to be direct and the films grown at $300^{\circ}C$ shows a higher optical transmittance of 80% and an energy band gap of 2.52 eV.

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차세대 전력반도체 소자 및 패키지 접합 기술 (Recent Overview on Power Semiconductor Devices and Package Module Technology)

  • 김경호;좌성훈
    • 마이크로전자및패키징학회지
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    • 제26권3호
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    • pp.15-22
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    • 2019
  • In these days, importance of the power electronic devices and modules keeps increasing due to electric vehicles and energy saving requirements. However, current silicon-based power devices showed several limitations. Therefore, wide band gap (WBG) semiconductors such as SiC, GaN, and $Ga_2O_3$ have been developed to replace the silicon power devices. WBG devices show superior performances in terms of device operation in harsh environments such as higher temperatures, voltages and switching speed than silicon-based technology. In power devices, the reliability of the devices and module package is the critically important to guarantee the normal operation and lifetime of the devices. In this paper, we reviewed the recent trends of the power devices based on WBG semiconductors as well as expected future technology. We also presented an overview of the recent package module and fabrication technologies such as direct bonded copper and active metal brazing technology. In addition, the recent heat management technologies of the power modules, which should be improved due to the increased power density in high temperature environments, are described.

막 증발법을 이용한 셰일가스 폐수 처리 가능성 평가 (Feasibility study on shale gas wastewater treatment using membrane distillation)

  • 조형락;최용준;이상호
    • 상하수도학회지
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    • 제30권4호
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    • pp.441-447
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    • 2016
  • Development of shale gas has drawn increasing attention since it is one of promising alternative energy resources. However, contamination of groundwater and surface water during the extraction of shale gas is becoming a serious environmental issues, which brings the needs to treat wastewater generated from hydraulic fracking. In this study, the feasibility of membrane distillation (MD) for the treatment of shale gas wastewater was investigated using a laboratory scale experimental setup. Flat-sheet MD membranes were used to treat produced water from a shale gas well in the United States. Different configurations such as direct contact MD (DCMD) and air gap MD (AGMD) were compared in terms of flux and fouling propensity. The foulants on the surface of the membranes were examined. The results suggest that MD can treat the shale gas produced water containing more than 200,000 mg/L of total dissolved solids, which is impossible by other technologies such as reverse osmosis (RO) and forward osmosis (FO). In this study, we investigated the possibility of processing and characterization of shale gas produce wastewater using membrane distillation. Laboratory scale membrane distillation experimental device was developed. It was compared the flat-sheet direct contact membrane distillation and flat-sheet air gap membrane distillation. AGMD flux in lower than the flux of DCMD, it was expected that the contamination caused by organic matters.

전착법을 이용한 Cu2O 박막 형성 및 공정 조건에 따른 특성 변화 (Influence of Process Conditions on Properties of Cu2O Thin Films Grown by Electrodeposition)

  • 조재유;하준석;류상완;허재영
    • 마이크로전자및패키징학회지
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    • 제24권2호
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    • pp.37-41
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    • 2017
  • $Cu_2O$는 초저가 태양전지의 흡수층으로 적용될 수 있는 물질 중 하나로 direct band gap($E_g={\sim}2.1eV$)을 갖고 있으며 최대 650 nm 파장의 빛을 흡수 할 수 있는 높은 흡수율을 가지고 있다. 또한 무독성, 풍부한 매장량으로 낮은 비용 등의 여러 장점을 가지며 간단하고 저렴한 방법으로 대량으로 제작이 가능하다. 본 연구에서 Au가 증착된 $SiO_2/Si$ 기판 위에 전착법을 통해 $Cu_2O$ 박막을 제작하였다. 우리는 용액의 pH와 작업전극에 인가되는 전위, 용액의 온도와 같은 공정조건을 바꾸어주었고 최종적으로 XRD와 SEM 사진 분석을 통해 박막의 특성을 확인하였다.

다원화합물 반도체 $ZnGaInS_4:Er^{3+}$ 단결정의 광발광 특성 (Photoluminescence of Multinary-compound Semiconductor $ZnGaInS_4:Er^{3+}$ Single Crystals)

  • 김남오;김형곤;방태환;현승철;김덕태
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 학술대회 논문집 전문대학교육위원
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    • pp.35-39
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    • 2000
  • $ZnIn_2S_4$ and $ZnGaInS_4:Er^{3+}$ single crystals crystallized in the rhombohedral (hexagonal) space group $C_{3v}^5(R3m)$, with lattice constants $a=3.852{\AA},\;c=37.215{\AA}$ for $ZnIn_2S_4$, and $a=3.823{\AA}$, and $c=35.975{\AA}$ for $ZnIn_2S_4:Er^{3+}$. The optical absorption measured near the fundamental band edge showed that the optical energy band structure of there compounds had a direct and indirect band gap, the direct and indirect energy gaps are found to be 2.778 and 2.682 eV for $ZnIn_2S_4$, and 2.725 and 2.651eV for $ZnIn_2S_4:Er^{3+}$ at 293 K. The photoluminescence spectra of $ZnIn_2S_4:Er^{3+}$ measured in the wavelength ranges of $500nm{\sim}900nm$ at 10 K. Eight sharp emission peaks due to $Er^{3+}$ ion are observed in the regions of $549.5{\sim}550.0nm,\;661.3{\sim}676.5nm$, and $811.1{\sim}834.1nm$, and $1528.2{\sim}1556.0nm$ in $CdGaInS_4:Er^{3+}$ single crystal. These PL peaks were attributed to the radiative transitions between the split electron energy levels of the $Er^{3+}$ ions occupied at $C_{2v}$, symmetry of the $ZnIn_2S_4$ single crystals host lattice.

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진공복사관식 집열기의 성능실측 및 최적화 연구 (Study on the Optical Performance of Evacuated Solar Collectors)

  • 천원기;강상훈;김기홍;이용국;장래웅
    • 한국태양에너지학회 논문집
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    • 제21권4호
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    • pp.63-71
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    • 2001
  • This work has been carried out to find the ideal operating conditions for solar vacuum tube collectors which are widely used at present. Various types of solar collectors including a flat plate one were experimentally tested and examined to determine their thermal efficiencies and operating characteristics. Generally, solar vacuum tubes can be classified into two groups according to their design features. Of these, one is characterized by the insertion of a metallic device(such as a finned heat pipe) in an evacuated glass tube for the collection and transportation of solar energy. The other utilizes double glass tubes where the smaller one is contained inside the bigger one and soldered to each other after the small gap between them is evacuated. Both of these solar collectors are designed to minimize convection heat losses by removing the air which is in direct contact with the absorber surface. The performance of the former type can be readily analyzed by applying the relevant correlations developed for flat plate solar collectors. This has been demonstrated in the present study for the case of a solar collector where a heat pipe is inserted in an evacuated tube.

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수직 Bridgman법으로 제작한 $\beta-In_2Te_3$ 단결정의 광학적 전기적 특성 (Optical and Electrical Property of $\beta$-Phases $In_2Te_3$ Single Crystal by Vertical Bridgman Method)

  • 김남오;이강연;정병호;최연옥;신화영;조금배
    • 전기학회논문지P
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    • 제58권4호
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    • pp.451-454
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    • 2009
  • The $\beta-In_2Te_3$ single crystal was grown by vertical Bridgman method. The $\beta-In_2Te_3$ single crystal had a face centered cubic(fcc) structure. The lattice constants were found to be $a\;=\;0.617\;{\AA}$. The direct optical energy gap ($E_g$) was found to be 1.11 ev at 300 K. Raman spectra peak of $\beta-In_2Te_3$ single crystal showed the low $E_{LO}$ mode at $105\;cm^{-1}$. The electrical conduction type was measured by the thermal method and was p-type. The electrical conductivity was found to be $1.8\;{\times}\;10^{-2}\;{\Omega}^{-1}cm^{-1}$ at 300 K. The activation energy was found to be 0.51 eV.

풍력발전기용 800kW급 직접구동형 발전기 개발 (Development of 800kW class Direct Drive Synchronous Generator for WECS)

  • 이홍기;김동언;서형석;한홍식;정영규;이월우;박기현;정진화;임민수;오만수
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2005년도 춘계학술대회
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    • pp.76-79
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    • 2005
  • 포항풍력에너지연구소와 (주)보국전기는 에너지 관리공단의 지원으로 2002년부터 직접구동형 풍력터빈( KBP-750D) 에 사용될 발전기 개발을 시작하여 2005년 3월 개발을 완료하였다. KBP-750D에 사용되는 발전기는 증속을 위한 gearbox를 사용하지 않는 직접 구동형이고, 영구자석을 사용하여 여자하는 형식이다. 이런 특징은 풍력발전에서 요구하는 주요 요구조건인 고 효율, 고 신뢰성을 만족시키기 위해서 매우 중요하다. 개발된 발전기는 25 rpm 에서 800 kW의 정격을 가지도록 설계되었다. 공극 직경은 3,320mm 이며, stator의 길이는 705mm, 공극은 4.5mm 이고, 극수는 84이다. 또한 전체 중량은 약 22 ton이다. 이 논문에서는 발전기의 물리설계, 공학설계, 제작 및 시험결과에 관해서 기술한다.

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