• Title/Summary/Keyword: diffusion treatment

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A study on the Structure of Turbulent Diffusion Flame Behind the Hollowed Flame Holder (중앙분공형 보염기 후류에 안정된 난류확산화염의 구조에 관한 연구(I))

  • Kang, I.G.;Lee, W.S.;Kim, T.H.;Lee, D.H.
    • Journal of Power System Engineering
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    • v.2 no.2
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    • pp.13-19
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    • 1998
  • The purpose of study is to investigate the flame stability and Structure of turbulent diffusion flame behind the hollowed flame holder, which is located on the waste gas coming out from the test furnace. Fluctuating temperature and ion current measurement and their statistical treatment were used for the purpose. Three types of flame were stabilized and each of which were changed by adequate equivalence ration. And we found that have no periodicity near reacting zone.

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Analysis of Dopant Effects in Ni-Silicide for CMOS Technology (CMOS소자를 위한 Ni Silicide의 Dopant에 따른 영향분석)

  • 배미숙;지희환;이헌진;안순의;박성형;이기민;이주형;왕진석;이희덕
    • Proceedings of the IEEK Conference
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    • 2002.06b
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    • pp.241-244
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    • 2002
  • The dependence of NiSi properties such as sheet resistance and cross-sectional profile on the dopants was characterized. There was little difference of sheet resistance between various dopants such as As, p, BF2 and B just after R'n formation of NiSi. However, the NiSi properties showed strong dependence on the dopants when thermal treatment was applied after RTf formation. BFa .implanted silicon was the best stable property while As implanted one was the worst. The main reason of the excellence property of BF2 sample is believed to be the retardation of Ni diffusion by the F. Therefore, retardation of Ni diffusion is very desirable fur high performance NiSi technology.

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Molecular Dynamics Simulation Studies of Benzene, Toluene, and p-Xylene in a Canonical Ensemble

  • Kim, Ja-Hun;Lee, Song-Hui
    • Bulletin of the Korean Chemical Society
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    • v.23 no.3
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    • pp.441-446
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    • 2002
  • We have presented the results of thermodynamic, structural and dynamic properties of liquid benzene, toluene, and p-xylene in canonical (NVT) ensemble at 293.15 K by molecular dynamics (MD) simulations. The molecular model adopted for these molecules is a combination of the rigid body treatment for the benzene ring and an atomistically detailed model for the methyl hydrogen atoms. The calculated pressures are too low in the NVT ensemble MD simulations. The various thermodynamic properties reflect that the intermolecular interactions become stronger as the number of methyl group attached into the benzene ring increases. The pronounced nearest neighbor peak in the center of mass g(r) of liquid benzene at 293.15 K, provides the interpretation that nearest neighbors tend to be perpendicular. Two self-diffusion coefficients of liquid benzene at 293.15 K calculated from MSD and VAC function are in excellent agreement with the experimental measures. The self-diffusion coefficients of liquid toluene also agree well with the experimental ones for toluene in benzene and for toluene in cyclohexane.

A Study on the Diffusion Behaviors in Weld Interface of Cr-Mo Steel/Austenitic Stainless Steel (Cr-Mo강/오스테나이트계 스테인리스강 용접재의 용접계면에서의 확산거동에 관한 연구)

  • 김동배;이상율;이종훈;이상용;양성철
    • Journal of Welding and Joining
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    • v.17 no.4
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    • pp.46-52
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    • 1999
  • Some of the pressurized reactor pressure vessels used in many chemical plants are made of low alloy carbon steel plates internally clad with an austenitic stainless steel for improved anti-corrosion properties. In this study, metallurgic structure of the weld interface of A 387 Grade12Class1 low alloy carbon steel claded with A182-F321 austenitic stainless steel after thermal exposure simulation heat treatment was investigated to display a characteristic behavior of dissimilar metal weld interface with thermal exposure during service at high temperature and pressure. EPMA, STEM, vickers-hardness test were performed and the results were correlated with the microstructure. To estimate the depth of the carburized/decarburized bands quantitatively, a model for carbon diffusion was proposed. The validity of the proposed theoretical relationships was confirmed by the directly measured data from the welded parts failed during service.

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Low Temperature Dyeing Process by Intercellular diffusion through Cell Membrane Complex Modification of Wool. - Technology based on CSIRO and ICI (양모의 저온 염색 소개 - Sirolan LTD Process from ICI)

  • 윤일남
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2001.11a
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    • pp.3-11
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    • 2001
  • Fundamental studies at the CSIRO division of Wool technology and ICI on the diffusion of dyes into wool〔1,2〕have let to development of a new approach to wool dyeing. In this method, the cell membrane complex of wool is modified before dyeing by treatment under mildly alkaline conditions with a special chemicals. Wool pretreated with ethoxylated quaternary ammonium salt has an increased rate of dyebath exhaustion and dye penetration early in the dyeing cycle. This enables the treated material to be dyed below the boil for a similar time to the conventional cycle. This technique can be used on untreated and shrinkresist-treated wool and wool/nylon blends. In addition to good macro-levelness and excellent coverage of tippiness, the low temperature dyeing process give higher exhaustion levels of dyestuffs and insect-resist agent and hence cleaner effluent liquors, compared with conventional dyeing process. Low Temperature Dyeing process cause significantly less fiber damage than conventional way. The reduction in damage is reflected in improved processing performance of the dyed wool.

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Color Enhancement by Oxygen Torch in Blue Sapphires (블루사파이어와 루비의 고온산소 화염처리에 의한 색향상)

  • Song Oh Sung;Kim Sang Yeob
    • Journal of the Korean institute of surface engineering
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    • v.38 no.2
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    • pp.83-87
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    • 2005
  • We enhanced the color of blue sapphires and rubies successfully by using a oxygen-propane torch flame annealing, which had not been employed so far. We confirmed that about 1 mm-thick de-coloring of the corundum samples were available with 60 minutes flame annealing through eye evaluation, color coordination characterization, and methylene iodide immersion observation. We also suggest that the color centers such as $[Fe_{Al}^{\cdot}]$ may transform into transparent $[Fe_{Al}^{x}],\;[Cr_{A1}^{x}]$ sites with $[V_o^']$ generation at the elevated temperature in oxygen-rich atmosphere by diffusion mechanism. Our results implied that the longer diffusion time and the higher oxygen partial pressure might lead to the better de-coloring enhancement in corundum gem stones.

Microstructure and Corrosion Characteristics of Al-Si Diffusion Coated Ni Base Super alloy (Al-Si확산코팅에 따른 Ni기 초합금의 미세조직과 부식특성)

  • 안종천;김택수;윤동주;이경구
    • Journal of the Korean institute of surface engineering
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    • v.32 no.2
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    • pp.100-108
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    • 1999
  • The microstructure and corrosion properties of Al-Si diffusion coated PWA1426 alloy have been investigated. Experimental variables are included temperatures of heat-treatment and coating thickness. The microstructure of coated layer and corrosion properties were analysed by SEM, EDS and hot corrosion test. Two major processes have been found to contribute to microstructural changes in the coating. These are, firstly, the transformation of the NiAl to other $Ni_2Al_3$-based phase and secondly, the precipitation of Cr containing phases. Specimens heat treated at $1080^{\circ}C$ showed superior corrosion resistance to heat treated at $880^{\circ}C$. These increase in life was attributed to the transformation of NiAl and increased coating thickness of PWA1426 alloy.

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H13소재의 쇼트피닝과 이온질화에의한 표면경화

  • Jo, Gyun-Taek;Son, Seok-Won;Yu, Gwang-Chun;Lee, Yeong-Guk;Lee, Won-Beom
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.11a
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    • pp.58-59
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    • 2012
  • Surface hardening mechanism of H13 steel was investigated when ion niriding after shot peening process was applied. Severe plastic deformation induced nanocrystallized grains at surface region. Higher nitrogen concentration was achieved in ion nitrided specimen with shot peening treatment than in single nitrided specimen. The elemental mapping on chromium and nitrogen by TEM-EELs showed chromium dissolved in matrix enhanced bulk nitrogen diffusion at surface region. Higher nitrogen diffusion also caused lattice distortion. Nano-sized grains, higher nitrogen concentration, and lattice diffustion contributed to the surface hardening.

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The Apparent Mass Capacity Method for Transient Diffusion Problems with Change of Phase

  • Kim, Yongsoo;Wonmok Jae;D. R. Olander
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.05b
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    • pp.643-650
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    • 1995
  • A numerical method for treating transient diffusion Involving change of phase is presented. In other methods of dealing with this class of problems, the mass flux balance at the moving phase boundary requires explicit treatment of two distinct phases. The technique, originating from the apparent heat capacity method in transient heat conduction with the phase change, avoids the difficulty by transferring the concentration discontinuity at the boundary to smoothed physical property variations near the moving front. This technique accomodates the nonlinearities which preclude use of analytical solutions. It was tested against known analytical solutions for simple cases and turned out to be quite accurate.

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Effect of VC Addition on the Microstructural Evolution of Fe-TiC Cermet (VC의 첨가에 따른 Fe-TiC계의 미세조직변화)

  • 채기웅
    • Journal of the Korean Ceramic Society
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    • v.36 no.4
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    • pp.366-371
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    • 1999
  • The effect of VC addition on the microstructural evolution of Fe-TiC cermet has been investigated. The microstructures of the Fe-TiC varied with the amount of VC addition. The addition of 1wt% VC enhanced the instability of liquid-solid interface ; the dissolving interface showed round shape instead of facetted one which was ascribed to the increase of lattice mismatch between TiC and solid-solution carbide. in the speci-men with 10wt% VC the new set of solid-solution carbide grains of uniform and small size was formed in-side coarse TiC particles by diffusion induced recrystallizatin (DIR). With increasing the heat-treatment time fine recrystallized grains were dispersed homogeneously in the matrix and resulted in the increase in fracture strength.

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