• Journal of the Korean Chemical Society
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• v.41 no.8
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• pp.385-391
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• 1997

Diffusion Coefficient$(D_0)$ and electrode reaction rate Constant$(K_0)$ of Co$(dimethyl bipyridine)_3(ClO_4)_2$ were determined by cyclic voltammetry and chronoamperometry. It was also investigated that the effects of solvent, concentration, and scan rate, etc. on the diffusion coefficient and the temperature effect on the rate constant. The peak currents and diffusion coefficients were dcreased as increasing the viscosity of solvent. Diffusion coefficient was $5.54{\times}10^{-6 }cm^2/sec$ and the reaction rate constant was $2.39{\times}10^{-3 }/s$ at 25$^{\circ}C$. The thermodynamic parameters such as ${\Delta}G^{\neq},\;{\Delta}H^{\neq},\;and\;{\Delta}S$ were calculated from plotting the reaction rate constants versus the solution temperatures. This compound was shown the catalytic effect on the oxygen reduction that the reduction peak current of oxygen was greatly enhanced and the peak potential was shifted to +0.2 volt.

• Journal of the Korean Chemical Society
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• v.22 no.5
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• pp.304-310
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• 1978

The relative permeabilities, distribution coefficients and diffusion coefficient of some salts which are important components in blood plasma through a poly(HEMA) membrane were measured. The crosslinker which was used for preparing the membrane was tetraethylene glycol dimethacrylate(TEGDMA), the weight percentage of the latter was about 2.8. We found that the diffusion coefficients ($D_m$) of the solutes decrease exponentially with increasing molecular weight, and also that $D_m$'s decrease linearly (except urea) with cylindrical radius (a). These facts were explained by a sieve pore flow model. The relative permeability and diffusion coefficient of urea at various temperature were larger than those of other solutes such as glycine, ${\beta}$-alanine, D-glucose, saccharose and maleic acid. The result indicates that the poly(HEMA) membrane might be suitable for hemodialysis application.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.05c
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• pp.174-177
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• 2001

The electron transport coefficients, the electron drift velocity W, the longitudinal diffusion coefficient $ND_L$ and $D_L/{\mu}$, in pure Xe were calculated over the wide E/N range from 0.01 to 500 Td at 1 Torr by two-term approximation of the Boltzmann equation for determination of electron collision cross sections set and for quantitative characteristic analysis of Xe molecular gas.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.05c
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• pp.182-185
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• 2001

The electron transport coefficients, the electron drift velocity W, the longitudinal diffusion coefficient $ND_L$ and $D_L/{\mu}$, in pure Ne were calculated over the wide E/N range from 0.01 to 300 Td at 1 Torr by two-term approximation of the Boltzmann equation for determination of electron collision cross sections set and for quantitative characteristic analysis of Ne molecular gas.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.05c
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• pp.164-167
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• 2001

The electron transport coefficients, the electron drift velocity W, the longitudinal diffusion coefficient $ND_L$ and $D_L/{\mu}$, in pure $CO_2$ were calculated over the wide E/N range from 0.01 to 500 Td at 1 Torr by two-term approximation of the Boltzmann equation for determination of electron collision cross sections set and for quantitative characteristic analysis of $CO_2$ molecular gas. And for propriety of two-term approximation of Boltzmann equation analysis, the calculated results compared with the electron transport coefficients measured by Nakamura.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.05c
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• pp.29-32
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• 2001

We measured the electron transport coefficients(the electron drift velocity, W, and the longitudinal diffusion coefficient, $D_L$) in pure $CF_4$ over the E/N range from 0.04 Td to 250 Td by the double shutter drift tube. And these electron transport coefficients in pure $CF_4$ were calculated over the E/N range from 0.01 to 250 Td at 1 Torr by using the two-term approximation of the Boltzmann equation.

• Journal of Korea Foundry Society
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• v.8 no.3
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• pp.287-295
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• 1988

The experiment was carried out for the purpose of studying the carburization of pure iron ingot and sintered iron powder by solid carbon in the atmosphere of CO gas. The volocity of carburization was estimaed by the diffusion coefficient D calculated by carburization equation. The results obtained were as follow: 1. The higher the carburization temperature, carburization depth and carbon concentration were increased, and the melting zone which had $2.8{\sim}3.4%C$ at the $3{\sim}4mm$ from interface of carburization was formed at $1300^{\circ}C$. 2. The main carburization mechanism of pure iron ingot and the sintered iron powder were proceeded by CO gas up to $1100^{\circ}C$, solid carbon over than $1300^{\circ}C$, respectively. 3. The main carburization mechanism of pure iron ingot at $1200^{\circ}C$ was proceeded by solid carbon, and sintered iron powder was proceeded bs CO gas, however, in case the reaction time, the carburization was proceeded by solid carbon over than 5hrs. 4. The diffusion coefficient D of carbon were $0.559{\times}10^{-6}cm^2.sec^{-1}$ at $1100^{\circ}C$, $0.237{\times}10^{-6}cm^2.sec^{-1}$ at $1200^{\circ}C$, $0.087{\times}10^{-6}cm^2.sec^{-1}$ at $1300^{\circ}C$, in case of pure iron ingot carburized. 5. The diffusion coefficient D of carbon were $0.124\;cm^2.sec^{-1}$ at $1100^{\circ}C$, $0.102\;cm^2.sec^{-1}$ at $1200^{\circ}C$, $0.480\;{\times}10^{-6}cm^2.sec^{-1}$ at $1300^{\circ}C$, in the case of sintered iron carburized at the pressuring $4ton\;/\;cm^2$.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.2
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• pp.99-103
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• 2010

A new analytic solution was derived for the diffusion into or from an immobile zone of a rectangular 2-D pore. For a long time, the new solution converges to a traditional mobile-immobile zone (MIM) model, but only if the latter is used with an apparent initial concentration that is smaller by almost 20% than the true one. This is the tradeoff for using a simple MIM model instead of an exact model based on the diffusion equation. The mass-transfer coefficient was found to be constant for a sufficiently long time; it was proportional to the molecular diffusion and inversely proportional to the square of the pore depth. The mass-transfer coefficient was time-dependent for a sufficiently short time and may be significantly larger than its asymptotic value.

• Korean Journal of Food Science and Technology
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• v.14 no.4
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• pp.315-323
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• 1982

The measurement of cell constant in a diaphragm-cell method is the most important factor. In order to get the correct cell constant, the diffusion coefficients of potassium chloride were measured, at various concentration and temperature of potassium chloride solution, and at the stirring rate in the cell. The pseudo-binary diffusion coefficients of organic aroma component (benzaldehyde) in sugar solution has been measured at various concentration and temperature with the cell constant obtained above. Experimental results were compared and discussed with the semi-empirical epuations from literatures. And, especially, the diffusion coefficient of benzaldehyde, $D_{ba}$ for a small solute diffusing in a viscous solvent of larger molecules is proportional to the -0.82 power of the viscosity of aqueous sugar solution, ${\mu}$ at constant temperature, $D_{ba}{\mu}^{0.82}=constant$.

• Journal of Ocean Engineering and Technology
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• v.32 no.4
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• pp.261-271
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• 2018

In this study, a hydraulic model test, to which Particle Image Velocimetry (PIV) system applied, was used to determine the hydrodynamic characteristics of the advection-diffusion of saltwater according to bottom conditions (impermeable/permeability, diameter, and inclination) and the difference of the initial salt. Considering quantitative and qualitative results from the experiment, the characteristics of the density current were discussed. As an experimental result, the advection-diffusion mechanism of salinity was examined by the shape of saltwater wedge and the flow structure of density currents with various bottom conditions. The vertical salt concentration obtained from the experiment was used as quantitative data to calculate the diffusion coefficient that was used in the numerical model of the advection-diffusion of saltwater.