• Title/Summary/Keyword: differential permeability

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Nondestructive Evaluation of Remanent Life of Turbine Rotor Steel by Measuring Reversible Magnetic Permeability (가역투자율 측정에 의한 터빈로터강의 비파괴적 잔여수명 평가)

  • Ryu, Kwon-Sang;Nahm, Seung-Hoon;Kim, Yong-Il
    • Journal of the Korean Society for Nondestructive Testing
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    • v.23 no.4
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    • pp.315-321
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    • 2003
  • The integrity of the turbine rotors can be assessed by measuring the material properties at service temperature. In order to evaluate the remanent life of turbine rotor steel nondestructively, a measurement system of reversible magnetic permeability using an alternating perturbing magnetic field was constructed. We present a new non-destructive method to evaluate the remanent life of 1Cr-1Mo-0.25V steel using the value of reversible magnetic permeability. This method is based on the existence of reversible magnetic permeability in the differential magnetization around the coercive field strength. We measured the first harmonics voltage induced in a coil using a lock-in amplifier tuned to an exciting frequency. The Results of reversible magnetic Permeability and Wickers hardness on the aged samples show that the peak interval of reversible magnetic permeability (PIRMP) and Vickers hardness decreases as aging time increases. A softening curve is obtained from the correlation between Vickers hardness and the PIRMP. This curve can be used as a non-destructive method to evaluate the remanent life of turbine rotor steel.

A Study on the Liquid Flow Characteristics in Layer Porous Media (다공질매체내의 유체유동 특성에 관한 연구)

  • Lee, C.G.;Hwang, C.B.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.5 no.4
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    • pp.243-248
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    • 1993
  • In this research, unsteady groundwater flow in unconfined and homogeneous three layer aquifers is studied theoretically and experimentally. Numerical solutions are obtained by Runge Kutta and Runge Kutta Gill method after transforming the governing nonlinear partial differential equations to nonlinear ordinary differential equations. Experimental apparatus includes a test section filled with fine, medium and coarse sands. Experimental results are compared with the numerical solutions and both experimental and numerical results correspond well with each other. This numerical approach may be also applied to the cases which have more aquifers.

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Investigation on Differential Settlement Characteristics of the Final Landfill Cover Used SRSL (부등침하 발생 시 SRSL이 적용된 매립지 최종복토층의 침하 특성 검토)

  • Kwon, Oh-Jung;Oh, Myoung-Hak;Cho, Wan-Jei;Park, Jun-Boum
    • Journal of the Korean Geosynthetics Society
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    • v.8 no.4
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    • pp.9-17
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    • 2009
  • This research was intended to verify the stability of landfill final cover using SRSL(Self Recovering Sustainable Liner) with regard to differential settlements due to the degradation of waste and so on in a waste landfill. Numerical analysis was performed using FLAC 2D software program with input parameters based on soil characteristic tests and reference data after the blank was designed in order to represent the decomposition condition of waste. The maximum settlement of landfill cover was calculated to investigate the structural stability of landfill cover with the different condition of settlement width, settlement depth, and number of differential settlements. The allowable maximum deformation rate of SRSL, which was calculated using field permeability tests, was 6 mm. The analysis showed that SRSL was stable in case of a differential settlement width not exceeding 24.5% of total cover width.

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Preparation of Hydroxy Polyimde Membranes for Gas Separation by Phase Inversion Method (상전이법을 이용한 기체 분리용 Hydroxy Polyimide 막의 제조)

  • Woo, Seung-Moon;Choi, Jong-Jin;Nam, Sang-Yong
    • Membrane Journal
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    • v.22 no.1
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    • pp.62-71
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    • 2012
  • In this study, for preparation of gas separation membrane with high permeability, hydroxy polyimide was synthesized using 6FDA and APAF. Synthesis of HPI was confirmed by H-NMR and FT-IR, thermal property of membrane was characterized by Differential scanning calorimetric (DSC) and thermogravimetric analyzer (TGA). Especially, the synthesized HPI can possible to search conversion to PBO at $450^{\circ}C$. To obtain the membrane having high permeability, ternary system consist of polymer, solvent and non-solvent additive was introduced, asymmetric HPI flat sheet membrane was prepared by phase inversion method. Finally, the change of morphology with each component was observed through FE-SEM.

Practical Design of the Sandmat Considering Consolidation Settlement Properties (연약지반의 침하특성을 고려한 샌드매트의 실용적 설계를 위한 고찰)

  • Lee, Bongjik;Kwon, Youngcheul;Lee, Jongkyu
    • Journal of the Korean GEO-environmental Society
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    • v.8 no.5
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    • pp.31-38
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    • 2007
  • The practical design method on sandmat uses a drain length, rate of consolidation settlement and permeability of sand as a major design factors. And, on the basis of this design process, it has been installed beneath the embankment with same thickness. However, the possibility the underestimation on the thickness of sandmat and the delayed drain have been pointed out by several authors caused by a differential settlement at the center and the end of embankment. In this study, therefore, the effect of the differential settlement on the thickness of sandmat and delayed drain through the numerical analysis of embankment was analyzed. As a result, a substantial sandmat thickness becomes small and the possibility of the delayed drain can be certified because of the development of differential settlement at the center and ends of embankment. As a countermeasure to overcome this problem, the applicability of the mound type sandmat was also investigated by the numerical method. It can be concluded that it maintains the designated substantial sandmat thickness throughout consolidation process, and is useful method to maintain the drain capacity. Especially, the mound type sandmat is effective method for a construction site where can cause a differential settlement such as embankment. Furthermore, it has to be designed on the basis of the accurate prediction of consolidation settlement as well as rate of consolidation settlement, drain length and permeability of sand.

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Characterization of Gas Permeation Properties of Polyimide Copolymer Membranes for OBIGGS (OBIGGS용 공중합체 폴리이미드를 이용한 기체분리막의 투과 특성평가)

  • Lee, Jung Moo;Lee, Myung Gun;Kim, Deuk Ju;Nam, Sang Yong
    • Membrane Journal
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    • v.24 no.4
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    • pp.325-331
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    • 2014
  • We synthesized novel polyimides with high gas permeability and selectivity for application of on board inert gas generation system (OBIGGS). 2,2-bis(3,4-carboxylphenyl) hexafluoropropane dianhydride (6FDA) and two kinds of amines with high permeability and solubility were used to prepare the novel polymide. 2,3,5,6-Tetramethyl-1,4-phenylenediamine (TMPD) was used to improve gas permeability and various kinds of diamines were used to improve the gas selectivity respectively. The polyimide copolymers were synthesized by commercial chemical imidization method and their average molecular weights were over 100,000g/mol. The glass temperature ($T_g$) and the thermal degradation temperature were characterized using differential scanning calorimeter (DSC) and thermogravimetric analysis (TGA). The synthesized copolymers showed high $T_g$ over $300^{\circ}C$ and high thermal degradation temperature over $500^{\circ}C$. The gas permeation properties were measured by time-lag equipment. Although general polyimides showed very low gas permeability, synthesized polyimide copolymer showed high $O_2$ permeability of 36.21 barrer with high $O_2/N_2$ selectivity around 4.1. From this result, we confirm that these membranes have possibility to apply to OBIGGS.

Differential Inhibition of $MPP^+$- or 6-Hydroxydopamine-induced Cell Viability Loss in PC12 Cells by Trifluoperazine and W-7

  • Lee, Chung-Soo
    • The Korean Journal of Physiology and Pharmacology
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    • v.9 no.4
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    • pp.247-253
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    • 2005
  • The present study assessed the effect of calmodulin antagonists trifluoperazine and W-7 against the cytotoxicity of $MPP^+$ and 6-bydroxydoparnine (6-OHDA) in relation to the mitochondrial dysfunction and cell death in PC12 cells. Trifluoperazine (an inhibitor of the mitochondrial permeability transition and calmodulin antagonist) and W-7 (a specific calmodulin antagonist) significantly attenuated the $MPP^+-induced$ cell viability loss in PC12 cells with a maximum inhibition at $0.5{\sim}1{\mu}M$; beyond these concentrations the inhibitory effect declined. Both compounds at this concentration range did not cause cell death significantly. In contrast to $MPP^+$, the trifluoperazine and W-7 did not depress the cytotoxic effect of 6-OHDA. Addition of trifluoperazine and W-7 inhibited the cytosolic accumulation of cytochrome c and caspase-3 activation in PC12 cells treated with $MPP^+$ and attenuated the formation of reactive oxygen species and the depletion of GSH, whereas both compounds did not reduce the effect of 6-OHDA. The results show that trifluoperazine and W-7 may attenuate the cytotoxicity of $MPP^+$ by inhibition of the mitochondrial permeability transition and calmodulin. Meanwhile, the cytotoxic effect of 6-OHDA seems to be mediated by the actions, which are different from $MPP^+$.

The State of Water in Modified Cellulose Membranes (변성 셀룰로오즈 막내의 물의 상태)

  • Lee, Soon Hong;Lee, Young Moo;Kim, Jin Il;Kim, Jae Jin
    • Applied Chemistry for Engineering
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    • v.4 no.1
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    • pp.125-131
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    • 1993
  • The state of water in various modified cellulose membranes such as [carboxymethyl cellulose(CMC)-gelatin] polyelectrolyte complex, methylcellulose(MC) grafted with acrylic acid(AA), [(MC-g-AA)-gelatin] polyelectrolyte complex, were determined by differential scanning calorimetric technique. The amounts of freezing(free) and nonfreezing(bound) water were estimated to determine the permeability coefficient of solutes through membranes. The state of water in membranes were influenced by the states of the composition, morphology, and their water content. The difference in diffusive permeability through the water-swollen membranes can be explained by the difference in the free and bound water content.

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Transport Properties of Polymer Blend Membranes of Sulfonated and Nonsulfonated Polysulfones for Direct Methanol Fuel Cell Application

  • Kim, Dong-Hwee;Kim, Sung-Chul
    • Macromolecular Research
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    • v.16 no.5
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    • pp.457-466
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    • 2008
  • The relation between the phase separated morphologies and their transport properties in the polymer blend membrane for direct methanol fuel cell application was studied. In order to enhance the proton conductivity and reduce the methanol crossover, sulfonated poly(arylene ether sulfone) copolymer, with a sulfonation of 60 mol% (sPAES-60), was blended with nonsulfonated poly(ether sulfone) copolymer (RH-2000, Solvay). Various morphologies were obtained by varying the drying condition and the concentration of the casting solution (10, 15, 20 wt%). The transport properties of proton and methanol molecule through the polymer blend membranes were studied according to the absorbed water. AC impedance spectroscopy was used to measure the proton conductivity and a liquid permeability measuring instrument was designed to measure the methanol permeability. The state of water in the blend membranes was confirmed by differential scanning calorimetry and was used to correlate the morphology of the membrane with the membrane transport properties.

Effect of Ca and Al Additions on the Magnetic Properties of Nanocrytalline Fe-Si-B-Nb-Cu Alloy Powder Cores

  • Moon, Sun Gyu;Kim, Ji Seung;Sohn, Keun Yong;Park, Won-Wook
    • Journal of Magnetics
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    • v.21 no.2
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    • pp.192-196
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    • 2016
  • The Fe-Si-B-Nb-Cu alloys containing Ca and Al were rapidly solidified to thin ribbons by melt-spinning. The ribbons were ball-milled to make powders, and then mixed with 1 wt.% water glass and 1.5 wt.% lubricant. The mixed powders were burn-off, and then compacted to form toroidal-shaped cores, which were heat treated to crystallize the nano-grain structure and to remove residual stress of material. The characteristics of the powder cores were analyzed using a differential scanning calorimetry (DSC) and a B-H meter. The microstructures were observed using transmission electron microscope (TEM). The optimized soft magnetic properties (${\mu}_i$ and $P_{cv}$) of the powder cores were obtained from the Ca and Al containing alloys after annealing at $530^{\circ}C$ for 1 h. The core loss of Fe-Si-B-Nb-Cu-based powder cores was reduced by the addition of Ca element, and the initial permeability increased due to the addition of Al element.