• 분석과학
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• 제9권1호
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• pp.91-97
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• 1996

수계에서 화학물질의 독성에 대한 humic acid(HA)의 영향을 예측하기 위하여 HA와 화학물질간의 결합상수($K_B$)를 equilibrium dialysis를 이용하여 cartap, diazinon, fenobucarb, pentachlorophenol, P,P'-DDT를 대상으로 측정하였다. $K_B$의 실험치 및 옥탄올/물 분배계수를 이용한 예측치로부터 대상 화합물 중 P,P'-DDT를 제외하고는 HA에 의해 수계 독성에 영향을 줄만한 농도의 감소는 없을 것으로 추정되었다. 실제 자연환경에서는 $K_B{\geq}10^5$ 또는 $K_{ow}{\geq}10^6$ (log $K_{ow}{\geq}6$)인 화학물질에 대해서만 HA에 의한 독성감소 효과를 기대할 수 있는 것으로 생각 되었다.

• 한국지능시스템학회논문지
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• 제15권6호
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• pp.682-687
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• 2005

본 논문에서는 생물의 2차원영상에서 5가지 특징을 추출한 다음 약품에 대한 생물의 행동 패턴 반응에 대하여 의사결정나무를 적용하여 패턴의 인식 및 분류를 하였다. 생물의 행동패턴을 대변하는 물리적인 특징인, 속도, 방향전환 각도, 이동거리에 대하여 각각 중간이상속도비율 FFT(Fast Fourier Transform), 2차원 정사영 면적, 프렉탈 차원, 무게중심을 사용하여 특징을 추출하였다. 이렇게 추출된 5가지의 특징변수들을 사용하여 의사결정나무 모델을 구성한 다음 생물의 약품 첨가에 대한 반응을 분석하였다 또한 결과에서는 기존의 생물의 행동패턴 구분에 쓰였던 전형적인 기법(conventional methods) 보다 본 연구에서 적용한 의사결정나무가 생물의 행동패턴이 가지는 물리적 요소에 대한 독해력을 가짐을 보임으로써 특정 환경에서 이동행동에 대한 분석을 용이하게 하고자 하였다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2002년도 추계학술발표회
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• pp.81-85
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• 2002

The possibility of simultaneous analysis of 24 pesticides out of 30 residual pesticides which are subjected to test in the golf courses was examined. The utility of the simultaneous analysis of multi-residue pesticides was evaluated by recovery test through a standard addition method of pesticides in water, soil, and lawn grass. The experimental results of the recovery rates for individual pesticides are as follows : The number of pesticide of which average recovery was over 70% regardless of medium was 16 pesticides. These pesticides were composed of 8 organophosphorus pesticides(Chlorpyrifos, Chlorpyrifos-methyl, Diazinon, EPN, Fenitrothion, Phenthoate, Phosalone, and Toclofos-methyl). 4 organochlorinated pesticides(Daconil, Captan, Endosulfan, and Tetradifon), 2 pyrethroid pesticides(Fepropathrin, Lambda-cyhalothrin) and 2 other pesticides(Bromopropylate, Pendimethalin). On the other hand, in case of Dicofol, average recovery by medium was over 70% for water and lawn grass but was only 53.3% for soil. Therefore, the simultaneous analytical method applied in this experiment is not appropriate for analysis of Dicofol in soil. Furthermore, among 7 pesticides, 2 pesticides(Amitraz and Pyraclofos) showed that theirs average recovery rates deviated from criteria(70~130%) at almost all media, while 5 pesticides(Bensulide, Deltamethrin, Iprodione, Phosphamidon and Tralomethlin) were not detected from all media by selected GC detector(NPD or ECD).

• 한국멀티미디어학회논문지
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• 제6권6호
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• pp.1062-1070
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• 2003

본 논문에서는 자동 추적 시스템을 이용하여 반자연적인 조건에서 화학 약물의 아치사량 투석에 반응하는 수중 생물중 하나인 물고기(송사리)의 행동을 관찰하였다. 결과의 분석을 위하여, 약물 투여 전의 대표적인 행동을 패턴 A로 정의하였으며, 약물 투여 후의 대표적인 행동을 패턴 B로 정의하였다. 실험 결과, 패턴 B가 약물 투여 후에 빈번하게 관찰되는 반면, 패턴 A는 약물 투여 전에 많이 관찰되었다. 또한, 물고기의 움직임 패턴을 자동으로 탐지하기 위하여 대표 패턴들을 인공신경망의 학습을 위하여 추출하였다. 독성 물질(다이아지논) 투여 후 패턴 B에 대한 평균 탐지율은 크게 증가하였으나, 패턴 A에 대한 탐지율은 크게 감소함을 볼 수 있었다 본 논문에서는 지표종의 행동 모니터링을 통하여 환경에서 독성 물질의 존재를 탐지하는 방법으로 인공 신경망의 적용을 보여주고 있다.

• International Journal of Fuzzy Logic and Intelligent Systems
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• 제7권1호
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• pp.58-65
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• 2007

Behavioral sequences of the medaka (Oryzias latipes) were continuously investigated through an automatic image recognition system in response to medaka treated with the insecticide and medaka not treated with the insecticide, diazinon (0.1 mg/l) during a 1 hour period. The observation of behavior through the movement tracking program showed many patterns of the medaka. After much observation, behavioral patterns were divided into four basic patterns: active-smooth, active-shaking, inactive-smooth, and inactive-shaking. The "smooth" and "shaking" patterns were shown as normal movement behavior. However, the "shaking" pattern was more frequently observed than the "smooth" pattern in medaka specimens that were treated with insecticide. Each pattern was classified using classification methods after the feature choice. It provides a natural way to incorporate prior knowledge from human experts in fish behavior and contains the information in a logical expression tree. The main focus of this study was. to determine whether the decision tree could be useful for interpreting and classifying behavior patterns of the medaka.

• 대한한의학회지
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• 제20권1호
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• pp.44-51
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• 1999

Analysis of residual pesticides in herbal drugs was performed by GC-ECD and GC-MS. Especially, selected ion monitoring(SIM) technique was applied to increase the GC/MS sensitivity. Analysis of residual pesticides was determined sensitivity and selectively without any internal standard by setting the SIM technique to their characteristic fragments for quantitation ion and confirmation ion. The combination of two detector, GC-ECD and MS-SIM technique, is abailable for determining a multiclass residual pesticides in herbal drugs. The average recoveries through the method were $65.9%{\sim}99.7%$ in herbal drugs. The data of gas chromatographic analysis was compared with the limits of residual pesticides in herbal drugs and agricultural foods. 4. 4-DDT was detected above the limits to the residual pesticides in herbal drugs. Diazinon and EPN were detected, but the limits of residual pesticides were less than that of agricultural foods.

• Food Science and Biotechnology
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• 제15권1호
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• pp.57-62
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• 2006

Six organophosphorus, one organochlorine, and three synthetic pyrethroid pesticides were analyzed for their residues during washing and hot-air drying of red peppers conducted in the production of powder. The residue ratio in organophosphorus pesticides was 33% in chlorpyrifos, 31 % in diazinon, 50% in methidathion, 80% in EPN, 28% in fenitrothion, and 60% in profenofos. The ratio in pyrethroids was 109% in cypermethrin, 102% in deltamethrin, and 106% in fenvalerate. That in organochlorine was 56% in ${\alpha}$-endosulfan and 90% in ${\beta}$-endosulfan. The results were greatly different between organophosphorus and pyrethroid pesticides. UV irradiation along with hot-air drying brought about a remarkable reduction of the residues, up to 70% as compared with hot-air drying only. The removal effect was most remarkable in pyrethroids, which are hardly removed by hot-air drying. The color of the pepper was not changed during UV irradiation. The use of oxidizing agents such as hydrogen peroxide or chlorine dioxide during washing did not show a remarkable removal of residues. The residue ratio was not affected whether the pesticide is contaminated artificially or naturally.

• Bulletin of the Korean Chemical Society
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• 제33권4호
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• pp.1183-1189
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• 2012

The KOrea Insecticide Exposure Model (KOIEM) was developed to facilitate ecological risk-based management of Korean insecticides. KOIEM, applied as a multimedia fate model, evaluates water, soil, air, and vegetation compartments based on three water-body types (streams, ditches, and ponds). Deltamethrin, a pyrethroid insecticide, was used to evaluate and create the model parameters. After exposure of both the stream and the ditch to deltamethrin, the KOIEM-predicted concentrations and the observed levels were in agreement. The model was also evaluated using the accuracy factor (AF), which was 4.32 and 0.35 for the stream and ditch, respectively. Ecological risk assessment was also performed to evaluate the application of KOIEM for four popular South Korean insecticides (cypermethrin, deltamethrin, diazinon, and permethrin). Despite the insecticides having low PECs in water, their risk quotients were typically above 1.0. Thus, KOIEM modification would be required in further studies to account for spatial variation.

• Environmental Analysis Health and Toxicology
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• 제18권2호
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• pp.145-153
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• 2003

The goal of this study is to develop a biomarker used in monitoring abnormal behaviors of Japanese medaka (Oryzias latipes) as a model organism caused by hazardous chemicals. Japanese medaka was treated by copper of appropriate sublethal concentrations after starvation for 48 hr. The untreated individuals showed common behavioral characteristics (i.e. , smooth and linear movements). Locomotive activity of the fish was monitored using an image processing and automatic data acquisition system. When treated with copper (100 ppb), the fish showed shaking patterns more frequently. As the concentration of copper increased to 1,000 ppb, activity decreated, and the fish showed an erratic movement. Fish were exposed to copper at various concentrations (0,100 and 1,000 ppb) for 24 hrs, and acetylcholine esterase (AChE) activity was observed. When fish were exposed to 1,000 ppb of copper, the body AChE activities appeared to decrease but the head AChE activities showed little change. Expressions of tyrosine hydroxylase (TH) protein in the different organs from both head (brain) and body (kidney) portions affected by the copper treatment were analyzed using immunohistochemical technique compared with control. Five organs of the fish (olfactory bulb, hyothalamus, optic lobe, pons and myelencephalon regions) showed a relatively strong TH protein expression in the control experiment. A differential expression of TH, however, was observed in the treatment (100 ppb and 1,000 ppb). The treatment (1,000 ppb) significantly suppressed TH protein production in the brain regions. In kidney, however, the same treatment caused little suppression compared with the control. Copper appeared to be less effective in suppression of TH than diazinon, a known TH suppressor. It was concluded that TH could be used at a potential biomarker to monitor the acute copper toxicity in Japanese medaka.

• 한국응용곤충학회지
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• 제16권4호
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• pp.217-220
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• 1977

IRRI에서 고안제작한 액상 주입기(Liquid applicator)에 의한 Carbofuran 액상근부주변 처리의 수도 해충 방제 효과에 대한 시험을 Capsule 근부처리, 입제, 수면처리와 비교 시험을 호남작물시험장 묘 포장에서 실시하였다. Carbofuran 액상근부 주변처리는 Carbofuran Capsule 근부 처리에 비하여 해충 방제효과가 낮었다. 그러나 Carbofuran, Diaainon입제 수면시용, 2내지 4회 처리와 대등내지는 상회하는 해충방제 효과가 있었다. 이들 해충 방제효과는 유신품종에 비하여 팔굉 품종에서 현저히 높였으며 액상 Carhofuran일회 근부처리는 수도 전 생유기에 걸친 이화명충, 애멸구와 줄무늬 잎마름병 및 끝동매미충 방제의 가능성이 엿 보였다.