• Bulletin of the Korean Chemical Society
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• 제20권3호
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• pp.352-354
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• 1999

The spectrophotometric determination of Cu(Ⅱ) with α-(2-benzimidazolyl)-α',α"-(N-5-nitro-2-pyridylhydrazone)-toluene has been investigated. The optimum conditions of pH, stability, concentration of ligand and surfactant were evaluated. This method is a simple and sensitive method for determination of Cu(Ⅱ) and offers a selective separation of Cu(Ⅱ) from sample solution containin- I ppm below amount of Ni(Ⅱ), Co(Ⅱ), Zn(Ⅱ) and Sn(Ⅱ). Copper was determined by measuring the absorbance of Cu(Ⅱ)-BINPHT complex extracted with benzene in Brij 58 surfactant at 410 nm. Beer's law is obeyed over the concentration range 0∼2.5 μgmL-1 and the detection limit (S/N=2) is 0.06 μgmL-1. The relative standard deviation at the 0.3 μgmL-1 is 2.4% (N=7). The method was applied for the determination of Cu(Ⅱ) in various milks.

• 생물정신의학
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• 제7권2호
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• pp.180-185
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• 2000

Objective : The present study was designed to compare Global Field Power Measurement and conventional method in P300 determination. Method : The subjects were composed of patients(N=20) with schizophrenia by DSM-IV and normal controls(N=20). The auditory event related potential P300 was measured by "oddball paradigm". P300 components were determined by Global Field Power Measurement and conventional method at 5 electrodes(Fz, Cz, Pz, $T_3$, $T_4$). Results : P300 amplitudes of patients were smaller than those of controls across all electrodes and in both methods, but there was no differential power in P300 determination between two methods. Asymmetry of auditory event-related potential P300 was not shown between patients with schizophrenia and normal controls. Conclusion : It is implicated that it depends on clinical situations and research purposes what method of P300 determination will be more appropriate for patients with schizophernia.

• 약학회지
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• 제28권6호
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• pp.321-325
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• 1984

A HPLC determination method of xanthinol nicotinate(I) was developed for study of its stability and characteristics in solutions. I was determined using an ${\mu}-Bondapak\;C_{18}$ column with a mobile phase of methanol: $H_2O$ (1 : 1) and UV absorbance detection at 254nm. The results revealed that the method was enough to use as stability indicating determination with the mean of 99.9% and standard deviation of ${\pm}1.42%$ when analyzed 10 times for standard solution.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 2001년도 ICCAS
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• pp.167.5-167
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• 2001

Single point attitude determination method provides an optimal attitude minimizing the Wahba loss function. However, for the insufficient number of measurement vectors, the conventional single point methods has no unique solution. Thus, we introduce the sequential method to and an optimal attitude minimizing the windowed loss function. In this paper, this function is de ned as the sum of square errors for all measurement vectors within the axed sliding window. For simple implementation, the proposed algorithm is rewritten as a recursive form. Moreover, the covariance matrix is derived and expressed as a recursive form. Finally, we apply this algorithm to the attitude determination system with three LOS measurement sensors.

• 산업경영시스템학회지
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• 제14권24호
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• pp.163-168
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• 1991

In the FMS design, the important points are the selection of parts and the determination of configuration. The common approach method which solve the selection of parts are the determination of configuration has improved that the two points are simultaneously. This study finds the best method which parts combination and configuration are satisfied at the same time. And the optimal replace time of equipment under limited budget on the view Point of engineering. economy.

• 약학회지
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• 제5권1호
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• pp.24-26
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• 1960

Micro-determination of Lead by Dithizone Method was studied as follows: 1) Max. absorption wave length of Dithizone-pb complex in CC $l_{4}$ soln. is 510m.mu., 2) at the range of 5.gamma.-120.gamma. pb content, Bourguer-Beer's law hold good, 3) co-existence of F $e^{++}$ Z $n^{++}$, and C $u^{++}$ interfere.rfere.

• 제어로봇시스템학회논문지
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• 제14권6호
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• pp.587-594
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• 2008

In this paper, an efficient integer ambiguity resolution method for GNSS attitude determination system is described. The proposed method solves the integer least-squares with quadratic equality constraints(ILSQE) problem and shows an expansion of the LAMBDA method can be used to solve it. The solution of ILSQE is shown and an efficient implementation with a LAMBDA based method is given. The method is compared with some other methods. The results of static and dynamic tests show the dramatic improvement of the success rates of integer ambiguity resolution.

• 방사성폐기물학회지
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• 제2권1호
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• pp.77-85
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• 2004

원전에서 발생된 중$.$저준위 방사성 폐기물의 경우 처분장으로 이송되기 이전에 드럼에 대한 세부적인 정보 특히 핵종 재고량에 대한 평가가 수행되어야 한다. 그러나 드럼처리된 방사성폐기물의 경우 평가 대상 핵종 농도에 대한 예측이 어려운 것이 일반적이다. 따라서 이를 극복하고자 직접측정이 어려운 경우 척도인자 방법을 활용하고 있다. 국내의 경우 1996년부터 고리원전에서 척도인자 개념이 적용된 핵종분석장치를 운영해오고 있다. 그러나 고리원전에 적용된 척도인자의 경우 많은 개선의 여지가 남겨져 있다. 따라서 현재 척도인자의 향상을 위한 연구가 진행 중에 있다. 본 논문에서는 연구의 범위에 대한 개략적인 소개와 핵종 재고량 평가 방법 중 보다 신뢰할 수 있는 평가 방법을 찾고자 통계적인 척도인자 평가 방법을 비교 평가했으며 이를 통해 고리원전에 사용된 산술평균 방법을 기하평균 방법으로 바꾸는 것이 예측의 정확성을 향상시킬 수 있을 뿐만 아니라 드럼내 핵종 재고량의 과대평가를 막고 합리적인 보수성을 유지할 수 있음을 알수 있었다.

• Bulletin of the Korean Chemical Society
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• 제27권6호
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• pp.863-868
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• 2006

The partial least squares (PLS-1) calibration model based on spectrophotometric measurement, for the simultaneous determination of sulfite and sulfide is described. This method is based on the difference between the rate of the reaction of sulfide and sulfite with Malachite Green in pH 7.0 buffer solution and at 25 ${^{\circ}C}$. The absorption kinetic profiles of the solutions were monitored by measuring the decrease in the absorbance of Malachite Green at 617 nm in the time range 10-180 s after initiation of the reactions with 2 s intervals. The experimental calibration matrix for partial least squares (PLS-1) calibration was designed with 24 samples. The cross-validation method was used for selecting the number of factors. The results showed that simultaneous determination could be performed in the range 0.030-1.5 and 0.030-1.2 $\mu$g m$L ^{-1}$ for sulfite and sulfide, respectively. The proposed method was successfully applied to simultaneous determination of sulfite and sulfide in water samples and whole human blood.

• 약학회지
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• 제28권2호
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• pp.61-67
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• 1984

A method is described for the spectrophotometric determination of platinum (IV) with 2-oximino-1-indanone based on solvent extraction of Pt:2-oximino-1-indanone complex. The 2-oximino-1-indanone reacted with Pt(IV) to form a dark-orange complex which shows a characterisic maximum absorption at 342nm. The optimum PH for the platinum extraction lies between 5.4~8.0. Beer's law obeys up to 0.98-16.3ppm of platinum (IV) and the molar absorption coefficient is $1.06{\times}10^{-4}L.mol^{-1}.cm^{-1}$. The relative standard deviation of the method was $\times2.1%$. The composition of the complex is estimated to be Pt : In= 1 : 1, by the mole ratio method and ion exchange resin experiment. The optimum condition for the determination of platinum has been studied in detail. The 2-oximin-1-indanone is found to be a selectivereagent for the determination of platinum, since the synthesixed 2-oximino-1-indanone did not react with other metals such as cobalt, cadmium, copper, manganese nickel, iron, lead and zinc, to form the complex. In this studies, we have also clarified Sindhwani and Singh's spectrophotometric determination data of various metals with acenaphthenequinone monooxime (Talanta 20,248, 1973), whose results were not correct.