• Title/Summary/Keyword: derivative method

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Aerodynamic admittances of bridge deck sections: Issues and wind field dependence

  • Zhang, Zhitian;Zhang, Weifeng;Ge, Yaojun
    • Wind and Structures
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    • v.25 no.3
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    • pp.283-299
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    • 2017
  • Two types of aerodynamic admittance function (AAF) that have been adopted in bridge aerodynamics are addressed. The first type is based on a group of supposed relations between flutter derivatives and AAFs. In so doing, the aero-elastic properties of a section could be used to determine AAFs. It is found that the supposed relations hold only for cases when the gust frequencies are within a very low range. Predominant frequencies of long-span bridges are, however, far away from this range. In this sense, the AAFs determined this way are of little practical significance. Another type of AAFs is based on the relation between the Theodorsen circulation function and the Sears function, which holds for thin airfoil theories. It is found, however, that an obvious illogicality exists in this methodology either. In this article, a viewpoint is put forward that AAFs of bluff bridge deck sections are inherently dependent on oncoming turbulent properties. This kind of dependence is investigated with a thin plate and a double-girder bluff section via computational fluid dynamics method. Two types of wind fluctuations are used for identification of AAFs. One is turbulent wind flow while the other is harmonic. The numerical results indicate that AAFs of the thin plate agree well with the Sears AAF, and show no obvious dependence on the oncoming wind fields. In contrast, for the case of bluff double-girder section, AAFs identified from the turbulent and harmonic flows of different amplitudes differ among each other, exhibiting obvious dependence on the oncoming wind field properties.

Frontier Orbitals of Fifteen C20H17(OH)3 Regioisomers: Hybrid DFT B3LYP Study

  • Lee, Seol;Lee, Ji Young;Lee, Kee Hag
    • Bulletin of the Korean Chemical Society
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    • v.34 no.8
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    • pp.2403-2407
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    • 2013
  • The hybrid density-functional (B3LYP/6-31G(d,p)) method was used to analyze the substitution effect on the $C_{20}H_{20}$ cage based on calculation of the frontier orbitals of fifteen $C_{20}H_{17}(OH)_3$ derivatives. All substitution products were geometrically optimized without constraints and confirmed by frequency analysis. The results suggest that the cis-1 cis-1 cis-2 regioisomer is the most stable isomer, which implies that hydrogen bonding exerts a stronger effect on the relative energies of the trihydroxide than long-range interactions. Thus, this supports the experimental result in which the bisvicinal tetrol was of particular preparative-synthetic interest. While the LUMO of each of the $C_{20}H_{17}(OH)_3$ regioisomers was equivalently delocalized over the void within the cage, the HOMO was limitedly delocalized on substituents and carbons in close proximity to the substituents. The characteristics of the HOMO of each of the regioisomers vary based on the substitution sites. This indicates that the 15 regioisomers of each $C_{20}H_{20}$ trisubstituted derivative might undergo an entirely different set of characteristic chemical reactions with electrophilic reagents. The results further suggest that the penta-substituted OH groups on the surface of the fullerene cage are more likely to be localized on a pentagon than to be homogeneously delocalized.

A Study on the Dynamic Positioning Control Algorithm Using Fuzzy Gain Scheduling PID Control Theory (퍼지게인 스케쥴링 PID 제어이론을 이용한 동적 위치 유지 제어기법에 관한 연구)

  • Jeon, Ma-Ro;Kim, Hee-Su;Kim, Jae-Hak;Kim, Su-Jeong;Song, Soon-Seok;Kim, Sang-Hyun
    • Journal of the Society of Naval Architects of Korea
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    • v.54 no.2
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    • pp.102-112
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    • 2017
  • Many studies on dynamic positioning control algorithms using fixed feedback gains have been carried out to improve station keeping performance of dynamically positioned vessels. However, the control algorithms have disadvantages in that it can not cope with changes in environmental disturbances and response characteristics of vessels motion in real time. In this paper, the Fuzzy Gain Scheduling - PID(FGS - PID) control algorithm that can tune PID gains in real time was proposed. The FGS - PID controller that consists of fuzzy system and a PID controller uses weighted values of PID gains from fuzzy system and fixed PID gains from Ziegler - Nichols method to tune final PID gains in real time. Firstly, FGS - PID controller, control allocation algorithm, FPSO and environmental disturbances were modeled using Matlab/Simulink to evaluate station keeping performance of the proposed control algorithm. In addition, simulations that keep positions and a heading angle of vessel with wind, wave, current disturbances were carried out. From simulation results, the FGS - PID controller was confirmed to have better performances of keeping positions and a heading angle and consuming power than those of the PID controller. As a consequence, the proposed FGS - PID controller in this paper was validated to have more effectiveness to keep position and heading angle than that of PID controller.

The Magnetic Properties of Polycrystalline Yttrium Iron Garnet by Ferromagnetic Resonance (강자성공명 현상을 이용한 YIG의 자기적 특성 연구)

  • 김기현;이대하;김영호
    • Journal of the Korean Magnetics Society
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    • v.9 no.1
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    • pp.7-16
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    • 1999
  • Stoichiometric and nonstoichiometric $Y_{3-x}Fe_{5+x}O_{12})$ polycrystalline samples (x=0.00, 0.05, 0.10, 0.30, -0.05, -0.10, -0.30) were prepared by solid state reaction method. The magnetic properties of the sample were investigated by FMR (ferromagnetic resonance) technique at microwave frequency 5.11 GHz (G-band) and 23.39 GHz (K-band) respectively. The spectroscopic splitting factor g were estimated to be 2.04~2.35 from the derivative absorption lines. As the samples became yttrium $(Y^{3+})$ excess and iron $(Fe^{3+})$ excess, Magnetizations were decreased. But resonance linewidth were increased. To investigate the anisotropy, the angular dependence of resonance magnetic fields were measured. Angular dependence of effective magnetizations were measured by FMR from 77 K to 300 K at K-band microwave frequency (23.39 GHz) and the saturation magnetizations were measured by VSM. The Bloch coefficients B and C were determined by fitting. $M_{eff}(0)$ was obtained by the extrapolation from 80 K. From this result, the spin wave stiffness constant D $(about\; 162~206 \;eV{\AA}^2)$and average square range of exchange interaction $$$(about \;5.84~12.13\;{\AA}^2)$ were determined.

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Study for Extraction of Stable Vocal Features and Definition of the Features (음성의 안정적 변수 추출 및 변수의 의미 연구)

  • Kim, Keun-Ho;Kim, Sang-Gil;Kang, Nam-Sik;Kim, Jong-Yeol
    • Korean Journal of Oriental Medicine
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    • v.17 no.3
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    • pp.97-104
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    • 2011
  • Objectives : In this paper, we proposed a method for selecting reliable variables from various vocal features such as frequency derivative features, frequency band ratios, intensities of 5 vowels and an intensity of a sentence, since some features are sensitive to the variation of a subject's utterance. Methods : To obtain the reliable voice variables, the coefficient of variation (CV) was used as the index to evaluate the level of reliability. Since the distributions of a few features are not Gaussian, but are instead skewed to the right or left, we transformed the features by taking the log or square root. Moreover, the definition of the variables that are suitable to represent the vocal property was explained and analyzed. Results : At first, we recorded the vowels and the sentence five times both in the morning and afternoon of the same day, totally ten recordings from each of six subjects (three males and three females). We then analyzed the CVs of each subject's voice to obtain the stable features with a sufficient repeatability. The features having less than 20% CVs for all six subjects were selected. As a result, 92 stable variables from the 222 features were extracted, which included all the transformed variables. Conclusions : Voice can be widely used to classify the four constitution types and to recognize one's health condition from extracting meaningful features as physical quantity in traditional Korean medicine or Western medicine. Therefore, stable voice variables can be useful in the u-Healthcare system of personalized medicine and for improving diagnostic accuracy.

Residue Analysis of Quinclorac in Soil by Supercritical Fluid Extraction and Fluorogenic Derivatization Coupled with High Performance Liquid Chromatography (초임계추출과 형광유도체를 이용한 HPLC 에서의 Quinclorac 의 토양중 잔류분석)

  • Kim, Yong-Whan
    • Applied Biological Chemistry
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    • v.40 no.5
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    • pp.442-446
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    • 1997
  • A new analytical method was developed by HPLC after supercritical fluid extraction and fluorogenic derivatization for the determination of quinclorac (3,7-dichloro-8-quinoline carboxylic acid) in soil. The graminicide quinclorac was extracted from soil by supercritical fluid extraction. Supercritical carbon dioxide at 7000 psi $(80^{\circ}C)$ modified with 30% of methanol extracted quinclorac from soil samples at the level of $0.1ng\;g^{-1}$ with 96% recovery. Extracted quinclorac was determined by HPLC as a fluorescent derivative. Derivatization was made with 4-bromomethyl-7-methoxycoumarin (4-Br-Mmc) using 18-crown-6-ether as a catalyst. The conversion was completed within 30 min and the limit of detection was 0.5 ppb to prove that the procedure could be used in the residue analysis of the pesticides containing carboxylic acid group.

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Drone-based Power-line Tracking System (드론 기반의 전력선 추적 제어 시스템)

  • Jeong, Jongmin;Kim, Jaeseung;Yoon, Tae Sung;Park, Jin Bae
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.67 no.6
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    • pp.773-781
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    • 2018
  • In recent years, a study of power-line inspection using an unmanned aerial vehicle (UAV) has been actively conducted. However, relevant studies have been conducting power-line inspection with an UAV operated by manual control, and they have developed just power-line detection algorithm on aerial images. To overcome limitations of existing research, we propose a drone-based power-line tracking system in this paper. The main contributions of this paper are to operate developed system under configured environment and to develop a power-line detection algorithm in real-time. Developed system is composed of the power-line detection and the image-based tracking control. To detect a power-line in real-time, a region of interest (ROI) image is extracted. Furthermore, clustering algorithm is used in order to discriminate the power-line from background. Finally, the power-line is detected by using the Hough transform, and a center position and a tilt angle are estimated by using the Kalman filter to control a drone smoothly. We design a position controller and an attitude controller for image-based tracking control, and both controllers are designed based on the proportional-derivative (PD) control method. The interaction between the position controller and the attitude controller makes the drone track the power-line. Several experiments were carried out in environments where conditions are similar to actual environments, which demonstrates the superiority of the developed system.

Preparation of Conducting Polymer PEDiTT Thin Film Using SAM Method (자기조립법을 이용한 전도성고분자 PEDiTT박막의 제조)

  • 손용근;강규식;심창용;최정식;이두연
    • Polymer(Korea)
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    • v.26 no.5
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    • pp.589-598
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    • 2002
  • thiathlophene (EDiTT) was synthesized. The yield of the synthesis was about 29%. The monomer was identified by using NMR, IR and UV/Vis spectroscopic methods. Poly (3,4-ethylenedithiathiophene) (PEDiTT) was prepared using this monomer and FeCl$_3$. The deep blue green color of the product was changed into brown color by the reduction with $N_2$H$_4$. This was soluble to common organic solvents. Spectroelectrochemistry was used to characterize the PEDiTT. NMP was the best solvent for PEDiTT. PEDiTT/NMP solution was used for making SAM type thin film of the polymer on gold electrode. Electrochemical and IR spectroscopic methods were used to identify the thin film.

Determination of Aluminum Leached from Cooking Utensils by using Flow Injection Analysis (흐름주입분석법에 의한 주방용기로부터 용출된 알루미늄의 정량)

  • Choi, Yong Wook
    • Journal of Korean Society on Water Environment
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    • v.20 no.3
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    • pp.281-289
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    • 2004
  • Optimal analytical conditions have been established for mixing and reaction coil length, concentrations of ECR, CTAB, and acetate, reaction temperature and pH in the determination of aluminum by using flow injection analysis(FIA). Detection limit and repeatability for this system were $3{\mu}g/L$ and better than 1% of relative standard deviation, respectively. The interference from iron(III) was suppressed up to 6mg/L of iron(III) by $0.1{\mu}M$ ascorbic acid, and the interference from fluoride could be tolerated in absorption of Al/ECR/CTAB derivative by 10mM boric acid at pH 3.5 adjusted with nitric acid. This FIA system was applied to the determination of aluminum leached from cooking utensils by distilled and tap water containing fluoride ranged from 0.5 to 2mg/L by measurement of absorbance for Al/ECR/CTAB at 585nm. The leached aluminum content was increased with increasing concentration of fluoride. The aluminum contents leached from aluminum utensils by tap water were about 9 fold higher than those leached by distilled water, whereas aluminum contents leached by distilled water containing fluoride were about 2 fold higher compared to those leached by distilled water. That represented that other dissolved substances as well as fluoride in tap water contributed to liberation of aluminum from aluminum utensils. A comparison between FIA data and ICP-AES data by correlation and paired t test showed that the FIA system could be accepted as a good alternative method for the determination of aluminum in tap water.

Case Report of Generalized Anxiety Disorder Treated with Guibiondamtang-gami (범불안장애를 호소하는 귀비온담탕 가미방 치험 1례)

  • Yang, Seung-bo;Kim, Yeon-jin;Lee, Hyung-min;Lee, Hyun-joong;Cho, Seung-yeon;Park, Seong-uk;Park, Jung-mi;Ko, Chang-nam
    • The Journal of Internal Korean Medicine
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    • v.37 no.2
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    • pp.361-367
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    • 2016
  • Objective: This clinical study reports on the effect of traditional Korean medicine on a patient with generalized anxiety disorder.Method: A patient who suffered from generalized anxiety disorder was treated with herbal medicine (Guibiondamtang-gami), acupuncture, moxibustion, and pharmacopuncture. We assessed the changes of anxiety-related symptoms with the state-trait anxiety inventory (STAI) score, the Beck anxiety inventory (BAI) score, a heart rate variability (HRV) test, and a second derivative of photoplethymogram waveform (SDPTG) test.Results: After taking Guibiondamtang-gami for 22 days, the patient’s STAI score, BAI score, and LF/HF (low-frequency/high-frequency heart rate variability) ratio decreased, while the differential pulse wave index and stress power in the SDPTG test increased.Conclusion: This clinical case study has demonstrated that traditional Korean medicine may be an effective option for treating generalized anxiety disorder.