• Title/Summary/Keyword: deposition rate

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Changes of Sedimentary Environment in the Tidal Flat of the Dammed Yeongsan River Estuary, Southwestern Coast of Korea (영산강 하구 갯벌의 퇴적환경 변화)

  • Kim, Young-Gil;Lee, Myong Sun;Chang, Jin Ho
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.25 no.6
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    • pp.687-697
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    • 2019
  • By monitoring sediment grain size and level variation of tidal flat surface for 6 years (2005-2011), and also by mooring TISDOS (tidal-flat sediment dynamics observation system) on the low intertidal flat in 2008, we investigated the sedimentary environment of tidal flat in the dammed Yeongsan River Estuary. The tidal flat of the Yeongsan River Estuary lost 82 % of its area because of coastal development projects, and a narrow tidal flat below mean sea level now remains. Most of the tidal flat sediments are composed of silt up to 70-94 %, and show the characteristics of clay deficiency and silt dominance. This is closely related with the coastal development, which led to the destruction of high tidal flats where most mud settled, and the modification of tidal current patterns. Moreover, the estuarine tidal-flat sediments reveal seasonal variation. They are coarse with abundant silt during windy autumn to spring, fine with abundant clay during the less-windy and high-discharge summer. This phenomenon indicates that the behavior of sediment particles on the low intertidal flats of the Yeongsan River Estuary is influenced by wind waves for silt and fresh water discharge and the tidal process for clay. Monitoring results of the altitude of tidal flat surface showed that the study area had eroded at an average rate of -2.6 cm/y during the period of 2005-2011, and also that an unusual deposition with a rate of 4 cm/y occurred in 2010. The erosion can be explained by an increased tidal amplitude and a strengthened ebb-dominant tidal asymmetry after the construction of an estuary dike and the Yeongam Kumho Seawall. The deposition in 2010 seems to have been closely related to the mass production of suspended materials from dredging of the estuary.

Micro-Structure and Magnetic Properties of Electroless Co-W-P Alloy Deposits Formed (무전해 Co-W-P 합금 도금 층의 미세구조와 자기적 특성)

  • Yun, Seong-Ryeol;Han, Seung-Hui;Kim, Chang-Uk
    • Korean Journal of Materials Research
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    • v.10 no.1
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    • pp.97-106
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    • 2000
  • In these respects the purpose of this research is manufacturing Co-W-P alloy thin film on the corning glass 2948 by electroless plating method using $NaH_2PO_2H_2O$ (sodium hypophosphite) as a reductant, and analyzing deposition rate, alloy composition, microstructure, and magnetic characteristics at various pH's and temperatures. For Co-P alloy thin film, the reductive deposition reaction occurred only in basic condition, not in acidic condition. The deposition rate increased as the pH and temperature increased, and the optimum condition was found at the pH of 10 and the temperature of 8$0^{\circ}C$. Also magnetic characteristics was found to be most excellent at the pH of 9 and the temperature of 7$0^{\circ}C$, resulting in the coercive force of 870Oe and the squareness of 0.78. At this condition, the contents of P was 2.54% and the thickness of the film was 0.216$\mu\textrm{m}$. For crystal orientation, we could not observe fcc for $\beta$-Co. On the other hand, (1010), (0002), (1011) orientation of hcp for $\alpha$-Co was observed. We could confirm the formation of longitudinal magnetization from dominant (1010) and (1011) orientation of Co-P alloy. For Co-W-P alloy thin film, coercive force was 500Oe and squareness was 0.6. For crystal orientation, (0002) orientation of $\alpha$-Co was dominatly found. Then we could confirm the formation of perpendicular magnetization. The content of P was constant at 0.8$\pm$0.2% and the content of W increased as the concentration of Na$_2$WO$_4$increased. When the concentration of Na$_2$WO$_4$was 0.1mol/L, the composition of W was 20%. We observed the changes of magnetic characteristics and microstructure of thin film depositions of Co-W-P by the heat treatment. For heat treatment, the temperature was increased step by step to 10$0^{\circ}C$, 20$0^{\circ}C$, 30$0^{\circ}C$, and 40$0^{\circ}C$ and it took 1 hour at each step in the reductive condition of hydrogen gas. By the heat treatment, flatness of surface was improved, but there were no changes on the magnetic characteristics and the microstructures.

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A Study on Corrosive Characteristics of Inconel 625 for Petroleum Application by FCAW Process (석유시추용 인코넬 625강의 FCAW용접에 의한 부식성에 관한 연구)

  • PARK KEYUNG-DONG;AN DO-KEYUNG;AN JAE-PIL
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2004.05a
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    • pp.365-369
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    • 2004
  • Recently, Inconel 625 is used widely in offshore processing piping in order to extend the maintenance tenn and improve the quality of anti-corrosion. According to the resistance to attack in various corrosive media at temperatures from $200^{\circ}C$ to aver $1090^{\circ}C$, in combination with good low- and high-temperature mechanical strength. In general, High quality weldments for this material are readily produced by commonly used processes. in recent years, the flux cored arc welding(FCAW) process is becoming more popular due to higher deposition rate and a better weld quality as compared to the shielded metal arc welding (SMAW) process, at the same time, exhibiting equally good weld metal toughness similar to the SAW process. In this study, the weldability and weldment characteristics(mechanical properties and corrosive environment) of Inconel 625 are considered in FCAW weld associated with the several weld shielding gases($80\%Ar\;+\;20\%\;CO_2,\;50\%Ar\;+\;50\%\;CO_2,\;100\%\;CO_2$) in viewpoint of welding productivity.

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Temperature effect on Dry Etching of ZrO2 in Cl2/BCl3/Ar Plasma (기판 온도에 따른 Cl2/BCl3/Ar 플라즈마에서 ZrO2 박막의 건식 식각)

  • Yang, Xue;Ha, Tae-Kyung;Wi, Jae-Hyung;Um, Doo-Seung;Kim, Chang-Il
    • Journal of Surface Science and Engineering
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    • v.42 no.6
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    • pp.256-259
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    • 2009
  • The wafer surface temperature is an important parameter in the etching process which influences the reaction probabilities of incident species, the vapor pressure of etch products, and the re-deposition of reaction products on feature surfaces. In this study, we investigated all of the effects of substrate temperature on the etch rate of $ZrO_2$ thin film and selectivity of $ZrO_2$ thin film over $SiO_2$ thin film in inductively coupled plasma as functions of $Cl_2$ addition in $BCl_3$/Ar plasma, RF power and dc-bias voltage based on the substrate temperature in range of $10^{\circ}C$ to $80^{\circ}C$. The elements on the surface were analyzed by x-ray photoelectron spectroscopy (XPS).

Effect of GaGe Sputtering Power on Ga Doping in Phase Change Memory Materials (상 변화 메모리 재료 내의 Ga 주입에 미치는 GaGe 스퍼터링 전력의 영향)

  • Jung, Soon-Won;Lee, Seung-Yun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.5
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    • pp.285-290
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    • 2015
  • The phase change memory material is an active element in phase change memory and exhibits reversible phase transition behavior by thermal energy input. The doping of the phase change memory material with Ga leads to the increase of its crystallization temperature and the improvement of its amorphous stability. In this study, we investigated the effect of GaGe sputtering power on the formation of the phase change memory material including Ga. The deposition rate linearly increased to a maximum of 127 nm and the surface roughness remained uniform as the GaGe sputtering power increased in the range from 0 to 75 W. The Ga concentration in the thin film material abruptly increased at the critical sputtering power of 60 W. This influence of GaGe sputtering power was confirmed to result from a combined sputtering-evaporation process of Ga occurring due to the low melting point of Ga ($29.77^{\circ}C$).

Oxygen Barrier Coating with Carbon Interlayer on Polypropylene

  • Kim, Seong-Jin;Song, Eun-Gyeong;Jo, Gyeong-Sik;Yun, Tae-Gyeong;Mun, Myeong-Un;Lee, Gwang-Ryeol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.210-210
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    • 2012
  • Gas barrier coating from dense thin film deposition has been one of the important applications such as food-packaging and organic display. Especially for food-packaging, plastic container has been widely used due to its low price and high through-put in mass production. However, the plastic container with low surface energy like polypropylene (PP) has been limited to apply gas barrier coating. That is because a gas barrier coating could not adhere to PP due to its too low surface energy and high porosity of PP. In this research, we applied carbon coating consisting of Si and O as an interlayer between silicon oxide (SiOx) and PP. A carbon layer was found to provide better adhesion, which was experimentally proved by oxygen transmission rate (OTR) and SEM images. However, we also found that there is a limitation in the maximum thickness of a carbon layer and SiOx film due to their high stress level. For this conflict, we obtain the optimal thickness of a carbon layer and SiOx film showing optimal gas barrier property.

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Ginsenosides analysis in the crude saponin fraction extracted from Korean red ginseng, and its efficacious analysis against acute pulmonary inflammation in mice

  • Lee, Seung Min;Lim, Heung Bin
    • Analytical Science and Technology
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    • v.30 no.3
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    • pp.146-153
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    • 2017
  • In this study, we isolated ginseng crude saponin (GCS) from Korean red ginseng (KRG) and determined the ginsenoside content in it to investigate the physiological and pathological effects of GCS on acute pulmonary inflammation induced by intratracheal instillation of cigarette smoke condensates (CSC) and lipopolysaccharide (LPS) solution in BALB/c mice. GCS was orally administered at doses of 10 mg/kg and 25 mg/kg for 3 weeks. The recovery rate of GCS from KRG was 6.5 % and total ginsenosides from GCS was 1.13 %, and the content of Rb1 was the highest among them. Total inflammatory cells in the lung homogenates and bronchoalveolar lavage fluid (BALF) increased following intratracheal administration of CSC and LPS. However, GCS administration impaired this increase. Furthermore, it inhibited the increase in leukocytes in the blood, considerably decreased neutrophils in BALF, and declined infiltration of inflammatory cells and deposition of collagen in the tracheal and alveolar tissue. In this study, GCS was found to have a protective effect against acute pulmonary inflammation and it may be beneficial in preventing various respiratory diseases.

Hafnium Carbide Protective Layer Coatings on Carbon/Carbon Composites Deposited with a Vacuum Plasma Spray Coating Method

  • Yu, Hui-Il;Kim, Ho-Seok;Hong, Bong-Geun;Sin, Ui-Seop;Mun, Se-Yeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.237.2-237.2
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    • 2016
  • A pure hafnium-carbide (HfC) coating layer was deposited onto carbon/carbon (C.C) composites using a vacuum plasma spray system. By adopting a SiC buffer layer, we successfully integrated C.C composites with a $100-{\mu}m-thick$ protective coating layer of HfC. Compared to the conventional chemical vapor deposition process, the HfC coating process by VPS showed increased growth rate, thickness, and hardness. The growth behavior and morphology of HfC coatings were investigated by FE-SEM, EDX, and XRD. From these results, it was shown that the addition of a SiC intermediate layer provided optimal surface conditions during the VPS procedure to enhance adhesion between C.C and HfC (without delamination). The thermal ablation test results shows that the HfC coating layer perfectly protected inner C.C layer from thermal ablation and oxidation. Consequently, we expect that this ultra-high temperature ceramic coating method, and the subsequent microstructure that it creates, can be widely applied to improve the thermal shock and oxidation resistance of materials under ultra-high temperature environments.

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High Work Function of AZO Fhin Films as Insertion Layer between TCO and p-layer and Its Application of Solar Cells

  • Kang, Junyoung;Park, Hyeongsik;Yi, Junsin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.426.1-426.1
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    • 2016
  • We report high work function Aluminum doped zinc oxide (AZO) films as insertion layer as a function of O2 flow rate between transparent conducting oxides (TCO) and hydrogenated amorphous silicon oxide (a-SiOx:H) layer to improve open circuit voltage (Voc) and fill factor (FF) for high efficiency thin film solar cell. However, amorphous silicon (a-Si:H) solar cells exhibit poor fill factors due to a Schottky barrier like impedance at the interface between a-SiOx:H windows and TCO. The impedance is caused by an increasing mismatch between the work function of TCO and that of p-type a-SiOx:H. In this study, we report on the silicon thin film solar cell by using as insertion layer of O2 reactive AZO films between TCO and p-type a-SiOx:H. Significant efficiency enhancement was demonstrated by using high work-function layers (4.95 eV at O2=2 sccm) for engineering the work function at the key interfaces to raise FF as well as Voc. Therefore, we can be obtained the conversion efficiency of 7 % at 13mA/cm2 of the current density (Jsc) and 63.35 % of FF.

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Effect of Surfactant in Electroless Ni-B Plating for Coating on the Diamond Powder (다이아몬드 분말상에 무전해 Ni-B 도금을 위한 계면활성제의 영향)

  • Yang, Changyol;Yu, Si-Young;Moon, Hwan-Gyun;Lee, Jung-Ho;Yoo, Bongyoung
    • Journal of Surface Science and Engineering
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    • v.50 no.3
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    • pp.177-182
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    • 2017
  • The properties of electroless Ni-B thin film on diamond powder with different parameters (temperature, pH, surfactant etc.) were studied. The surface morphology, structure and composition distribution of the Ni-B film were observed by field effect scanning electron microscope (FE-SEM), energy-dispersive spectrometer (EDS), X-ray diffraction (XRD) and Auger electron spectroscopy (AES). The growth rate of Ni-B film was increased with increase of bath temperature. The B content in Ni-B film was reduced with increase of bath pH. As a result the structure of Ni-B film was changed from amorphous to crystalline structure. The PVP in solution plays multi-functional roles as a dispersant and a stabilizer. The Ni-B film deposited with adding 0.1 mM-PVP was strongly introduced an amorphous structure with higher B content (25 at.%). Also the crystallite size of Ni-B film was reduced from 12.7 nm to 5.4 nm.