• 한국생산제조학회지
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• 제8권2호
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• pp.126-136
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• 1999

We studied on crack growth retardation in single overloading condition. Crack tip branching which as the second mechanism on crack growth retardation was examined. Crack tip branching was observed to kinked type and forked type. It was found that the branching angle range was from 25 to 53 degree. The variations of crack driving force with branching angle were calculated with finite element method The variation of {{{{ KAPPA _I}}}}, {{{{ KAPPA _II}}}} and total crack driving force(K) were examined respectively So {{{{ KAPPA _I}}}}, {{{{ KAPPA _II}}}} and K mean to mode I, II and total crack driving force. Present model(Willenborg's model) for crack growth retardation prediction was modified to take into consideration the effects of crack tip branching When we predicted retardation with modified model. it was confirmed that predicted and experimental results coincided with well each other.

• Bulletin of the Korean Chemical Society
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• 제23권9호
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• pp.1201-1210
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• 2002

A new series of hyperbranched aromatic polyesters containing azoxybenzene mesogens and polymethylene spacers were prepared by polymerizing AB2 type monomers that have the isophthaloyl dicarboxylic acid terminal at one end and the p-oxyp henol terminal at the other end. The monomers contain a built-in azoxybenzene mesogen that is linked to the terminal groups through polymethylene spacers. The polyesters prepared were characterized by solution viscosity, differential scanning calorimetry, X-ray diffractometry and polarizing microscopy. All of the polyesters were found to be thermotropic (nematic). Their glass-transition temperatures and mesophase temperature ranges were very sensitive to the length of the two spacers existing in the repeating unit. The degree of branching of one of the polyesters was determined by the NMR spectroscopy and found to be 0.56.

• 한방재활의학과학회지
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• 제30권4호
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• pp.233-241
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• 2020

This study was performed to evaluate the effect of high frequency therapy applied to the region branching to the external carotid artery for peripheral facial paralysis sequelae. A patient suffering with facial edema due to facial paralysis sequelae had been treated with acupuncture, high frequency therapy on the branch area to the external carotid artery for 7 weeks. The evaluation of clinical outcome was done by degree of swelling by measuring the distance of the face and skin temperature of face through digital infrared thermographic imaging. After treatment, the patient's degree of swelling and the temperature difference between the affected side and normal side was decreased. In addition, the temperature was changed in the entire facial area as well as the treatment point of high frequency therapy. This result shows that acupuncture combined with high frequency therapy at the region branching to the external carotid artery could be an effective way to improve facial blood flow, although further clinical studies will be needed.

• Food Science and Biotechnology
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• 제17권2호
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• pp.234-240
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• 2008

The optimal conditions for the production of branched dextrin from com starch (CSBD) using branching enzyme (BE) were established by investigating the degree of retrogradation of the gelatinized starch. The physicochemical properties of CSBD prepared using the established process were evaluated. It was found that physicochemical properties of com starch were greatly modified by BE treatment. CSBD had a higher dextrose-equivalent value and water solubility than the corresponding control. On the other hand, the viscosities in gelatinized solution and amylose contents of CSBD were lower than those of the control. A high-performance size-exclusion chromatography/multiangle laser light scattering/retractive index (HPSEC/MALLS/RI) system showed that the average molecular weight of CSBD was lower than that of the control. The pasting viscosities of CSBD were stable during the entire temperature cycle. In general, the BE treatment resulted in the retrogradation during storage being lower for CSBD than for the control.

• Macromolecular Research
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• 제17권5호
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• pp.289-295
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• 2009

Low viscosity aromatic hyperbranched polyester epoxy resin (HTBE) was synthesized by the reaction between epichlorohydrin (ECH) and carboxyl-end hyperbranched polyester (HTB) which was prepared from inexpensive materials $A_2$ (1,4-butanediol glycol, BEG) and $B_3$ (trimellitic anhydride, TMA) by pseudo one-step method. The molar mass of the HTB was calculated from its acid value by "Recursive Probability Approach". The degree of branching (DB) of the HTB was characterized by model compounds and $^1H$ NMR-minus spectrum technology, and the DB of the HTB was about $0.47{\sim}0.63$. The viscosity and epoxy equivalent weight of the HTBE were $3,600{\sim}5,000\;cp$ and lower than 540 g/mol respectively. The reaction mechanism and structure of the $AB_2$ monomer, HTB and HTBE were investigated by MS, $^1H$ NMR and FTIR spectra technology. The molecular size of HTBE is under 8.65 nm and its shape is ellipsoid-like as determined by molecular simulation.

• 폴리머
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• 제36권2호
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• pp.149-154
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• 2012

생체적합성을 가진 키토산과 강력한 항산화제로 알려진 리포산을 합성하여 만든 양친매성 고분자를 이용하여 약물전달시스템으로서의 응용 가능성을 알아보았다. 수용액 상에서 자기조립의 성질을 가지는 양친매성 고분자는 나노입자를 형성하고 이 입자 안에 항암제로 널리 쓰이는 5-fluorouracil을 고체분산법을 이용하여 봉입하였다. 최적의 약물전달체를 얻기 위하여 키토산에 결합된 리포산의 비율을 조절하여 입자크기 및 약물봉입률을 비교하였다. DLS를 이용하여 측정한 나노입자는 약 250 nm 정도의 크기를 가졌고 그 봉입률은 10% 내외로 측정되었다. 42%의 리포산 치환율을 가지는 공중합체가 약물전달체로서 가장 우수한 성능을 보여주었다.

• 한국식품조리과학회지
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• 제8권3호
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• pp.291-296
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• 1992

The physicochernical properties of Korean buckwheat starches were investigated. The results were as follows; 1. Water binding capacity of kangwon hull buckwheat starch was 106.55% and that of Kangwon rice buckwheat was 99.35%. 2. The pattern of change in swelling power of hull buckwheat starch for increasing temperature started to increase at 60$^{\circ}C$ and increased rapidly from 80$^{\circ}C$, and that of rice buckwheat increased slowly from 60$^{\circ}C$ to 90$^{\circ}C$. 3. The ranges of gelatinization temp. of hull buckwheat and rice buckwheat starches were 70~75$^{\circ}C$ and 75~85$^{\circ}C$, respectively. 4. The blue value of hull buckwheat starch and rice buckwheat starch were 6.25 and 0.62, respectively. 5. The alkali number of hull buckwheat starch and rice buckwheat starch were 1.28 and 3.68 respectively. 6. The amylose content of hull buckwheat and rice buckwheat starch were 32.26% and 38.09%. 7. Periodate oxidation of hull buckwheat starch resulted that amylose had me average molecular weight of 103, 004, degree of polymerizatlon of 572 and amylopectin had me degree of branching of 7.64, glucose unit per segment of 13.09, and periodate oxidation of rice buck wheat starch resulted mat amylose had me average molecular weight of 125, 654, degree of polymerization of 698 and amylopectin had degree of branching of 6.59, glucose unit per segment of 15.16.

• 멤브레인
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• 제21권1호
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• pp.1-12
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• 2011

연료전지용 프로톤 전도성 고분자로서 분지체 함량이 조절된 부분불소계 Sulfonated poly(arylene ether sulfone) 이오노머 블록공중합체막의 합성 및 특성에 관하여 연구하였다. 분지형태의 부분불소계 블록고분자 전해질막 제조를 위해 설폰화 활성이 높은 단량체, 설폰화 활성이 낮은 단량체 그리고 분지체를 합성하였고, 블록형성을 위해 biphenyl계 올리고머를 합성하였다. 분지체의 양에 따른 막 특성변화를 고찰하기 위해, biphenyl계 올리고머와 sulfonyl계 단량체의 몰 비를 4 : 6으로 고정하고 분지체의 함량을 2 mol%까지 늘려가면서 중부가형태의 열중합을 통하여, 다른 분지체의 함량을 가지는 공중합체를 얻었다(BBC-40Bx). 제조된 분지형태의 공중합체들을 chlorosulfonic acid (CSA)를 사용하여 후설폰화(post-sulfonation)하였다(SBBC-40Bx). 제조된 화합물, 단량체, 분지체 및 중합체들은 $^1H$-NMR, $^{19}F$-NMR 및 FT-IR분석을 통하여 성공적으로 합성되었음을 확인하였다. 분지형태의 블록공중합체(SBBC-40Bx)는 분지체의 함량이 증가함에 따라 이온교환능력(IEC), 함수율 및 이온전도도가 증가하는 경향을 보였다.

• The Plant Pathology Journal
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• 제21권3호
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• pp.221-228
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• 2005

A total of 179 isolates of Trichoderma spp. were collected from oyster mushroom substrates in Korea. On the basis of morphological and cultural characteristics, Trichoderma isolates were divided into seven groups, namely T. atroviride, T. citrinoviride, T. harzianum, T. longibrachiatum, T. virens, and two unidentified species, referred to as Trichoderma sp. 1 and 2. The predominant species was Trichoderma sp. 2 (n=86) followed by Trichoderma sp. 1 (n=52). Trichoderma sp. 1 and 2 were morphologically distinct not only from the other species of Trichoderma reported but also from each other in the characteristics such as mycelial growth rate, colony appearance, shape of conidia and conidiophores and branching pattern of phialides, although branching pattern of phialides of Trichoderma sp. 1 was similar to that of T. harzianum. In virulence test, the degree for compost colonization of Trichoderma sp. 2 was significantly greater than that of the other Trichoderma species. Trichoderma sp. 2 was found to be the main cause of green mold disease in oyster mushroom production. More work including molecular characterization is needed to confirm the species of Trichoderma sp. 1 and 2.

• The Korean Journal of Ecology
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• 제14권3호
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• pp.327-343
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• 1991

Clonal growth and rhizome architecture of calmagrostis epigeios, were studied in a 15-year old coastal reclamed land. As c. epigeios patch grew from center to margin radially over time, concentric annuli were added. the radial increases of the mature patch were 80~130cm/yr. the patch ages of c. epigeios estimated by relationships between the diameter and is radial increament, were 1~6year old. There were the marked variations of density, phytomass, shoot height and inflorecence frequency with increasing age of rhizome system within the patch. the maximum performance occurred at 2-year-old concentric annuli of the patch. The growth phasic continuum with aging was divided into 5 grwth phases ; pioneer, building, matyre, senile and degenerate. The rhizome aging had a more significant effect on the inflorescence frequency than on the other attributes. new rhizomes tended to diverge from the direction of the parent ramet by sympodial growth. in a 1-year-old patch, average length of rhizome segment was 7cm, average number of internode was 6, and the tillering frequency was 27%. The tillering in the early stage resultd in the increase of shoot density and the producation of multibranching rhizome. as the result of that, circular patchwas formed in a year. The branching structure based on such facts was represented graphically in branching degree of 60 and 100. therefore, c. epigeios with clonal growth may establish and grow vigorously earlier than other glycophytes in high salt conditions such as the coastal reclaimed land.